A simple solution-immersion process for the fabrication of superhydrophobic cupric stearate surface with easy repairable property

The present work reports a simple and time-saving method to fabricate cupric stearate film on zinc substrate by a solution-immersion process. Superhydrophobic surfaces are conventionally prepared employing two steps: roughening a surface and lowering its surface energy. The fabrication of superhydrophobic cupric stearate surface is reported using a one-step process by immersing a zinc plate coated with copper into the stearic acid solution, simplifying the complexity of two different steps involved in the conventional methods. The surface of the zinc plate coated with copper is found to be covered with low surface energy cupric stearate film providing the water contact angle of 160 ± 1° with the rolling off properties. In addition, the damaged superhydrophobic surface can restore superhydrophobicity property by immersing the surface into the stearic acid solution again.     

“曲线运动”的速度方向演示实验缺陷及改进

曲线运动的速度方向是高一物理"曲线运动"一节的教学难点,教材试图通过"砂轮"和"转伞"的实例加以说明.可是很多学生没见过用砂轮磨刀具时形成的火星是何形状,课堂上演示此实验,既不现实,也不安全.     

Dirichlet空间上的循环复合算子

该文主要证明了在Dirichlet空间上由复合算子{C\-φ:φ∈Aut(D)}生成的代数为循环算子代数;同时对任意的解析映射φ:D→D,C\-φ都不可能为超循环算子给出了证明.     

用于高功率激光装置中的电脉冲整形系统

采用射频GaAs场效应管和微带传输线技术,研制出用于高功率激光装置中的电脉冲整形系统.该系统电脉冲整形宽度为3.5 ns,幅度在0~5 V范围内调节,时域调整精度200 ps.整形后的方波,前沿383 ps,后沿642 ps,顶部不平坦度4~5%,波形幅度稳定性4~5%（p-p).利用该系统产生的整形电脉冲驱动电光波导调制器进行激光脉冲整形,得到了理想的整形激光脉冲.     

算子值酉随机矩阵及其渐近自由性

该文在算子值非交换概率空间上引入半标准酉随机矩阵的概念, 证明了它是算子值Haar酉元的矩阵模型,并给出了半标准酉随机矩阵的渐近自由判定定理.     

162Lu的高自旋态及A=160区双奇核晕态能级的符号因子反转

利用¹⁴⁷Sm(¹⁹F,4nγ)¹⁶²Lu反应研究了¹⁶²Lu的高自旋态. 由7个带BGO康普顿抑制的高纯锗探测器和一个小平面探测器进行了在束γ测量,首次建立了双奇核¹⁶²Lu转晕带的能级纲图. 发现在低转动频率下,¹⁶²Lu的转晕带能级发生符号因子反转. 对质量数A=160核区双音核的转晕带重新进行了分析和考察,讨论了转晕带能级符号因子反转的系统性.     

Synthesis and Biological Activity of Some Novel Aryl‐Substituted 1,3,4‐Oxadiazole Mannich Bases Containing Pyrimidine Rings

A series of novel Mannich base derivatives (E₁–E₁₅) of 5‐aryl‐1,3,4‐oxadiazole‐2‐thione with substituted pyrimidine were synthesized and characterized by elemental analysis, IR, ¹H‐NMR. The antifungal activities of these compounds were also originally studied. The results showed that most of the title compounds exhibited relatively good fungicidal activities. Especially compounds E₈ and E₁₃ showed better antifungal activity than comparison compound hymexazol. The relationship of structure and activity revealed that the presence of the methyl group at four and six positions of pyrimidine ring remarkably enhanced the antifungal activity of title compounds.     

电喷雾质谱在寡糖序列分析中的应用

选取具有不同结构特征的N-糖链、硫酸软骨素寡糖、人乳寡糖以及海洋来源的壳寡糖、褐藻胶寡糖、卡拉胶寡糖和硫酸岩藻寡糖等,对电喷雾质谱在寡糖的主链序列、分支位点、硫酸基取代位置确定、单糖组成和聚合度分析等方面的应用技术及碎片离子的断裂规律进行了总结.根据相邻同类碎片离子之间的质荷比差值可初步判断寡糖的单糖组成类型;通过与色谱分离技术联用或衍生化方法可提高寡糖的分辨率和离子化效率,并测得寡糖的分子量及聚合度;借助串联质谱及对寡糖还原端的特异性标记,可获得寡糖的还原端残基和部分序列信息;根据寡糖产生的特征碎片离子及其丰度大小可判断残基的特定位置和类型.另外,寡糖的分支通常作为一个整体发生糖苷键断裂或产生D离子,据此可判断分支点的位置;根据硫酸寡糖产生的特异性跨环断裂碎片,可以确定硫酸基的连接位置.这些规律和方法的总结为未知寡糖的结构和序列的分析提供了启发和指导.     

Silicification‐Induced Cell Aggregation for the Sustainable Production of H2 under Aerobic Conditions

Photobiological hydrogen production is of great importance because of its promise for generating clean renewable energy. In nature, green algae cannot produce hydrogen as a result of the extreme sensitivity of hydrogenase to oxygen. However, we find that silicification‐induced green algae aggregates can achieve sustainable photobiological hydrogen production even under natural aerobic conditions. The core–shell structure of the green algae aggregates creates a balance between photosynthetic electron generation and hydrogenase activity, thus allowing the production of hydrogen. This finding provides a viable pathway for the solar‐driven splitting of water into hydrogen and oxygen to develop green energy alternatives by using rationally designed cell–material complexes.