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991.
A combination of a DNA ligase and a restriction endonuclease provides a DNA polymerase activity, which might suggest a novel strategy for polymer synthesis. 相似文献
992.
Using the mixture of cetyltrimethylammonium bromide (CTAB) and p‐Octyl polyethylene glycol phenyl ether (OP‐10) as templates, siliceous MCM‐48 materials can be synthesized with low molar ratio of CTAB to silica (0.139:1) and low concentration of mixed surfactants (ca.5%) and within a wide range of OP‐10/CTAB ratio (0.08?0.25). The materials were characterized by X‐ray powder diffraction, N2 adsorption/desorption isotherm, TEM, TG‐DSC and 29Si MAS NMR. Measurements indicated that the use of mixed surfactants allowed better condensation and higher ordering of the cubic mesostructure; at the same time, some properties of these materials were sensitive to the OP‐10/CTAB ratio. It was also found that the reduced pH of the gel which had been crystallized for a certain time gave a highly reproducible synthesis with a high silica yield (about 95%). Furthermore, the reaction mechanism of the synthesis is discussed in detail. 相似文献
993.
岩,心是油气储层的基本单元,其内部结构和渗流性质反映了油藏的基本特征.岩。心的精细描述是油藏描述、储层动态监测及设计强化采油方案的重要基础.本文利用核磁共振(NMR)自旋密度做成像,快速无损地观测到两类基本储油岩石——砂岩和灰岩的内部结构,提供了岩石渗透性、孔隙性及灰岩沉积环境等重要信息.1实验方法以自旋回波单片NMR成像脉冲序列为基础,设。P平面内样品的目施密度为P(。,v).演化期t。,在。方向梯度场G。作用下,各处横向磁化矢量获得的相移为式中,7为共振核(在成像中一般为质子)的旋磁比,g为坐标位置·… 相似文献
994.
磷酸铝类分子筛是近年来继Y型和ZSM七分子筛之后的第三代合成分子筛材料,其骨架由A10。和P0。四面体均匀交替地组成问.由于带负电行的A10。和带正电荷的PO。四面体数目相等,整个骨架呈电中性,所以这类分子筛本身无离子交换能力和催化活性.当用硅或某些金属离子(如Mg、Fe、Co、Zn等)对磷酸铝分子筛进行同晶取代,就会在骨架上造成电行不平衡,从而使这类分子筛具有一定的离子交换能力和酸性【习.因而对硅或金属离子在磷酸错类分子筛中取代机理的研究一直是人们感兴趣的问题问.Vpl-5是最近才合成出来的具有18圆环一维孔结构的… 相似文献
995.
Xin‐Zhou Yang Li‐Gen Lin Chun‐Ping Tang Yong‐Qiang Liu Yang Ye 《Helvetica chimica acta》2007,90(2):318-325
Five new nonalkaloid constituents, a neolignan, japonin A ( 1 ), a macrocyclic lactone, japonin B ( 2 ), a (phenylethyl)benzoquinone, japonin C ( 3 ), a phenanthraquinone, japonin D ( 4 ), as well as a dihydrostilbene, stilbostemin M ( 5 ), were isolated from the roots of Stemona japonica, together with eight known compounds. Their structures were established by spectroscopic analyses. 相似文献
996.
Ramiro Pino Olivier Bokanowski Eduardo V. Ludeña Roberto López Boada 《Theoretical chemistry accounts》2007,118(3):557-561
Bearing in mind the insight into the Hohenberg–Kohn theorem for Coulomb systems provided recently by Kryachko (Int J Quantum
Chem 103:818, 2005), we present a re-statement of this theorem through an elaboration on Lieb’s proof as well as an extension
of this theorem to finite subspaces.
Contribution to the Serafin Fraga Memorial Issue. 相似文献
997.
Sergeev G. B. Smirnov V. V. Rostovshchikova T. N. Komissarova N. V. Indoleva Ye. V. 《Tetrahedron》1987,43(24):5853-5863
Complexes and reactions of 2-methylbutene-2 with hydrohalogen (HCl, HBr) have been studied in solid phase at 80–150 K. It has been found that 2-methylbutene-2 forms with HX complexes of 1:1 and 1:2 composition. Hydrohalogenation proceeds via the rearrangement of complex 2HX·C5H10 into complex of the addition product with HX. Kinetic equation depends on the reagents ratio. In excess of HX (1< HX:C5H10< 10) reaction can be described by the first order kinetic equation. If the ratio HX:C5H10 is more than 10, reaction is described by polychronous kinetic law. The effective activation energy of solid phase hydrohalogenation does not exceed 20 kJ/mole. The molecular mechanism of hydrohalogenation in solid phase has been proposed. 相似文献
998.
999.
Carolina A. Pinto P. M. Büchler J. Dweck 《Journal of Thermal Analysis and Calorimetry》2007,87(3):715-720
The catalyst
used in fluidized catalytic cracking (FCC) units of refineries after several
recovery cycles in regeneration units, reduces its activity and it is partially
substituted by new catalyst in the process. As it has a high silicon and aluminum
oxides content, the pozzolanic properties of a Brazilian FCC spent residual
catalyst, used in different substitution degrees to cement, were evaluated
by three thermal analysis techniques during the early stages of hydration
of a type II Portland cement. NCDTA curves show in real time that the residual
catalyst, accelerates the stages of cement hydration. TG and DSC curves of
respective pastes after 24 h of hydration evidence the pozzolanic activity
of the waste, respectively, by the lower water mass loss during the dehydroxylation
of the residual calcium hydroxide and by the lower dehydroxylation endothermal
effect. Within the analyzed period, the higher is the cement substitution
degree, the higher is the pozzolanic activity of the residual catalyst. 相似文献
1000.
Changlun Chen Di Xu Xiaoli Tan Xiangke Wang 《Journal of Radioanalytical and Nuclear Chemistry》2007,273(1):227-233
The fate and transport of toxic metal ions and radionuclides in the environment is generally controlled by sorption reactions.
The extent of sorption of divalent metal cations is controlled by a number of factors including cosorbing or complexing. In
this work, the effects of pH, humic acid HA/Co(II) addition orders, ionic strength, concentration of HA, and foreign cations
on the Co(II) sorption on γ-Al2O3 in the presence of HA were investigated. The sorption isotherms of Co(II) on γ-Al2O3 in the absence and presence HA were also studied and described by using S-type sorption model. The experimental results showed
that the Co(II) sorption is strongly dependent on the pH values, concentration of HA, but independent of HA/Co(II) addition
orders, ionic strength, and foreign cations in the presence of HA under our experimental conditions. The results also indicated
that HA enhanced the Co(II) sorption at low pH, but reduced the Co(II) sorption at high pH. It was hypothesized that the significantly
positive influence of HA at low pH on the Co(II) sorption on γ-Al2O3 was attributed to strong surface binding of HA on γ-Al2O3 and subsequently the formation of ternary surface complexes such as ≡S-OOC-R-(COO−)
x
Co2−x
. Chemi-complexation may be the main mechanism of the Co(II) sorption on γ-Al2O3 in the presence of HA. 相似文献