共轴球面光学系统的热象差分析

本文系统分析了径向均匀温度场中,热对共轴球面光学系统的影响,得到了初级位置热象差与初级倍率热象差的一般表达式.在此基础上得到了均匀温度场中薄透镜系统的热象差表示式,该热象差表示可以用来指导无热象差光学系统的设计.最后根据上述分析,讨论了几种简单系统的热效应与无热象差设计途径.     

Design Rules for Two-Dimensional Organic Semiconductor-Incorporated Perovskites (OSiP) Gleaned from Thousands of Simulated Structures**

Two-dimensional (2D) halide perovskites are an attractive class of hybrid perovskites that have additional optoelectronic tunability due to their accommodation of relatively large organic ligands. Nevertheless, contemporary ligand design depends on either expensive trial-and-error testing of whether a ligand can be integrated within the lattice or conservative heuristics that unduly limit the scope of ligand chemistries. Here, the structural determinants of stable ligand incorporation within Ruddlesden-Popper (RP) phase perovskites are established by molecular dynamics (MD) simulations of over ten-thousand RP-phase perovskites and training of machine learning classifiers capable of predicting structural stability based solely on generalizable ligand features. The simulation results show near-perfect predictions of positive and negative literature examples, predict trade-offs between several ligand features and stability, and ultimately predict an inexhaustibly large 2D-compatible ligand design-space.