复合型锶铁氧体纳米晶粒的改性研究

利用X光衍射和透射电子显微技术,对粒子Fe₃O₄-SrFe₁₂O₁₉的复合机理进行了研究.弄清了尖晶石型外延包裹层的生长机理.证实了外延层和内核粒子通过电子交换产生了很强的耦合作用.经过改性之后,尖晶石型晶体层在SiFe₁₂O₁₉粒子表面得到良好的生长. 关键词：     

SOLITON EXCITATIONS IN A DIATOMIC LATTICE WITH NONLINEAR ON-SITE POTENTIAL

We consider the soliton excitations in a diatomic chain with nonlinear on-site potential based on a quell-discreteness approximation, Different from the theoretical approach devel-oped before, our method is valid in the whole Brillouin zone of phonons. The gap solitons observed recently in a nonlinear diatomic pendulum lattice can be well explained qualita-tively. It is also shown that if the wave number of the carrier wave is near the edge of the Brillouin zone, the results coinside with that of Kivshar and Flytzanis about the gap solitons in diatomic lattices when the difference of mass between two kinds of atoms becomes small.     

计及表面张力的非传播孤波理论

本文研究了表面张力对非传播孤波运动的影响,对Larraza和Putterman的理论进行了修正。发现表面张力使孤波横向振动频率范围增大,振幅增高,宽度减小。当表面张力系数a=0时,结果与Larraza和Putterman的理论相一致。     

On the method of equivalent inclusions in elastodynamics and the scattering fields of two ellipsoidal inhomogeneities

Gurtin’s variational principle is used to derive the equivalence equalions for general linear elastodynamical problems of multiple inhomogeneities. An approximate expression on scattering field of two ellipsoidal inhomogeneities is obtained by the method of equivalent inclusions. And some numerical examples are presented.     

基于不同碱基含量的[FeFe]-氢化酶模型化合物功能化聚合物的合成与表征

将含二炔基的[2Fe2S]模型化合物[Fe2(μ-SCH2C≡CH)2(CO)6](A)和双叠氮单体2,6-(N3CH2)Py(B,Py=吡啶)与含碱性基团的双炔单体(2-Py CH2)N(CH2C≡CH)2(C,Py=吡啶)通过"点击反应"以不同比例进行共聚,得到了6种含不同碱基量的[FeFe]-氢化酶模型化合物功能聚合物Polymer-1~Polymer-6。通过红外光谱、硫元素分析、热重、扫描电镜和电化学对这些聚合物进行了表征。红外光谱和电化学研究表明二铁六羰基单元A以二铁五羰基的形式存在于聚合物中。在共聚过程中,增加单体C的含量能显著改变聚合物的形貌和增加其在有机溶剂中的溶解度,同时热稳定性也有所增加。这些聚合物在含有醋酸的DMF介质中催化质子还原的行为表明,通过单体C引入的碱性基团所形成的次级配位环境对二铁中心的催化性能有显著影响。     

用透射反射扫描法检测光学薄膜的激光损伤

 用波长1.06μm的激光透射反射自动扫描装置扫描了激光辐照前后薄膜的反射比和透射比。薄膜样品的工作波长为1.06μm。将扫描结果与相衬显微镜观察到的形貌相对照。实验结果表明，用透射反射扫描法不仅能反映出相衬显微镜所能观察到的损伤，而且也能发现某些显微镜所不能发现的损伤。由于透射比和反射比可以反映出薄膜对激光的传输性能，因此也能反映出薄膜能否继续工作，以此来判定损伤与否。因此用透射反射扫描法可以作为检测损伤的手段，由于简单易行，可以在线检测。避免目前损伤测试工作中繁重的人工操作。     

Collective Modes of a Quasi-Two-Dimensional Superfluid Fermi Gas in BCS-BEC Crossover

We investigate the collective modes of a quasi-two-dimensional （Q2D） superfluid Fermi gas in Bardeen-Cooper-Schrieffer Bose-Einstein condensation （BCS-BEC） crossover. For solving a generalized Gross-Pitaevskii equation by using a time-dependent variational method, we take a trial wavefunction with the form of hybrid Gaussianparabolic type, which not only reflects the Q2D character of the system and also allows an essentially analytical approach of the problem. We present a Q2D criterion that is valid for various superfluid regimes and displays clearly the relation between the maximum condensed particle number and the parameters of trapping potential as well as atom-atom interaction. We show that due to the small particle number in the Q2D condensate, the contribution to oscillating frequencies by the quantum pressure in the strong confinement direction is significant and hence a Thomas-Fermi approximation can not be used.     

单轴压力诱导CMR钙钛矿晶格及磁输运变化

通过原位加压下X射线衍射,CMR钙钛矿La_0.83Sr_0.17MnO₃中由单轴压力诱导的晶格常数的超常变化及显著的晶格畸变被观察到.沿[200]方向的晶格压缩系数,即dlnd _Mn-O/d_Mn-O可达3.8X10^-4MPa.在20 MPa的单轴压力下,巨压电阻效应及磁化强度增强行为同时被观察到.上述现象显示CMR钙钛矿的晶格易于发生变化,并且其电磁性质是结构敏感的.     

运行锅炉排烟损失的稳定性控制

锅炉的排烟损失是锅炉设备的一项主要热损失。如何对实际运行的锅炉进行稳定性控制使其排烟损失达到设计值，则是节能工作的一个重要环节。本文利用计算排烟损失的函数关系式，通过正交设计求得实际运行状态下的参数控制值，以达到减少排烟损失的目的。     

具有二阶和三阶非线性一维光子晶体中的耦合模孤子

研究同时具有二阶和三阶非线性的一维光子晶体中的耦合孤子动力学.从Maxwell方程出发,利用多重尺度法,导出了光学整流场与两个基频电场包络的非线性耦合模方程组,给出了耦合模方程组的孤子解.结果表明,由于二阶非线性导致的光学整流场对基频电场有调制作用,使得两个基频电场分量可以呈现为亮孤子亮孤子、暗孤子暗孤子及亮孤子-暗孤子对 当两个基频电场的振动频率趋于光子晶体频带的带边频率时,光学整流场消失