MBBR水气协同脱氮启动方法研究

考察了水气协同条件对移动床生物膜反应器启动的影响。在添加氨氧化菌营养盐并通入50×10-6NO2气体时取得了理想的挂膜效果:挂膜速度快,生物膜稳定,有机物和总氮的去除率分别为73.81%和67.90%,且在进水水质波动较大的情况下出水稳定;同时,NO2气体也得到了净化,净化效率超过90%。     

CATIONIC CONDUCTIVITY FOR THE CROSSLINKED P [OLIGO (OXYETHYLENE) METHACRYLATE-COoMETHACRYLOYL ALKYLSULFONIC ACID LITHIUM]

Crosslinked copolymers with single Li~+-ionic conductivity were prepared from oligo (oxyethylene) methacrylate (MEO_n), methacryloyl alkylsulfonic acid lithium (SAMLi), and oligo (oxyethylene) dimethacrylate (DMEO_n). Li~+-ionic conductivity of the copolymer is improved by crosslinking and presented as a function of polymerization degree (n) in MEO_n, comonomeric salt concentration (O/Li), and crosslinking degree. The crosslinked copolymer P (0.7 MEO_(14)-0.3DMEO_(14)-SHMLi) without other small molecular additives exhibits an optimum Li~+-ionic conductivity of 1.2×10~(-6) S/cm at 25℃. Dc polarization test in the cell composed of Li/copolymer/Li shows a constant dc ionic conductivity which closes gradually to the ac one with decreasing dc polarization potential.     

新型含二茂铁有机配合物的合成及其电化学性质

以二茂铁为起始原料,经氯汞化反应、溴代反应、Suzuki偶联反应、水解反应和取代反应等5步反应合成了一种新型的含二茂铁结构单元的有机配合物(7),其结构经1H NMR、13C NMR、IR和HR-MS(ESI-TOF)表征。电化学研究结果表明:化合物6的E1/2小于化合物7,具有较高的氧化还原活性。     

芦丁合钴与DNA相互作用研究

合成了芦丁合钴配合物,通过元素分析、ICP、IR1、H NMR和TG-DTA等手段进行了表征,确定其分子式为[Co3(R t)2(H2O)12](CH3COO)2;运用电化学、吸收光谱、荧光发射光谱等方法研究了配合物与小牛胸腺DNA(CT DNA)的作用机理,并计算了键合常数为2.15×104L.mol-1,实验结果表明芦丁合钴与CT DNA以嵌入模式结合。     

乙烯在纳米催化剂InVO4-TiO2上的可见光降解

The InVO₄-TiO₂ nano-crystalline photocatalyst was prepared by sol-gel method and characterized by DRS, FTIR, Raman and XRD. The photocatalytic activities of the prepared sample were investigated by photocatalytic degradation of ethylene in the gaseous phase under visible light irradiation (λ>450 nm). The results indicate that both of pure TiO₂ and InVO₄ or their simple mixture show no photocatalytic activities for degradation of ethylene under visible light irradiation. However, as-synthesized InVO₄-TiO₂ catalyzes the degradation of ethylene into CO₂ under visible light irradiation. In addition, the interaction between InVO₄ and TiO₂ results in some structural distortion to all the crystal forms of TiO₂ in as-synthesized catalyst InVO₄-TiO₂.     

ELECTRICAL AND MECHANICAL PROPERTIES OF POLYANILINE FILMS——EFFECT OF NEUTRAL SALTS ADDED DURING POLYMERIZATION*

The electrical and mechanical properties of polyaniline (PANI) films syn-thesized by the presence of the selected neutral salts in the polymerization were measuredas a function of the properties and the concentration of the selected neutral salts, andthe protonation state. It was found that both the electrical and mechanical properties ofPANI films were enhanced by adding neutral salts in the polymerization. The adding ofthe neutral salts in the polymerization resulted in extended conformation of polymer chainand increasing of molecular weight of PANI, which may be the reasons why the electricaland mechanical properties of PANI films were improved by the presence of neutral salts inthe polymerization.     

三氯化铁掺杂稀土聚乙炔的电性能

自从1981年A.Prón等人用三氯化铁掺杂钛系聚乙炔而得到高电导率掺杂聚乙炔以来,对此掺杂聚乙炔的低温电性能已作了一定的研究。不同作者所报道结果可分为两类:一类报道各种掺杂量聚乙炔的电导率均随温度降低而单调减少;另一类则观察到随温度的降低电导率约在200K时出现最大值(增加5%),接着电导率降低。新近我们报导了三氯化铁掺杂的稀土聚乙炔的基本特性。本文进一步对此掺杂稀土聚乙炔的低温电性能作了研究,观察到与上述两种情况相似但不完全相同的结果。     

STUDIES ON ENHANCED CONDUCTIVITY OF STRETCHED CONDUCTING POLYMERS

A physical model of series of the conductivity on chain and the interchain conductivitybetween chains is proposed to explain enhanced conductivity of stretched conducting polymers.This model suggests that the enhanced conductivity for stretched conducting polymers might bedue to increasing of the interchain conductivity between chains along the elongation direction afterdrawing processes if the conductivity on chain is assumed much larger than that of the interchainconductivity between chains. According to this model, it is expected that the temperaturedependence of conductivity measured by four-probe method for stretched conducting polymers iscontrolled by a variation of the interchain conductivity between chains with temperature, whichcan be used to explain that a metallic temperature dependence of conductivity for stretchedconducting polymers is not observed although the conductivity along the elongation direction isenhanced by two or three orders of magnitude.     

Synthesis,Single-crystal Structure,and Computational Studies of a Yavapaiite Structure Compound:Pb(Sb_(0.5)Fe_(0.5))(PO_4)_2

The single crystals and powder of a Yavapaiite Structure phosphate,namely,PbSb_(0.5)Fe_(0.5)(PO_4)_2,were synthesized by solid state method and characterized by X-ray single-crystal diffraction and powder diffraction.The title compound crystallizes in the monoclinic system,space group C2/c(No.15) with a = 16.716(4),b = 5.186(7),c = 8.130(2) ?,β = 114.93(6)o,Z = 4,R(I 2s(I)) = 0.0430,R indices(all data) = 0.0460,and T = 293(2) K.The title compound belongs to the Yavapaiite Structure A(Ⅱ)M(Ⅳ)(PO_4)_2 compounds,and the Sb1 atom and Fe1 atoms occupy the same site(M) and their occupancy factors are refined to be 0.5 and 0.5 having a sum occupancy factor of 1.0.Its structure consists of [M(PO)_4]_2 nn layers running parallel to the(b,c) plane built up of cornerconnected MO_6 octahedra and PO_4 tetrahedra.Additionally,the calculations of energy band structure,and density of states have been performed with the density functional theory method.The studies of computational calculation and UV experimental results show that the new compound is an indirect band-gap insulator.     

新课程下高中物理课堂合作学习的优化策略

随着物理新课程改革的推进,合作学习在课堂教学中得到了广泛的推广与实施,但是仍存在流于形式,分组不科学,责任不明确,评价不全面等方面的问题.针对以上问题,需要在课堂合作学习的不同阶段从合作学习理念、合作学习目标、合作分组、教学方法及评价机制等方面进行优化.