两种C_（60）－甘氨酸酯衍生物的室温荧光光谱

两种Ｃ_（６０）－甘氨酸酯衍生物的室温荧光光谱周德建，甘良兵，谭海松，骆初平，姚光庆，黄春辉（北京大学稀土材料化学及应用国家重点实验室，北京，１００８７１）关键词Ｃ_（６０）－甘氨酸酯衍生物，浓度猝灭，荧光寿命Ｃ６０在低温或室温及在紫外或可见光的激发下...     

用电光相位调制器显示超声行波波前

本文提出了一种用连续激光器,在时间相关理论依据下,以电光相位调制显示超声行波波前的新方法;并考虑到运动相位和静止相位的差异,提出了一种特殊的空间滤波技术,从而显示了超声行波的高对比像.     

Analysis of Phthalate Esters in Air,Soil and Plants in Plastic Film Greenhouse

The phthalate esters such as MDP,DEP,BDP and DEHP in air,soil and plant smples in plastic film greenhouse were clean up with fine silica gel column and determined with HPLC.It was found that the concentrations of PEs in ari and soil samples in plastic film greenhouse are much higher than those of contrast samples. But concentration of PEs in plants in plastic film greenhouse are not remarkably affected by the pollution of air and soil.     

磷酸盐、氟磷酸盐和氟化物玻璃中过渡金属离子的顺磁共振研究(Ⅱ)——Co2+,Ni2+

低温77K下,在三种玻璃中都观察到了Co²⁺的ESR信号,认为Co²⁺是处干四面体格位,从实验所得的有效g值,判别出中心离子与配位体间化学键的性质变化,本文还研究了氟磷酸盐玻璃中Ni²⁺ESR,辨认了Ni²⁺的谱线,用自旋哈密顿作了比较详细的分析计算,并解释了一般氧化物玻璃中很难观察到Ni²⁺的ESR的原因。 关键词：     

溶剂萃取原子吸收光谱法测定建材样品中微量铁

本文研究了在微酸性介质中用抗坏血酸还原Ｆｅ（Ⅲ），Ｆｅ（Ⅱ）与１，１０－二氮杂菲（ｐｈｅｎ）形成Ｆｅ（ｐｈｅｎ）＾２＋３配合物，加入ＣｌＯ＾－４阴离子与之形成离子缔合物，再用有机溶剂硝基苯萃取，火焰原子吸收测定有机相。本法检出限为１．１ｎｇ／ｍＬ，回收率为９８．５％－１０６％。     

关于激子谱线近傍的三阶非线性光学系数

本文计算了在激子谱线近傍,由于激子谱线的吸收饱和而引起的三阶非线性光学系数,并具体估计了GaAs的激子谱线和Cu₂O的黄系激子谱线的情况。 关键词：     

YBaCuO BICRYSTAL JUNCTIONS AND DC SUPERCONDUCTING QUANTUM INTERFERENCE DEVICES

We have prepared yttria-stabilized-zirconia bicrystal substrates using a simple hot-pressing method. The grain-boundary junctions have been fabricated with YBa₂Cu₃O₇ thin films grown epitaxially on the bicrystals. The patterns are defined by conventional photolithography, The dc and microwave characteristics of the junctiorts and the dc superconducting quantum interference devices (SQUIDs) have been intensively studied. The current-voltage curves are bridge-typed with noise rounding near the critical current. Resistive tail has been observed in the resistance versus temperature curves. The results are compared with the theoretical prediction for classical Josephson junctions. It is found that the behavior of bicrystal junctions can be described in the frame of classical theory. The deviations are attributed to the nonuniformity of the junctions. The small loop dc SQUIDs demonstrate diffraction and interference effects with regard to the applied magnetic field. A large square-washer with a new configuration has been designed to enhance the effective area of dc SQUID as a magnetometer. It has achieved a magnetic field resolution down to 1 pT/(Hz)^1/2(at 10Hz) at 77K.     

UV辐射光谱的光电测量研究

为了设计出符合要求的紫外产生材料和更好地对紫外光谱进行测量，提出了以原子材料为基础产生紫外光谱和采用紫外传感器测量紫外光谱的方法。这在对抗紫外制导方面具有十分重要的研究和实用价值。根据相关理论，重点对原子紫外光谱，尤其是碱金属原子核外电子的能量跃迁进行了分析和计算，列出了计算的谱线数据。介绍了目标紫外光谱的测量原理。在选用合适的紫外材料激发后，采用双光栅单色仪和紫外传感器进行测量。最后，给出了紫外传感器对紫外辐射的测量实验结果和测量曲线。     

高功率重复频率三电极气体开关自击穿特性

 以“CHP01”加速器为实验平台，对自行研制的重复频率三电极气体开关的自击穿特性开展了实验研究。研究了开关自击穿特性与气压、气流流速、电极形状等因素的关系，并对实验结果进行了分析。结果表明：随着气压的升高，开关自击穿电压分散性变大；适当流速的气流有助于减小开关的自击穿分散性，但气流流速过大将加大自击穿分散性；当通过改变电极形状增大极间场增强因子时，开关电极间场增强因子变大，开关分散性减小，但平均自击穿电压有所降低。     

NaIO4-H2O2 流动注射化学发光法测定天然水中硒的研究

建立了一种简易、快速检测天然水中痕量硒的流动注射化学发光法。该法基于NaIO4-H2O2(pH 7.0)氧化Se(0)生成Se(Ⅳ)所产生O*的化学发光,发光强度与一定浓度范围内的Se呈线性关系,加入环己烷和Triton-100能增强这一体系的发光强度。该法测定Se的线性范围为1.0×10-7~1.0×10-5mol.L-1,检测限为4.2×10-8mol.L-1,对4.0×10-7mol.L-1的Se进行测定的RSD为3.5%(n=8)。用该法对天然水体中Se进行了测定,结果满意。