PAMPS/SiO_2杂化水凝胶的合成及电场敏感性研究

以2-丙烯酰胺-2-甲基丙磺酸(AMPS)为有机原料,正硅酸乙酯(TEOS)为无机原料,过硫酸钾为引发剂,N,N'-亚甲基双丙烯酰胺为交联剂,通过原位-凝胶水溶液聚合法合成了一系列不同二氧化硅含量和不同聚离子浓度的聚(2-丙烯酰胺-2-甲基丙磺酸)/二氧化硅杂化电场敏感性水凝胶.通过扫描电子显微镜(SEM)表征凝胶的结构,研究水凝胶在去离子水以及氯化钠溶液中的溶胀和消溶胀行为.结果表明,系列凝胶的平衡溶胀度介于224.9至325.6之间,复合凝胶的溶胀速率随TEOS用量的增加而降低;除理想杂化凝胶外,随着聚离子浓度的升高,凝胶在氯化钠溶液中的消溶胀速率逐渐减小.对凝胶的电场敏感性研究表明,当聚离子浓度大于氯化钠溶液浓度时,凝胶进一步溶胀,反之则消溶胀,其中杂化凝胶的再溶胀性能减弱,而消溶胀行为变得更为明显.同时制得的理想杂化凝胶,较纯有机凝胶具有更为理想的力学性能,最大抗压缩强度可达23.4 MPa.     

开槽管微波腔中微波场分布初步研究

开槽管微波腔已被用于铷原子频标,但是其中的微波场分布尚不清楚. 利用高频结构仿真软件(HFSS)获得了开槽管微波腔内微波场的分布,利用激光-微波双共振方法实现了微波腔场分布的实验测量,所得结果与理论结果一致. 研究结果表明,腔内微波场磁力线呈轴向分布,这表明该种微波腔是适用于原子频标的. 研究结果还表明,腔内微波场存在明显的空间不均匀性,这会导致一些区域的原子不能充分利用,限制原子的钟跃迁信号强度. 因此,现有的开槽管腔结构还有改进的余地.     

A CLASS OF COLLINEAR SCALING ALGORITHMS FOR UNCONSTRAINED OPTIMIZATON

A Class of Collinear Scaling Algorithms for Unconstrained Optimization. An appealing approach to the solution of nonlinear optimization problems based on conic models of the objective function has been in troduced by Davidon (1980). It leads to a broad class of algorithms which can be considered to generalize the existing quasi-Newton methods. One particular member of this class has been deeply discussed by Sorensen (1980), who has proved some interesting theoretical properties. In this paper, we generalize Sorensen's technique to Spedicato three-parameter family of variable-metric updates. Furthermore, we point out that the collinear scaling three- parameter family is essentially equivalent to the Spedicato three-parameter family. In addition, numerical expriments have been carried out to compare some colliner scaling algorithms with a straightforward implementation of the BFGS quasi-Newton method.     

AN IMPROVEMENT ON UNCONSTRAINED CONVEX PROGRAMMING APPROACH TO LINEAR PROGRAMMING

For satate form linear gram as Fang and sao deined and approach which would find an optimal solution by solving an anconstrained convex dual programming.Thedual was construcied by applying an emropic peturbation and a simple Inequality Inz0n,In this paper,we suggest than a paperbation functiontake the place of Inx such that the new approdt has good numerical stability andhas all properties of the original method     

激光抽运铷原子频标实验研究

采用饱和吸收偏振稳频半导体激光器,建立了激光抽运铷频标实验系统. 实现了该系统的闭环锁定. 进行了频率稳定度的初步测试,短期稳定度为1.2×10^-11 τ^-1/2. 对测试结果进行了分析,并提出了相应的改进措施.     

La2O3掺杂对SnO2基陶瓷显微结构与电阻率的影响

以La2O3作掺杂剂,制备了La2O3掺杂的SnO2陶瓷.采用XRD、SEM以及其它测试手段对该陶瓷进行测试.结果表明:掺入适量的La2O3能够降低SnO2基陶瓷电阻率,促进SnO2晶相的形成和生长,对SnO2基陶瓷的致密化起到良好的作用.     

铷原子频标鉴频信号信噪比相关问题分析

频率稳定度是铷原子频标最重要的性能指标. 铷频标频率稳定度主要由原子鉴频信号的信噪比决定. 本文分析了微波腔的结构、铷光谱灯的光谱纯度和同位素滤光方案对信噪比的影响,指出采用模式优越、微波填充因子大的微波腔,光谱纯度高的铷光谱灯,用分离滤光方法进行同位素滤光,可以提高铷原子鉴频信号的信噪比,从而使铷频标的稳定度指标得到进一步改善.      

镧与Sn-Pb合金体系中组元的相互作用关系

采用二元系Ｍｉｅｄｅｍａ生成热模型及其Ｔａｎａｋａ过乘熵修正和三元系Ｃｈｏｕ几何模型分析了稀土元素Ｌａ与Ｓｎ－Ｐｂ软钎料合金体系中组元元素的相互作用关系,热力学计算表明,在Ｓｎ－Ｐｂ合金体系中,Ｌａ具有“亲Ｓｎ”倾向。这是添加稀土元素Ｓｎ－Ｐｂ软钎料合金金属学性能的一个基本前提 。     

Effect of Calcination Temperature on Catalytic Activity and Textual Property of Cu/HMOR Catalysts in Dimethyl Ether Carbonylation Reaction

The effect of calcination temperature on the catalytic activity for the dimethyl ether (DME) carbonylation into methyl acetate (MA) was investigated over mordenite supported copper (Cu/HMOR) prepared by ion-exchange process. The results showed that the catalytic activ-ity was obviously affected by the calcination temperature. The maximal DME conversion of 97.2% and the MA selectivity of 97.9% were obtained over the Cu/HMOR calcined at 430 oC under conditions of 210 oC, 1.5 MPa, and GSHV of 4883 h^-1. The obtained Cu/HMOR catalysts were characterized by powder X-ray diffraction, N₂ absorption, NH₃ temperature program desorption, CO temperature program desorption, and Raman techniques. Proper calcination temperature was effective to promote copper ions migration and diffusion, and led the support HMOR to possess more acid activity sites, which exhibited the complete decomposing of copper nitrate, large surface area and optimum micropore structure, more amount of CO adsorption site and proper amount of weak acid centers.     

一类三角级数的收敛性

利用Euler公式求三角级∞∑m=1 sinmx/n与∞∑m=1 cosmx/m的和函数并讨论其一致收敛性.