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排序方式: 共有993条查询结果,搜索用时 203 毫秒
121.
In this investigation, a facile sonochemical route has been developed for the preparation of silver vanadium oxide (SVO) micro/nanorods by using silver salicylate and ammonium metavanadate as silver and vanadate precursor, respectively. Here, silver salicylate, [Ag(HSal)], is introduced as a new silver precursor to fabricate AgVO3 nanorods. The effect of numerous solvents and surfactants on the morphology and sonochemical formation mechanism of AgVO3 nanorods was studied. AgVO3 nanorods were characterized by SEM and TEM images, XRD patterns, FT-IR, XPS, and EDS spectroscopy. SEM, TEM, and XRD results showed that AgO nanoparticles were formed onto AgVO3 nanorods in the presence of ethanol, cyclohexanol, dimethylsulfoxide (DMSO), and acetone. By using polyethylene glycol (PEG-6000) and N,N-dimethylformamide (DMF) as organic additives, the thickness of AgVO3 nanorods decreased. 相似文献
122.
Davar M. Boghaei Fatemeh Behzadian-Asl Hamid Reza Khavasi 《Journal of chemical crystallography》2008,38(4):311-314
Abstract The chemical preparation and crystal structure for a 4,4′-azodi(phenylcyanamide) salt) in the solid state are reported. This
compound crystallizes in the triclinic space group P
with the following unit cell parameters: a = 9.759(3) ?, b = 11.237(4) ?, c = 11.919(4) ?, α = 95.54(3)°, β = 98.50(3)°, γ = 109.39(2)°, Z = 1 and V = 1204.4(7) ?3. The 4,4′-azodi(phenylcyanamide) dianion, azodicyd2−, is approximately planar, with the cyanamide groups (–N=C=N) in an anti conformation relative to each other and the azo group (–N=N–) adopting the more thermodynamically stable trans conformation. The crystal X-ray analysis shows that there are one azo molecule cation, two tetrabutylammonium cations and
one water molecule in unit cell. Intermolecular O–H···N hydrogen bonds may be effective in the stabilization of the crystal
structure of this compound and to form linear chain structure in the packing.
Index Abstract Synthesis and crystal structure of Bis (Tetrabutylammonium)(4,4′-Azodi(phenylcyanamide)) salt . [(n-Bu)4N]2[Azodicyd2-] · H2O
Davar M. Boghaei 1*, Fatemeh Behzadian-Asl 1 and Hamid Reza Khavasi2
1 Department of Chemistry, Sharif University of Technology, P.O. Box 11155-9616, Tehran, Iran
2 Department of Chemistry, Shahid Beheshti University, Evin, Tehran 1983963113, Iran
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
123.
Fazaeli Yousef Hosseini Mohammad Amin Shahabinia Fatemeh Feizi Shahzad 《Journal of Radioanalytical and Nuclear Chemistry》2019,320(1):201-207
Journal of Radioanalytical and Nuclear Chemistry - Porphyrins and 68Ga have emerged as novel synergic options for PET applications so the idea of preparation of a novel porphyrin complex using this... 相似文献
124.
Karami Fatemeh Ahmadi Nadooshan Afshin Westerberg Lars G. Tadi Beni Yaghoub 《Journal of Thermal Analysis and Calorimetry》2019,137(1):327-342
Journal of Thermal Analysis and Calorimetry - This study was conducted with the aim of investigating the Newtonian nanofluid flow in a catheterized tapered artery through using a completely... 相似文献
125.
126.
Syntheses and photoisomerization of the new sulfone derivatives, 4,4‐di (p‐trifluoromethylphenyl)‐2,6‐diphenyl‐4H‐thiopyran‐1, 1‐dioxide and 4‐(p‐trifluoromethylphenyl)‐2,4,6‐triphenyl‐4H‐thiopyran‐1,1‐dioxide, have been investigated. The relative molar ratios of the photoproducts are compared with those of 2,4,4,6‐tetraphenyl‐4H‐thiopyran‐1,1‐dioxide as well as electron‐donating substituted 4‐methyl‐2,4,6‐triaryl‐4H‐thiopyran‐1,1‐dioxides as model compounds under identical experimental conditions using 1H NMR spectroscopy. The results observed are discussed on the basis of a triplet excited state di‐π‐methane rearrangement. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:557–561, 2008; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20455 相似文献
127.
Khezri Behrooz Maskanati Maryam Zohrevand Bahareh Liyaghati-Delshad Mozhdeh Soltanali Fatemeh 《Structural chemistry》2022,33(2):315-322
Structural Chemistry - This is an analysis report on the use of density functional theory (DFT) to investigate the potentials of pristine and amino acid–functionalized C4B32 borospherenes in... 相似文献
128.
Mahmoud Roushani Zahra Saedi Fatemeh Hamdi Hamid Reza Rajabi 《Journal of the Iranian Chemical Society》2018,15(10):2241-2249
In this study, a new Cr(III)-imprinted polymer (Cr(III)-IIP) is prepared from CrCl3·6H2O, methacrylic acid functional monomer, ethyleneglycoldimethacrylate cross-linking agent, 2,2?-azobisisobutyronitrile radical initiator and 2,2-(azanediylbis (ethane-2,1-diyl))bis(isoindoline-1,3-dione) ligand. To obtain the maximum adsorption capacity, the optimum condition was studied through pH, type and concentration of eluent, IIP weight, sample volume as well as the adsorption and desorption times. The Cr(III) ion content was determined via flame atomic absorption spectrometer. In optimum conditions, the adsorption capacity of the IIP for Cr(III) was obtained to be 74.65 mg g?1, using 50 mg of IIP and the initial pH solution of 3.0. Both the adsorption and desorption times for quantitative analyses of Cr(III) ions were 15 and 5 min; respectively. After elution of the adsorbed ions by 3 mL of 4 mol L?1 HNO3 aqueous solution, the established IIP-based SPE procedure provides a reasonable pre-concentration factor of 100. The IIP-based pre-concentration method provides a low detection limit of 1.7 µg L?1 with good repeatability (RSD?=?3.22%). Reusability studies confirmed that synthesis IIP is reusable and recoverable up to six cycles. According to the selectivity experiments, it was concluded that the prepared sorbent possesses more affinity toward Cr(III) ions than other ions such as Al3+, Pb2+, Cu2+, Mn2+, Fe2+, Zn2+, and Ni2+ ions. To evaluate the potential applicability of the proposed separation method, the pre-concentration and determination of trace amounts of Cr(III) were performed successfully in food samples with complex matrices, a bestial sample (i.e. cow liver) and an herbal product (i.e., broccoli) as real samples. 相似文献
129.
A mixed CuI/CuIIcatalyst based on magnetic cysteine functionalized graphene oxide (CuI/II@Cys-MGO) was prepared and used for the azidonation reaction of aryl boronic acids and one-pot synthesis of 1,4-diaryl −1,2,3-triazoles. Aryl azides were obtained in good yields and short reaction times via cross-coupling of aryl boronic acids with sodium azide in the presence of CuII catalytic species in this catalytic system. The azide-alkyne cycloaddition reaction was catalyzed by CuI catalytic species in CuI/II@Cys-MGO nanocomposite. 相似文献
130.
Fatemeh Jafari Mehmandoost-Khajeh-Dad Ali Akbar Mohammadi-Dadkan Maysam Ghal-Eh Nima Yazdandoust Hamideh 《Physics of Particles and Nuclei Letters》2019,16(6):761-767
Physics of Particles and Nuclei Letters - Plastic scintillators are widely used in detecting nuclear radiation due to their low construction cost, the ability to be produced in nearly any shape and... 相似文献