ICP-AES直接测定土壤、沉积物中常、微量元素的光谱干扰和校正方法研究

本文研究了感耦等离子体原子发射光谱(ICP-AES)法直接测定土壤、沉积物中常、微量元素的光谱干扰,以及用多元光谱拟合(MSF)校正的方法.讨论了积分时间及谱线漂移对MSF法的影响.比较了离峰扣背景法与MSF法的效果,对水系沉积物GBW07306测定结果表明,MSF法得出的结果更接近推荐值,且其检出限及相对标准偏差比离峰扣背景法分别改善了1.3～9.0倍和1.1～4.9倍.     

钙钛矿透氧膜材料中金属离子价态的化学测定

建立了钙钛矿材料中金属离子的碘滴定分析方法,并通过该方法对BaCe0.1CoxFe0.9-xO3-δ和BaZr0.1CoxFe0.9-xO3-δ钙钛矿透氧膜材料中钴铁离子价态进行了测定.研究表明,随着钴含量的增加,钴铁离子的平均价态呈下降趋势,这意味着氧空位浓度也在随之增加.对比发现在相同掺杂比例时(x),BaCe0.1CoxFe0.9-xO3-δ体系中钴铁离子的平均价态要低于BaZr0.1CoxFe0.9-xO3-δ系列中钴铁离子的平均价态,因此BaCe0.1CoxFe0.9-xO3-δ系列比BaZr0.1CoxFe0.9-xO3-δ系列拥有更多氧空位数.     

Experimental investigation of loss and gain characteristics of an abnormal In_xGa_(1-x)As/GaAs quantum well structure

In this Letter, the loss and gain characteristics of an unconventional InxGa1-xAs∕Ga As asymmetrical step well structure consisting of variable indium contents of InxGa1-xAs materials are measured and analyzed for the first time, to the best of our knowledge. This special well structure is formed based on the indium-rich effect from the material growth process. The loss and gain are obtained by optical pumping and photoluminescence(PL)spectrum measurement at dual facets of an edge-emitting device. Unlike conventional quasi-rectangle wells, the asymmetrical step well may lead to a hybrid strain configuration containing both compressive and tensile strains and, thus, special loss and gain characteristics. The results will be very helpful in the development of multiple wavelength In Ga As-based semiconductor lasers.     

生物转盘高效脱氮的实验研究

采用单轴三级生物转盘(RBC),在水力停留时间(HRT)为5、8、12h时,总氮(TN)去除率分别为30.94%、51.52%、58.67%。证明了生物转盘具有同步硝化反硝化的功能。增加硝化液回流系统后,在温度为15℃、回流比为200%时,TN去除率为74.57%。改变转盘的转速及水温,在试验中水温30℃、生物转盘转速10r/min时,转盘对TN的去除率达到最大值为85.35%。实验结果表明,生物转盘在污水脱氮上有较好的应用前景。     

基于坐标变换的斜角切削力学研究

在直角切削模型的基础上,首先将在法平面坐标系中得到的切削力通过坐标变换得到主剖面坐标系中的切削力;再把主剖面坐标系中的切削力利用坐标变换得到切深-进给平面中的切削力理论公式。通过坐标变换得到的切削力理论公式更简洁,物理意义清晰,并能反映出切削偏角对切削力的影响。通过对数值计算与数值仿真两种方法模拟得到的切削力进行比较,得出两者的误差率在8.3%~15.7%,说明两者具有良好的一致性,从而证明了模型的正确性。斜角切削力的理论公式为实际切削加工中切削力的解析预测奠定了基础。     

单根锑掺杂ZnO微米线热电发电机的制备及热电性能

采用化学气相沉积(CVD)方法,在无催化剂的条件下,生长出了锑掺杂的超长、大尺寸ZnO微米线。测试表明微米线的平均长度可达1~2.5 cm,微米线中锑元素的含量约为3.1%(n/n)。此外,将挑选出的单根锑掺杂ZnO微米线以银浆为电极制作成热电发电机,并研究了微米线长度和微米线直径对器件输出性能的影响。研究表明当器件两电极之间的温差为20 K且两电极间微米线的长度为1.6 cm时,器件能够输出的最大电压和最大输出功率分别约为36 m V和10.8 n W,微米线的赛贝克系数约为-1.80 m V·K-1。此外,热电器件的输出电压随着微米线长度的增加而增大,随微米线直径的增加而减小。     

高转速下采用S-RESIDOR方法测量1H-27Al偶极偶合常数

提出利用S-RESIDOR(Symmetry-based Resonance Echo Saturation Irradiation DOuble Resonance)方法测量¹H-²⁷Al偶极偶合常数. 通过理论模拟,讨论了四极作用常数、饱和照射脉冲功率、照射时间对¹H/²7Al S-RESIDOR实验的影响. 发现四极作用常数对¹H/²⁷Al S-RESIDOR偶极去相曲线影响较小,中等强度的饱和照射功率即能满足实验要求. 高转速下,在氢型丝光沸石上进行了¹H/²⁷Al S-RESIDOR实验,测量得到Br-nsted酸位上的 ¹H与骨架上²⁷Al的偶极偶合常数为874 Hz.     

Beam halo experiment at IHEP

Space-charge forces acting in mismatched beams have been identified as a major cause of beam halo. In this paper,we describe the beam halo experimental results in a FODO beam line at IHEP. With this beam transport line, experiments are carried out to compare the measured data with the multi-particle simulations and to study the formation of a beam halo. The maximum measured amplitudes of the matched and mismatched beam profiles agree well with simulations. Details of the experiment are presented.     

Modified read-out system of the beam phase measurement system for CSNS

The customized beam phase measurement system can meet the requirement of beam loss control of the radio-frequency quadrupole (RFQ). However, its read-out part cannot satisfy the requirement of China Spallation Neutron Source (CSNS). CSNS uses the Experimental Physics and Industrial Control System (EPICS) as its control system. So it is necessary to develop the EPICS read-out system consisting of EPICS IOC databases, driver support and OPIs. The new system has been successfully tested in the RFQ. In the future, it will be applied to the beam diagnostics of CSNS.