一个基于N'-(3-溴-5-氯-2-羟基苯亚甲基)-3-羟基-4-甲氧基苯甲酰肼的甲基麦芽酚配位的氧钒(Ⅴ)配合物:合成、晶体结构及其胰岛素增强活性

制备了1个芳酰腙化合物:N'-(3-溴-5-氯-2-羟基苯亚甲基)-3-羟基-4-甲氧基苯甲酰肼(H₂L),并利用元素分析、红外、紫外、高分辨质谱、核磁共振氢谱和碳谱对其进行了表征。利用H₂L与甲基麦芽酚和VO(acac)₂在甲醇中反应得到了1个甲基麦芽酚配位的氧钒(Ⅴ)配合物[VO(mat)L]·MeOH。通过元素分析、红外和紫外光谱对其进行了表征,同时还研究了配合物的热稳定性。通过单晶X射线衍射进一步确认了H₂L和配合物的结构。通过对C2C12肌细胞的胰岛素模拟实验,表明该配合物能显著促进细胞对葡萄糖的利用,其细胞毒性仅为0.07 g·L^-1。     

改进的指数函数方法求时空分数阶混合(1+1)维KdV方程的新精确解

借助修正的Riemann-Liouvielle分数阶导数,采用了改进的指数函数展开法,得到了时空分数阶混合(1+1)维KdV方程的新精确解。先将时空分数阶混合(1+1)维KdV方程转化为整数阶方程;其次引入新的辅助常微分方程,得到方程在不同约束条件下的新精确解,最后对具有代表性的第一种情形下的新解进行了计算机仿真。     

结构应力耦合的微悬臂阵列

微悬臂器件被广泛应用于力学显微镜和光力学研究中,实现微悬臂之间的耦合在高精密测量和量子声子网络构建方面具有重要的应用前景。不同于通过电、磁相互作用实现微纳共振器之间耦合的方法,设计并制备了通过结构应力实现耦合的微悬臂阵列。模拟和实验结果表明,这种结构应力耦合微悬臂阵列不仅可以获得较大的耦合强度和较高的力学性能,同时悬臂之间的耦合强度也容易控制。对于其它形式的微纳共振器,同样可以利用结构应力耦合这种方法来实现共振器之间耦合的阵列。     

Transverse Zeeman background correction method for air mercury measurement

By utilizing a natural mercury lamp, the transverse Zeeman background correction method, which is used for trace mercury measurement in air, is studied. In this paper, a natural mercury lamp is used as a light source, and is placed in a 1.78-T magnetic field. The lamp emits two linearly polarized light beams σ± and π of 253.65-nm resonance line, which are used as bias light and absorbing light, respectively. A polarization modulation system is used to allow σ± and π light beams to pass through alternately with a certain frequency. A multipath optical cell with 12-m optical path is used to increase optical distance. Based on the system described above, the influence caused by UV absorbing gases, such as NO2, SO2, acetone, benzene, and O3, is analyzed. The results show that it may reduce the detection limit when the concentrations of these gases exceed 83.4 ppm, 20.3 ppm, 142.3 ppm, 0.85 ppm, and 0.55 ppm, respectively. The detection limit of the system is calculated and can achieve up to 1.44 ng/m3 in 10 minutes. Measurements on mercury sample gas and air are carded out, and the measured data are compared with the data of RA-915 mercury analyzer （Russia）. The result shows that the correlation coefficient reaches up to 0.967. The experimental results indicate that the transverse Zeeman background correction method can be used to quantify trace mercury in air with high-precision.     

双向反射分布函数绝对测量装置研制

基于太阳-漫射板+稳定性监视辐射计的星上定标方式能有效地提高遥感数据定量化水平,其中漫射板的双向反射分布函数(BRDF)定标精度是高精度星上定标的关键,BRDF绝对测量可实现漫射板的高精度定标。为解决高精度BRDF绝对测量的关键技术,设计了高亮度、高稳定度、高均匀性积分球光源;使用单色仪和单片探测器对大动态范围入射和反射辐亮度信号进行高精度探测,并利用锁相放大器对信号进行放大和采集;采用样品漫射板三维转动和三维平移及光源一维转动的组合运动形式,以高精密六轴串联机械手和中空分度盘分别作为样品漫射板和光源的定位机构,可高精度、无遮挡、快速地构建BRDF测量所需的几何关系。研制的装置可实现包括"平面外"在内的全角度BRDF绝对测量,可测量的入射、反射光束角度范围:天顶角为0°~75°、方位角为0°~360°,目前可测量的光谱范围为250~1700nm,装置的BRDF绝对测量不确定度优于1%。     

一种抑制二倍频半波孔现象的短波通设计方法

短波通滤色片是光学系统,尤其是激光系统中普遍使用的一种薄膜,它的基本结构为(0.5LH0.5L)N。但薄膜的非均质性会产生半波孔现象,从而影响滤色片的光学特性。利用导纳技术分析了折射率非均质性产生半波孔现象的原因:非均质性使常规膜系基本周期内导纳轨迹的终点偏离起点;这种偏离越大,半波孔现象就越严重。优化了常规膜系的基本周期结构,通过在高低折射率膜层之间引入导纳匹配层,使得改良后的基本周期导纳轨迹的终点与起点偏差大大减小,提高了半波处的透射率,从而提出了一种可以抑制由非均质性引起的半波孔现象的短波通设计方法,并依据实际制备工艺进行了误差分析。最终成功制备出了具有超宽透射带的短波通滤色片,实验和理论曲线具有很好的一致性。     

Development of a quasi-periodic undulator for the HLS

China's first quasi-periodic undulator (QPU) has been developed for the Hefei Light Source (HLS). It uses a magnetic configuration with varied thicknesses of NdFeB blocks, which is based on the QPU of European Synchrotron Radiation Facility (ESRF). The depression of 3^rd harmonic radiation is significantly improved over the ESRF QPU, as deduced from the measured magnetic fields. A method of configuring shims of different geometries and sizes, based on a symmetric principle to correct multi-pole field integrals, is demonstrated.