Geometrical study of paraxial light beam transmission in free space

By introducing an imaginary space transform curvature ρ_s, a complex space called Riemannian space is constructed, in which the light propagating in free space has the trajectory of straight line while propagating. Moreover, this curvature couples with that of the wave front of the paraxial beam ρ_w, and therefore a complex curvature ρ_c is constructed, which can be employed to investigate the behavior of the light transmission and to generalize the ABCD law. Project supported by the National Hi-Tech Inertial Confinement Fusion Committee, the Guangdong Natural Science Foundation the Postdoctoral Foundation of Guangdong and National Postdoctoral Foundation of China.     

类金钢石非晶碳薄膜的光吸收和光致发光研究

我们用激光轰击石墨靶成功地制备出类金刚石无氢非晶碳薄膜.测量了光学吸收、光致发光及其随入射光强度的变化关系.结果表明,这种薄膜具有类金刚石的性质,光学带隙在1.67-2.25eV,发光在可见光区呈宽带结构.低激发强度下发光强度超线性变化,而在高激发强度下则为线性发光.我们用非成对载流子复合的模型对结果给出了合理的解释.用带尾态饱和的模型解释了发光峰值随激发光强增加而蓝移的现象.     

稳态锁模产生4ps激光脉冲

首次利用ＧａＡｓ光电导开关，控制Ｎｄ：ＹＬＦ激光器腔内Ｑ值，实现稳态锁模，获得脉宽和能量稳定性极高的４ｐｓ激光脉冲。     

Study of hot bands in the B2Σ+u-X2Σ+g system of C-2 anion

Optical heterodyne magnetic rotation enhanced velocity modulation spectroscopy was employed to observe the visible absorption spectra of the B^2Σ^+_u-X^2Σ^+_g electronic transition of C^-_2. Four hot bands (0,1), (1,2), (2,3) and (3,4) have been observed and the band (3,4) is measured directly for the first time, so far as we know, by absorption. A rotational analysis was carried out to obtain molecular constants. With the Franck－Condon principle and the vibrational Boltzmann distribution, we have estimated the vibrational temperature of C^-_2 to be about 3000K.     

有限秩的幂零p-群的p-自同构

设G是一个有限秩的幂零p-群,α和β是G的两个p-自同构,记I= ((αβ(g))(βα(g))-1)|g∈G),则(i)当I是有限循环群时,α和β生成一个有限P-群; (ii)当I是拟循环p-群时,α和β生成一个可解的剩余有限P-群,它是有限生成的无挠幂零群被有限p-群的扩张．     

Two New Ionone Derivatives from Rhododendron przewalskii Maxim

Two new ionone derivatives,named rhododendrone and rhododendronside,were isolated from the alcohoilc extract of the aerial parts of Rhododendron przwalskii Maxim.Their structures were elucidated on the basis of spectroscopic analysis.     

求解无线传感器网络路由问题的蚁群最优化算法及其收敛性

首先将无线传感器网络的路由问题转化成求解最小Steiner树问题,然后给出了求解无线传感器网络路由的蚁群优化算法,并对算法的收敛性进行了证明．最后对找到最优解后信息素值的变化进行了分析．即在限制信息素取值的条件下,当迭代次数充分大时,该算法能以任意接近于1的概率找到最优解,并且当最优解找到后,最优树边上的信息素单调增加,而最优解以外边上的信息素在有限步达到最小值．     

2‐Cyanoprop‐2‐yl dithiobenzoate mediated reversible addition–fragmentation chain transfer polymerization of acrylonitrile targeting a polymer with a higher molecular weight

The reversible addition–fragmentation chain transfer (RAFT) polymerization of acrylonitrile (AN) mediated by 2‐cyanoprop‐2‐yl dithiobenzoate was first applied to synthesize polyacrylonitrile (PAN) with a high molecular weight up to 32,800 and a polydispersity index as low as 1.29. The key to success was ascribed to the optimization of the experimental conditions to increase the fragmentation reaction efficiency of the intermediate radical. In accordance with the atom transfer radical polymerization of AN, ethylene carbonate was also a better solvent candidate for providing higher controlled/living RAFT polymerization behaviors than dimethylformamide and dimethyl sulfoxide. The various experimental parameters, including the temperature, the molar ratio of dithiobenzoate to the initiator, the molar ratio of the monomer to dithiobenzoate, the monomer concentration, and the addition of the comonomer, were varied to improve the control of the molecular weight and polydispersity index. The molecular weights of PANs were validated by gel permeation chromatography along with a universal calibration procedure and intrinsic viscosity measurements. ¹H NMR analysis confirmed the high chain‐end functionality of the resultant polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1272–1281, 2007