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研磨作为4H碳化硅(4H-SiC)晶片加工的重要工序之一,对4H-SiC衬底晶圆的质量具有重要影响。本文研究了金刚石磨料形貌和分散介质对4H-SiC晶片研磨过程中材料去除速率和面型参数的影响,基于研磨过程中金刚石磨料与4H-SiC晶片表面的接触情况,推导出简易的晶片材料去除速率模型。研究结果表明,磨料形貌显著影响4H-SiC晶片的材料去除速率,材料去除速率越高,晶片的总厚度变化(TTV)越小。由于4H-SiC中C面和Si面的各向异性,4H-SiC晶片研磨过程中C面的材料去除速率高于Si面。在分散介质的影响方面:水基体系研磨液的Zeta电位绝对值较高,磨料分散均匀,水的高导热系数有利于控制研磨过程中的盘面温度;乙二醇体系研磨液的Zeta电位绝对值小,磨料易发生团聚,增大研磨过程的磨料切入深度,晶片的材料去除速率提高,晶片最大划痕深度随之增大。 相似文献
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Johisner Penagos‐Llanos Olimpo García‐Beltrn J. A. Caldern Edgar Nagles J. J. Hurtado 《Electroanalysis》2019,31(4):695-703
The detection of Allura red (AR) by electrochemical reduction using a different electrode from the conventional mercury electrode is presented. A carbon paste with cobalt (II, III) oxide composite electrode (CoOx/CPE) is reported for the first time for the detection of AR. Moreover, others dyes such as tartrazine (TZ), sunset yellow (SY), amaranth (AM), Ponceaut 4‐R (P‐4R), and Sudan (SD) as well as pharmaceutical agents such as paracetamol (PMC) that are present in samples that contained AR did not show a reduced signal between 0.0 and ?0.3 V, which is the potential range where AR reduction was observed. The surface electroactivity was studied using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM). The presence of CoOX increased the cathodic peak current for AR by more than 50 % and 65 % via CV and square wave voltammetry (SWV), respectively, compared with an unmodified carbon paste electrode. Under the optimal parameters, (pH=3.0, accumulation time (tACC)=60 s and accumulation potential (EACC)=0.50 V), the detection limit for AR was 0.05 μmol L?1. The new sensor was sensitive and stable for the detection of AR. Moreover, it was easily manufactured and very convenient for food samples such as soft and isotonic drinks as well as chili sauce. 相似文献
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Amanda S. Santana Diego B. Carvalho Nadla S. Cassemiro Luiz H. Viana Gabriela R. Hurtado Marcos S. Amaral Najla M. Kassab Palimécio G. Guerrero Jr. Sandro L. Barbosa Miguel J. Dabdoub Adriano C.M. Baroni 《Tetrahedron letters》2014
A simple synthesis of 3-iodothiophenes was demonstrated using a wide range of (Z)-thioenynes. The key step in the iodocyclofunctionalization was the selective reduction of the triple bond in (Z)-thioenynes by the addition of iodine as an electrophilic agent. The 3-iodothiophenes were obtained in good to excellent yields of 61–92%. The 3-iodothiophenes were used as substrates in Sonogashira cross-coupling reactions to obtain thiophene acetylenes. 相似文献
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通过UV-Vis、FTIR、DSC、以及色差、力学性能的测试表征,实时追踪分析了在紫外光老化过程中,含Pb、Sn以及Ca-Zn热稳定剂的PVC体系微观结构和宏观性能的演变过程.结果表明,在相同光老化条件下,PVC/Pb、PVC/Sn和PVC/Ca-Zn体系的微观结构变化规律基本一致,过程中主要的化学反应是,大分子吸收光能后,发生脱HCl生成共轭双键的反应、生成羰基的氧化反应、交联反应和降解反应;不同热稳定剂的作用,主要表现在对于微观结构变化的幅度和动力学过程的影响不同.相应地,3种体系的外观色差和力学性能的变化规律也相似,但色差的变化程度和速度以及老化后力学性能的保持率因所含热稳定剂的不同而不同,其中含Sn体系的颜色稳定性最好,含Pb体系的力学性能保持率最高。 相似文献
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García-Meca C Hurtado J Martí J Martínez A Dickson W Zayats AV 《Physical review letters》2011,106(6):067402
We experimentally demonstrate a low-loss multilayered metamaterial exhibiting a double-negative refractive index in the visible spectral range. To this end, we exploit a second-order magnetic resonance of the so-called fishnet structure. The low-loss nature of the employed magnetic resonance, together with the effect of the interacting adjacent layers, results in a figure of merit as high as 3.34. A wide spectral range of negative index is achieved, covering the wavelength region between 620 and 806 nm with only two different designs. 相似文献
18.
In a witness rectangle graph (WRG) on vertex point set P with respect to witness point set W in the plane, two points x, y in P are adjacent whenever the open isothetic rectangle with x and y as opposite corners contains at least one point in W. WRGs are representative of a larger family of witness proximity graphs introduced in two previous papers. We study graph-theoretic properties of WRGs. We prove that any WRG has at most two non-trivial connected components. We bound the diameter of the non-trivial connected components of a WRG in both the one-component and two-component cases. In the latter case, we prove that a graph is representable as a WRG if and only if each component is a connected co-interval graph, thereby providing a complete characterization of WRGs of this type. We also completely characterize trees drawable as WRGs. In addition, we prove that a WRG with no isolated vertices has domination number at most four. Moreover, we show that any combinatorial graph can be drawn as a WRG using a combination of positive and negative witnesses. Finally, we conclude with some related results on the number of points required to stab all the rectangles defined by a set of n points. 相似文献
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Zong Xin PI Hou Wen XIN* Department of Chemical Physics University of Science Technology of China Hefei 《中国化学快报》2001,(3)
IntroductionStochastic resonance (SR) is a nonlinear effect which describes the optimal detection of a weak periodic signal by the action of external noise in nonlinear systems. SR was originally proposed to account for periodicity in the Earth's ice ages1, and it has been observed in a wide range of biological2-4 , physical5 and chemical6 systems. The systems mentioned above which may give rise to SR have a denominator despite many examples of SR in different scientific areas. It is noted… 相似文献