液相色谱-电喷雾离子阱串联质谱同时分析烟草中的20种游离氨基酸

建立了液相色谱-电喷雾离子阱串联质谱(LC-ESI-IT-MS/MS)同时分析烟草中20种游离氨基酸的方法。烟草样品经萃取后过滤直接进样,无需进行衍生和固相萃取等其他前处理步骤。液相色谱采用HyPURITY C18反相色谱柱(200 mm×2.1 mm, 5 μm),采用1%(体积分数,下同)乙腈水溶液(含0.1%九氟戊酸)和90%乙腈水溶液(含0.1%九氟戊酸)为流动相进行梯度洗脱。结果表明,20种氨基酸的检出限(LOD)为0.01～0.05 μmol/L (S/N=3),线性相关系数均大于0.9977,峰面积测定的相对标准偏差(RSD)为0.78%～4.93%。该方法分析效率、灵敏度和选择性高,已成功应用于多种烟草样品中氨基酸的分析测定。     

k-means-RBF集成神经网络在工业尾气检测中的应用

神经网络是工业尾气检测系统的一个重要组成部分. 为提高神经网络的预测精度和收敛速度, 建立k-means-RBF集成神经网络模型. 首先, 通过选取不同的径向基函数神经网络参数, 得到一组RBF神经网络; 然后, 利用k-means算法对生成的RBF神经网络进行聚类, 并筛选出各类中精度较高的神经网络; 最后, 通过简单平均法对筛选出的神经网络进行集成, 得到高性能的k-means-RBF集成神经网络模型. 为验证模型有效性, 搭建基于k-means-RBF集成神经网络模型的工业尾气检测系统进行验证. 结果表明, 与粒子群算法优化后的Back Propagation (PSO-BP)神经网络模型相比, k-means-RBF集成神经网络模型的平均预测精度提高78.27%, 收敛时间节省99.65%     

关于铜极和锌极组成的原电池的命名

在物理化学教学中对于Zn|ZnSO_4|CuSO_4|Cu这种电池有的教师讲为丹聂尔电池有的讲为雅可比电池,同时在几本苏联译本的物理化学书中也是不一致的。如物理化学及胶体化学上册(周念祖,李存朴译),物理化学及胶体化学下册(虞宏正等译)中皆称为丹聂尔电池。而物理化学下卷(张志炳等译)物理化学     

偶边界条件下的热致暗空间光孤子

设计了偶边界条件下激发热致暗空间光孤子的实验装置，并在叶绿素丙酮溶液中进行了实验，最后阐述了暗空间光孤子的量子本质. 关键词：     

EFFECTS OF MOLECULE AGGREGATION STATE OF HINDERED PHENOL ON DYNAMIC MECHANICAL PROPERTIES OF CHLORINATED POLYETHYLENE*

Hindered phenol compound 3,9-bis{1,1-dimethyl-2[β-(3-tert-butyl-4-hydroxy-5-methylphenyl)propionyloxy]ethyl}-2,4,8,10-tetraoxaspiro[5,5]-undecane (AO-80) is a polymorphous material with different physical structures. The initial AO80 is highly crystalline, whereas AO-80 obtained by cooling from its molten state is an amorphous material. Annealing treatment below the melting point of AO-80 results in structural development. The mixture of chlorinated polyethylene (CPE) and vitrified AO-80 particles exhibits a dramatic change in the dynamic mechanical properties during heat treatment at 130℃. This change can be attributed to the decomposition of the vitrified AO-80 particles and the hybridization of two constituents. The vitrified AO-80 particles can crystallize again in a CPE matrix by annealing at 100℃, but this crystal is different from that of the initial AO-80 in its microstructure. In addition, the incorporation of CPE chains caused a dramatic increase in the modulus. As a result, the AO-80 crystal particles that contain some CPE chains act as multifunctional crosslinks and the CPE/AO-80 hybrid was found to be a new type of elastomer.     

ZnS光学双稳性器件中的不稳定性

本文首次报道ZnS干涉滤光片双稳器件中的自再生脉冲现象,并对器件产生这一不稳定性的条件和过程进行了分析及模拟计算,该器件有可能作为光学脉冲发生装置用于数字光计算研究,演示了光计算回路的逻辑功能.     

光学双稳态研究20年

综述了光学双稳态的概念和理论以及光学双稳态器件的分类和材料研究。重点介绍了半导体光双稳器件研究的发展，并且指出了光学双稳态研究的最新进展、应用前景和目前的困难。     

染料非线性标准具的光学逻辑功能

本文报道用单个充染料的非线性标准具成功地演示了五种全光学逻辑功能:与、或、与非、或非和异或。并提出了一个理论模型,根据这样模型算得的描述透射光强弛豫过程的理论曲线与实验曲线完全一致。     

Study of van Gieson''s picrofuchsin staining on second-harmonic generation in type I collagen

Second-harmonic generation （SHG） microscopy is a recently developed nonlinear optical imaging modality for imaging tissue structures with submicron resolution and is a potent tool for visualizing pathological effects of diseases. In this letter, we present our investigation on the influence of van Gieson＇s （VG） alcoholic pierofuchsin staining on SHG in type I collagen （from tendon-rich C57BL/6）. Multi-channel imaging and spectra analysis show that the strong SHG signal produced in fresh collagen type I fiber has been greatly suppressed after VG staining, which indicates that staining may induce the structural or characteristic changes of SHG-dependent crystal formed by collagen constituents, such as glycine, proline, and hydroxyproline.