上新世华山松化石中的甾体化合物

从上新世华山松(Pliocene Pinus armandii)化石木中分离鉴定了5个甾体成分: 24ξ-n-丙基-胆甾烷-3-酮(1), 豆甾 烷-3-酮(2), 24α-乙基-3α-胆甾醇(3), 4-豆甾烯-3-酮(4)和3β-谷甾醇(5). 化合物1为一个新的C₃₀甾体. 它们的结构由波谱方法鉴定.     

碳纳米纤维负载铁钴镍硼化物可控制备及其电催化析氢性能研究

通过乙醇催化燃烧法制备了碳纳米纤维（CNFs），采用化学沉积法在CNFs载体上负载铁钴镍硼化物（FeCoNiB），并以多种测试手段对其表征，研究了化学沉积工艺条件对FeCoNiB粒径、分散、成分及结构的影响，建立了碳纳米纤维负载的铁钴镍硼化物（FeCoNiB/CNFs）可控制备方法。采用电化学测试手段研究了FeCoNiB/CNFs在碱性环境下的氢气析出反应（HER）催化性能。结果表明，在100 mA/cm²的电流密度下，FeCoNiB/CNFs的过电位仅为366 mV，塔菲尔斜率低至41 mV/dec；在持续10 h的稳定性测试中电位衰减幅度很小，基本保持不变。这说明FeCoNiB/CNFs制备成本低，但其高稳定性可媲美贵金属的高催化活性HER催化剂；该研究可为非贵金属HER催化剂的研制及低成本电解水制氢技术的规模化应用提供参考。     

求Emden-Fowler方程积分的分析力学方法

研究求Emden-Fowler方程积分的分析力学方法,包括Hamilton-Poisson方法,Lagrange-Noether方法,Lie-Hojman方法以及Hamilton-Jacobi方法等.     

A symmetry and a conserved quantity for the Birkhoff system

A symmetry and a conserved quantity of the Birkhoff system are studied. The symmetry is called the Birkhoff symmetry. Its definition and criterion are given in this paper. A conserved quantity can be deduced by using the symmetry. An example is given to illustrate the application of the result.     

Analytical mechanics methods for solving Whittaker equations

The purpose of this paper is to study the solution of the celebrated Whittaker equations by using analytical mechanics methods, including the Lagrange--Noether method, Hamilton--Poisson method and potential integral method.     

吸附剂修饰铁基氧载体的氧化动力学研究

研究了吸附剂修饰合成Fe_2O_3/Al_2O_3的氧化动力学。其中,吸附剂(K_2O、Na_2O、CaO)用于控制化学链燃烧过程中有毒氯化物、硫化物以及重金属的排放。首先在热重分析仪(TGA)上利用合成气作为还原气氛使氧载体呈还原态(FeO/Al_2O_3),在空气气氛下进行了原FeO/Al_2O_3以及三种吸附剂修饰FeO/Al_2O_3的氧化实验,实验温度分别为850、875、900和925℃。通过八种等温动力学模型对900℃下原FeO/Al_2O_3的氧化过程进行了分析。结果表明,phase boundary-controlled(contracting cylinder)模型能够很好地描述其氧化过程(FeO向Fe_2O_3转化过程)。利用该模型分别计算了原FeO/Al_2O_3、K_2O修饰FeO/Al_2O_3、Na_2O修饰FeO/Al_2O_3和CaO修饰FeO/Al_2O_3的氧化动力学参数,其表观活化能分别为13.71、20.21、21.62和24.20 k J/mol。通过进行比较依据动力学参数计算得到的转化率随时间的函数以及实验获得的转化率随时间的函数,进一步证实了phase boundary-controlled(contracting cylinder)模型的可靠性以及相应动力学参数的准确性。     

Picosecond Pulse Laser Microstructuring of silicon

We report the experimental results of picosecond pulse laser microstructurlng (pulse duration 35 ps, wavelength 1.06μm, repetition rate 10 Hz) of silicon using the direct focusing technique. Arrays of sharp coldcal spikes located below the initial surface have been formed by cumulative picosecond pulsed laser irradiation of silicon in SF6. Irradiation of silicon surface in air, N2, or vacuum creates ripple-like patterns, but does not create the sharp conical spikes.     

High-Power Er^3＋／Yb^3＋ Codoped Double-Cladding Fibre Amplifier with More Than 2 W Output Power

A high-power Er^3 /Yb^3 -codoped double-cladding all-fibre amplifier was successfully demonstrated and exper-imentally investigated. The amplifier could be operated with a maximum output power of 2.18 W and 2.11 Wat 1541nm and 1550nm wavelengths, respectively, when the maximum pump power was 6.07W. The powerconversion effciency was up to 35.6% and 34.4% at the two wavelengths, respectively. The output power and the gain were greater than 2.00 W and 20.OdB, respectively, in the wavelength range from 1539nm to 1565nmfor 20.OmW input signal power. The gain fluctuation and the noise figure around 1550nm wavelength were less than 0.3 dB and 6.0 dB, respectively.     

三元P—Cu—W杂多阴离子柱撑水滑石的制备

用微波法制备了杂阴离子柱撑水滑石，经ＸＲＤ，ＩＲ，ＥＳＲ和ＤＴＡ表征，证明制备的样品具有良好的层柱结构，其热稳定性比相应的杂多酸盐提高约４０℃。杂多阴离子中Ｃｕ＾２＾＋并非处于标准的八面体场中，而是处于一种近似于五配位的立方锥场，并随嵌入层间后更趋势于民位。     

基于神经网络模型的CCD像差修正

针对传统CCD标定中由于修正像差造成标定算法复杂、精度不高、结果不稳定的特点,提出了用4层前向神经网络模型修正CCD像差的方法。为了检验算法,用修正像差后的CCD对空间点进行三维重建,并与传统方法作了对比。结果表明,基于神经网络模型的CCD像差修正方法可以获得比传统方法更高的精度和稳定性。