Self-Assembly of Macrocyclic Boronic Esters Bearing Tellurophene Moieties and Their Guest-Responsive Phosphorescence

Guest-controlled diastereoselective self-assembly of a diboryltellurophene and a chiral tetrol bearing an indacene backbone was achieved to give either hetero- or homochiral macrocyclic boronic esters, selectively. The heterochiral isomer (hetero-[2+2]^Te) exhibited a higher inclusion ability for electron-deficient aromatic guests, leading to effective quenching of phosphorescence from the diboryltellurophene moieties. The reported macrocycles collectively represent a promising arene sensing approach based on phosphorescence.     

例说"过度理想化"

在中学物理教和学中,"理想化"是研究问题必不可少的思维方式和操作手段.新课伊始,教材就提出质点模型,开启了一个理想化的教学阶段,它代表的是实物模型,如后来强调的"点电荷"、"理想气体"等等.应该注意到我们同样也依赖着过程理想化模型,如简单的"匀变速直线运动",因为要"在任何相等的时间内速度变化相等",你做得到吗?气体完全的"等温过程",你找得到吗?实际上我们还使用着环境理想化模型,如地球表面附近的重力加速度大小方向都相同,出了一个"匀强的引力场",到后来就有"匀强电场"、"匀强磁场"与大家反复相见等等.     

KT1202事故转子的强度计算及模拟试验分析

本文对ＫＴ１２０２事故转子做了详细、全面的强度及有限元计算分析，在大量方案计算比较及模拟试验的基础上，找到了事故处理的方法。修复后的转子经二年多的运行实践检验，证明该方法是有效且成功的，为国家带来了巨大的经济效益。     

UiO-66/CoSO4复合材料对环境中盐酸左氧氟沙星的高效去除

以UiO-66为前驱体制得UiO-66/CoSO₄复合材料，借助扫描电子显微镜、透射电子显微镜、元素分析和比表面积分析等手段对复合材料的微观形貌和结构进行表征，采用吸附平衡实验，系统考察该复合材料的吸附性能.结果表明，在相同条件下UiO-66/CoSO₄复合材料比UiO-66对盐酸左氧氟沙星的去除率提高26.5%，且复合材料在30 min对盐酸左氧氟沙星的吸附达到平衡，最大吸附容量为108.4 mg·g^-1，其吸附特性符合假二级动力学模型.该UiO-66/CoSO₄复合材料制备过程简单，对实际环境水样和土样中盐酸左氧氟沙星的去除率在94.7%以上，且经过5次再生循环使用后，吸附效率无明显下降.     

THE HYDROSILYLATION REACTION OF LADDERLIKE POLYVINYLSILSESQUIOXANE WITH 1, 1, 3, 3-TETRAMETHYLDISILOXANE

The hydrosilylation reaction of ladderlike polyvinylsilsesquioxane (Vi-T)with 1, 1, 3, 3-tetramethyldisiloxane (H- MM ) catalyzed by dicyclopentadienyl-dichloroplat-inium (Cp_2PtCl_2) was carried out well in tetrahydrofuran (THF) to produce a soluble whitesolid. This product was characterized by IR, ~1H-NMR, ~(13)C-NMR, ~(29)Si-NMR, DSC, X-raydiffraction method, gel permeation chromatography (GPC), vapour pressure osmometry(VPO), atomic force microscopy (AFM) and molecular simulation. These results provethat the product contains nanoscale tubular structure.     

Synthesis and insecticidal bioactivities of 2,3-dihydroimidazo[1,2-a]pyridin-5(1H)-one derivatives

A novel synthesis of 2,3-dihydroimidazo[1,2-a]pyridin-5(1H)-one, and insecticidal derivatives were described.     

Convenient access to functionalized vinylcyclopentenols from alkynyloxiranes

Beta,gamma-alkynyl aldehydes, generated in situ by treatment of alkynyloxiranes with a catalytic amount of Sc(OTf)3 or BF3.OEt2, are effectively trapped by a variety of allyl nucleophiles to afford homopropargylic homoallylic alcohols in good yield and selectivity. Such products are used as substrates for the synthesis of functionalized vinylcyclopentenols via enyne metathesis.     

Efficient Circularly Polarized Electroluminescence from Achiral Luminescent Materials**

Circularly polarized electroluminescence (CP-EL) is generally produced in organic light-emitting diodes (OLEDs) based on special CP luminescent (CPL) materials, while common achiral luminescent materials are rarely considered to be capable of direct producing CP-EL. Herein, near ultraviolet CPL materials with high photoluminescence quantum yields and good CPL dissymmetry factors are developed, which can induce blue to red CPL for various achiral luminescent materials. Strong near ultraviolet CP-EL with the best external quantum efficiencies (η_exts) of 9.0 % and small efficiency roll-offs are achieved by using them as emitters for CP-OLEDs. By adopting them as hosts or sensitizers, commercially available yellow-orange achiral phosphorescence, thermally activated delayed fluorescence (TADF) and multi-resonance (MR) TADF materials can generate intense CP-EL, with high dissymmetry factors and outstanding η_exts (30.8 %), demonstrating a simple and universal avenue towards efficient CP-EL.     

On formulas for Dedekind sums and the number of lattice points in tetrahedra

This paper explores a simple yet powerful relationship between the problem of counting lattice points and the computation of Dedekind sums. We begin by constructing and proving a sharp upper estimate for the number of lattice points in tetrahedra with some irrational coordinates for the vertices. Besides providing a sharper estimate, this upper bound (Theorem 1.1) becomes an equality (i.e. gives the exact number of lattice points) in a tetrahedron where the lengths of the edges divide each other. This equality condition can then be applied to the explicit computation of the classical Dedekind sums, a topic that is the central focus in the second half of our paper. In this half of the paper, we come up with a number of interesting results related to Dedekind sums, based on our upper estimate (Theorem 1.1). Among these findings, Theorem 1.9 and Theorem 1.10 deserve special attention, for they successfully generalize two of Apostol's formulas in [T.M. Apostol, Modular Functions and Dirichlet Series in Number Theory, Springer-Verlag, New York, 1997], and also directly imply the famous Reciprocity Law of Dedekind sums.     

灰树花β-葡聚糖的高效凝胶渗透色谱行为

以4种不同蛋白质含量的灰树花β-1,3/1,6-葡聚糖 (GF1,GF2,GF3,GF4) 和1种α-1,4/1,6-葡聚糖 (P100)为研究对象,探讨了它们在不同盐浓度和不同pH下的高效凝胶渗透色谱(HPGPC)行为。结果表明：灰树花β-葡聚糖相对分子质量在低于0.025 mol/L的氯化钠溶液中急剧降低,在0.1~0.2 mol/L的氯化钠溶液中趋于平稳。在pH 3~6时,其相对分子质量随pH增加而急剧增加;在pH 6~9范围内变化较小;pH高于9后又稍微增加。在相同条件下,α-1,4/1,6-葡聚糖的相对分子质量不受盐浓度和pH值变化的影响。灰树花β-葡聚糖在水溶液中可形成超螺旋结构,该结构受溶液盐浓度和pH值变化的影响,导致分子聚集状态不同,从而呈现不同的凝胶渗透色谱行为,表现为相对分子质量升高或降低。