β－甲基地高辛药物中有关物质的检测

报道了用高效液相色谱法检测β－甲基地高辛中的有关物质。色谱条件：色谱柱用ＳｐｈｅｒｉｓｏｒｂＣ_（１８），１０μｍ，４．６ｍｍ×１５０ｍｍ，检测波长２１８ｎｍ，流动相：乙腈－水（３４：６６）。检测结果提示，目前的精制工艺需进一步改进。     

La[B5O8(OH)(H2O)]NO3•2H2O的合成与结构

采用熔融硼酸法合成了一种具有层状结构的新型水合稀土多硼酸盐, La[B₅O₈(OH)(H₂O)]NO₃•2H₂O, 并利用单晶X射线衍射技术确定了它的结构. 它属于单斜晶系, P21/n空间群. 其基本构建单元 (fundamental building block, 简称FBB)是由三个BO4和两个BO3基团所构成的一个双三元环[B5O12]基团. 结构中每一个FBB通过共顶点氧原子与周围四个同样的单元连接成具有九元环窗口的二维[B5O10]层, La³⁺位于九元环中心附近. [B5O10]层沿着b方向进行堆积, 硝酸根离子和结构中部分结晶水分子位于相邻的[B5O10]层之间.     

硝酸肼的量热研究

用精密自动绝热量热计测定了在220 K—370 K温度范围内硝酸肼的热容、熔化热、熔化温度和熔化熵。所得热容数据的精密度以百分偏差的均方根值表示为±0.2％。三次熔化热测定的相对偏差为±0.1％。为验证结果的可靠性, 用该装置测定了冰的熔化热和熔化温度, 其结果与文献值一致; 又用法国SETARAM公司的高温量热计测定了硝酸肼的熔化热和熔化温度, 其结果与我们用量热法测定的结果一致; 从量热结果计算出了该试样的纯度, 该结果亦与化学分析的结果一致。这些均可说明我们所测得的数据是可靠的。     

Thermal Decomposition Characteristics of 1,7-Diazido-2,4,6-trinitrazaheptane and its Application in Propellants

The thermal decomposition characteristics of1,7-diazido-2,4,6-trinitrazaheptane (DATH) and multi-component systems containing DATH were studied by using DSC, TG and DTG techniques. Three –NO₂ groups in the DATH molecule break away first from the main chain when DATH is heated up to 200°C. Following this process, the azido groups and the residual molecule decompose rapidly to release a great deal of heat within a short time. In the multi-component systems, DATH undergoes a strong interaction with the binder of the double-base propellant and a weak interaction with RDX. The burning rates of the two propellants were determined by using a Crawford bomb. The results showed that the burning rate rises by about 19–66% when 23.5%DATH is substituted for RDX in a minimum smoke propellant. Meanwhile, the N₂ level in the combustion gases is enhanced, which is valuable for a reduction of the signal level of the solid propellant. This revised version was published online in July 2006 with corrections to the Cover Date.     

用DSC研究纯三水铝石溶出动力学

在DSC上研究了NaOH溶液中合成三水铝石的溶出过程动力学。应用非等温反应动力学模型计算了动力学参数,分析和确定了反应机理。模型计算结果与用DSC测得的结果吻合。     

微波种子乳液聚合制备多孔乳胶粒

微波辐照下，通过间歇无皂种子乳液聚合制得聚(苯乙烯-甲基丙烯酸甲酯-丙烯酸)复合乳液，将所得复合乳液进行碱／酸分段处理，得到具有多孔结构的乳胶粒。用透射电镜对胶粒形态进行了表征。研究了酸处理初始pH值及酸处理时间对胶粒成孔的影响。     

Synthesis and biological evaluation of 3-{[4-(4-[18F]fluorophenyl)methyl] piperazin-1-yl}-methyl-1H-pyrrolo[2,3-b]pyridine for in vivo studies of dopamine D4 receptor

The compound 3-{[4-(4-[¹⁸F]fluorophenyl)methyl]piperazin-1-yl}-methyl-1H-pyrrolo[2,3-b]pyridine ([¹⁸F]3), which is an analogue of L-745,870 binding D₄ This revised version was published online in July 2006 with corrections to the Cover Date.     

氧化铝显微结构和磨损性能的研究

对种分和碳分氧化铝的显微结构以及磨损前后氧化铝显微结构进行了观察,结合氧化铝磨损指数分析发现,不同强度氧化铝的磨损性能有区别,磨损指数接近的氧化铝磨损性能有可能不同.     

钙黄绿素蓝荧光法测定食品中的微量锌（Ⅱ）

本文研究了在ＣＴＭＡＢ存在下，用钙黄绿素蓝荧光法测定食品中的微量锌（Ⅱ）的实验条件。在本实验条件下，Ｚｎ（Ⅱ）与钙黄绿素蓝生成１：１的配合物使钙黄绿素蓝的荧光增强，最大激发波长和最大发射波长分别为３５３ｎｍ和４４０ｎｍ。     

相变温度低且宽的含有胆甾烯基和反式-4-烷基环己基苯氧基的二介晶化合物

Unsymmetrical dimesogenic compounds with cholesteryl and 4-（trans-4-n-alkylcyclohexyl）phenoxy parts were synthesized by condensation of cholester-3-yl 6-bromohexanoate with appropriate 4-（trans-4-n-alkylcyclohexyl）- phenols. Structures and thermal phase behaviour of these dimesogenic compounds have been confirmed by IR, IH NMR, elemental analysis, DSC, polarity microscopy and XRD measurements. Their thermal phase behaviour was significantly different with that of other cholesterol-based dimesogens while they exhibited low and wide phase transition temperature.