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Atomic simulations using embedded atom method (EAM) are performed for Cu (100) nanobelts to study the structural and mechanical behaviour. Cu (100) nanobelts are along[001] taken as the z-axis and have a rectangular cross section in the x - y plane, with [100] and [010] taken as x and y axes. The periodic boundary is used along the z-axis to simulate an infinitely long nanobelt, and other surfaces are free. The simulations are carried out under the mechanical loading with an elongation strain rate of 8.0×10^8 s^-1 along the z-axis. The results show that the nanobelt undergoes a transition from the initial structure with a (100) axis and {100} lateral surfaces to a new structure with the (112) as the z-axis and the lateral surfaces are {111} and {110} respectively, instead of the original {100} surfaces. The mechanism of the structural transition is ascribed to the dislocation propagation through the nanobelt under the external stresses. 相似文献
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建立以大体积进样(250μL)–离子色谱测定水中溴酸盐(BrO_3~–)的方法。采用Ag柱离线去除样品中大量Cl~–以消除Cl~–干扰,同时保证痕量溴酸盐未沉淀,过滤后直接进样测定。BrO_3~–的质量浓度在2.0~25.0μg/L范围内与色谱峰面积呈良好的线性关系,线性相关系数r=0.999 2,方法检出限为0.8μg/L。自来水和矿泉水样品3浓度水平加标回收率为85.0%~101.0%,测定结果的相对标准偏差为3.6%~12.9%(n=6)。该方法样品处理简单,检出限低,准确度和精密度高,满足分析测试的要求。 相似文献
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液相色谱-质谱分析中的基质效应 总被引:12,自引:3,他引:9
介绍了液相色谱-质谱(LC-MS)分析中基质效应的产生机制、来源、评定方法和消除措施.基质效应由共流出的分析物和基质的竞争以及影响接口的离子化效率所致,主要来源于生物样品中的内源性组分和样品处理后引入的杂质.不同批次的生物样品,其基质效应存在差异,可通过柱后注射法和提取后添加法2种方法评定基质效应.实例介绍了基质效应、提取回收率和整个方法过程效率的具体计算方法.基质效应可能影响LC-MS方法的灵敏度、准确度和精密度,通过样品前处理、氘代内标的使用、色谱分离、质谱分析等过程的优化可有效消除基质效应. 相似文献
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A pixel array CdZnTe imaging system, employing a 40 × 40× 5 mm^3 pixellated CdZnTe detector, is established. The imaging polarization effect in the CdZnTe pixellated detector for a collimated CS137 Gamma source is investigated in detail. The experimental results for different irradiated fluxes indicate that excessive irradiated flux indeed causes central pixels to be shut off completely. The imaging performance of the polarized detector is severely degraded. Polarized detector counts are simultaneously reduced to one-third of the non-polarized detector counts. A theoretical model of potential distribution is also proposed by solving the Poisson equation and, in turn, the electric potential distortion for high irradiated flux is discussed by comparison with the experimental results. 相似文献
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建立了用交联羧甲基魔芋葡甘聚糖(CCMKGM)作为微柱预富集填料,分离富集-GFAAS测定环境水样中痕量铅、镉和铜的新方法。研究了溶液酸度、样品的流速和体积、洗脱剂的浓度和体积、共存离子等对CCMKGM微柱吸附重金属离子的影响。结果表明:在pH为5.0~7.0的条件下,三种重金属离子可定量吸附在CCMKGM微柱上;采用1.0 mL 0.5 mol·L-1的盐酸溶液可将吸附在CCMKGM微柱上的铅、镉和铜定量洗脱。Pb2+, Cd2+, Cu2+的检出限(3σ)分别为0.038, 0.000 5和0.014 μg·L-1,相对标准偏差(RSD)分别为3.5%, 9.2%和4.7%(初始浓度cPb2+ =cCu2+=1.0 μg·L-1, cCd2+=0.1 μg·L-1,n= 11),富集倍数50。将该法用于环境标准样品的测定,测得值与标准值相符。 相似文献
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一类非牛顿流体流动问题的变分原理和广义变分原理 总被引:1,自引:1,他引:0
本文将钱伟长教授[1]的不可压缩粘性流的最大功率消耗原理推广到一类特殊的非牛顿流体─-广义牛顿流体的流动问题,并采用识别的拉氏乘子法来解除变分约束条件,导出其广义变分原理。 相似文献
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