宽带隙Cu(In,Al)Se2薄膜的制备及表征

以特殊脉冲电沉积方法制备CuInSe2(CIS)前驱体薄膜, 通过真空蒸镀法在CIS薄膜上沉积Al膜, 经硒化退火后在氧化铟锡(ITO)基底上制备了Cu(InAl)Se2(CIAS)薄膜. 采用扫描电子显微镜(SEM)、X射线能谱(EDS)、X射线衍射(XRD)、X射线光电子能谱(XPS)、紫外-可见吸收光谱(UV-Vis)对其形貌、结构、成分及光学吸收性质进行了表征. 结果表明, 制备的CIAS薄膜颗粒均匀, 表面平整致密, 呈黄铜矿结构. 薄膜在可见光区具有良好的吸收, 带隙约为1.65 eV.     

含有咪唑生色团系列树型有机分子二阶非线性光学性质的密度泛函理论研究

应用密度泛函理论(DFT)B3LYP/6-31G*方法计算研究了系列树型含有咪唑生色团的有机分子的结构和非线性光学性质.计算结果表明:该系列分子具有A- -D- -A(A:受体,D:给体)结构,分子基态的偶极矩、极化率、二阶NLO系数( )随共轭链的增长及吸电子基的增强而增大;同时,前线轨道能级差值越小此类分子的二阶极化率总有效值( )越大.计算的吸收光谱显示此系列树型分子在低能区域247.79nm-419.87nm都有一个最强吸收,并且均是最高占据轨道与最低空轨道之间的跃迁.     

SO4.-自由基氧化苯丙氨酸反应机理的

采用时间分辨的动力学瞬态吸收光谱和脉冲辐解技术研究了水溶液及水/乙腈混合溶液中SO₄^.- 自由基氧化苯丙氨酸的反应. 结果表明氧化性的SO₄^.- 自由基进攻苯丙氨酸首先生成在310 nm 处有一强吸收峰的苯丙氨酸阳离子自由基3, 然后再经由三条相互竞争的途径反应: 羟基化、脱质子、脱羧. 3个反应进行的难易强烈依赖于苯丙氨酸羧基和氨基末端的离子态以及溶剂的性质. 苯丙氨酸的羧基以非质子态存在时脱羧反应才能发生. 脱质子反应在高pH的溶液中较中性或酸性溶液中易于进行, 而且随着介质中乙腈的增加与羟基化反应相比较脱质子反应占主导, 而在纯的水溶液中羟基化反应更易进行.     

Test particle simulations of resonant interactions between energetic electrons and discrete,multi-frequency artificial whistler waves in the plasmasphere

Modulated high frequency(HF) heating of the ionosphere provides a feasible means of artificially generating extremely low frequency(ELF)/very low frequency(VLF) whistler waves, which can leak into the inner magnetosphere and contribute to resonant interactions with high energy electrons. Combining the ray tracing method and test particle simulations, we evaluate the effects of energetic electron resonant scattering driven by the discrete, multi-frequency artificially generated ELF/VLF waves. The simulation results indicate a stochastic behavior of electrons and a linear profile of pitch angle and kinetic energy variations averaged over all test electrons. These features are similar to those associated with single-frequency waves. The computed local diffusion coefficients show that, although the momentum diffusion of relativistic electrons due to artificial ELF/VLF whistlers with a nominal amplitude of ～ 1 pT is minor, the pitch angle scattering can be notably efficient at low pitch angles near the loss cone, which supports the feasibility of artificial triggering of multi-frequency ELF/VLF whistler waves for the removal of high energy electrons from the magnetosphere. We also investigate the dependences of diffusion coefficients on the frequency interval(△f) of the discrete, multi-frequency waves.We find that there is a threshold value of △f for which the net diffusion coefficient of multi-frequency whistlers is inversely proportional to △f(proportional to the frequency components Nw) when △f is below the threshold value but it remains unchanged with increasing △f when △f is larger than the threshold value. This is explained as being due to the fact that the resonant scattering effect of broadband waves is the sum of the effects of each frequency in the ‘effective frequency band’. Our results suggest that the modulation frequency of HF heating of the ionosphere can be appropriately selected with reasonable frequency intervals so that better performance of controlled precipitation of high energy electrons in the plasmasphere by artificial ELF/VLF whistler waves can be achieved.     

次预不变凸集值优化导数型最优性条件

引入了集值映射的α-阶锥次预不变凸概念,借助于α-阶相依上导数,建立了锥次预不变凸集值映射的导数型择—性定理,并利用择—性定理获得了集值优化导数型的最优性必要条件.     

扩展HK网络结构与同步能力的研究

研究两种高聚类系数无标度网络演化机理对网络同步能力的影响．首先,以Holme和Kim（HK）模型为基础,提出了度分布和聚类系数均可调的扩展HK模型（EHK模型）．扩展HK模型将HK模型中的三角结构扩展到了旧节点之间,解决了HK模型边的演化只存在新旧节点之间以及每个时间步加入网络节点的边数固定的不足．其次,研究了三角结构演化机理对网络同步能力的影响．最后,仿真研究发现三角结构的演化机理降低了两类无权网络的同步能力．     

Oscillatory and anti-oscillatory motifs in genetic regulatory networks

Recently,self-sustained oscillatory genetic regulatory networks(GRNs) have attracted significant attention in the biological field.Given a GRN,it is important to anticipate whether the network could generate oscillation with proper parameters,and what the key ingredients for the oscillation are.In this paper the ranges of some function-related parameters which are favorable to sustained oscillations are considered.In particular,some oscillatory motifs appearing with high-frequency in most of the oscillatory GRNs are observed.Moreover,there are some anti-oscillatory motifs which have a strong oscillation repressing effect.Some conclusions analyzing these motif effects and constructing oscillatory GRNs are provided.     

AHP灰色综合评价的新训驾驶员训练评估

随着汽车行业的不断发展,我军车辆装备的高信息程度逐渐增强,要求部队新训驾驶员的培训方法不断更新,寻求科学有效的训练方法必须依据训练实践的评估.依据部队新训驾驶员的考核大纲,对其训练科目进行的分析,建立科学的指标体系,利用层次分析法(Analytic Hierarchy Process,简称AHP)确定了指标权重,根据灰色综合评价法原理,建立了新训驾驶员训练评估模型,对提高驾驶员训练质量效益有着重要的现实意义.     

应用数字散斑相关技术研究缺口根部高温疲劳变形

应用数字散斑相关技术研究了耐热合金试件在450°环境中缺口根部的弹塑性变形及其与疲劳循环次数的相关性。疲劳试验在单边带缺口的拉伸板状试件上进行。试件由耐热合金GH4169材料制成,试件表面预先通过离子溅射法制作了离散的金粒散斑图。试验采用逐级循环加载和疲劳循环加载交替的方式进行。首先进行逐级循环加载,将最大载荷Pmax平均分成8级,由0逐级加载至最大载荷,再由最大载荷逐级卸载至0;同时由图像系统半自动地、连续同步地采集系列散斑图。然后按0→Pmax→0加载方式,连续进行250次疲劳循环加载。逐级循环加载和疲劳循环加载不断交替,直至疲劳断裂。利用数字散斑相关技术计算出缺口根部的弹塑性应变,进而求出缺口根部应变、名义迟滞回线面积及斜率与疲劳循环次擞的相关性。试验结果对于耐热合金材料的疲劳寿命研究很有意义。     

孔周弹塑性变形与疲劳循环次数的相关性

应用白光散斑相关技术研究了孔周弹塑性变形与疲劳循环次数的相关性,以便探索疲劳寿命的预测方法.疲劳实验在单边带缺口的拉伸板状试件上进行,试件由GH4169材料制成,试件表面上喷涂了白光散斑图.疲劳加载采用0→Pmax→0的循环加载方式,加载波形为正弦波,加载频率为10Hz.实验中,按一定的疲劳循环周次在零载及最大载荷两种状态下停机、采图.应用数字图像相关技术求出孔周附近的残余位移场,并应用逐点最小二乘法求出应变场.实验中获得了一些对于疲劳寿命研究很有意义的结果.