ICP—AES法同时测定硼铁中的主要成分及杂质

本文研究了用ＩＣＰ－ＡＥＳ法同时测定硼铁中的主要成分Ｂ、Ｆｅ及杂质元素、Ａｌ、Ｍｎ，Ｓｉ的方法。采用碱熔融法分解样品，选Ｃｄ作为内标元素。     

Spectral structure of CuBr vapor laser lines

The atomic density, the buffer gas pressure, and the voltage dependence of the 510.6 nm laser line shape and its temporal evolution emitted from a Cu/CuBr vapor laser are measured. It is found that the monochromaticity of these laser lines can be improved greatly at a relative high buffer gas pressure. The temporal evolution of the line shape offers a stereoscopic view of a laser pulse. The sequence of appearance of the peaks of the line shape is governed by the intensity of the hyperfine component of the copper line.     

Mo掺杂Mn4Si7的光电性质的第一性原理计算

采用基于密度泛函理论(DFT)的第一性原理计算方法,计算了Mn4Si7及Mo掺杂Mn4Si7的电子结构和光学性质.计算结果表明Mn4 Si7的禁带宽度Eg=0.804 eV,Mo掺杂Mn4Si7的禁带宽度Eg=0.636 eV.掺杂使得Mn4 Si7费米面附近的电子结构发生改变,导带底由Γ点转移为Y点向低能方向下偏移,价带顶向高能方向上偏移,带隙变窄.计算还表明Mo掺杂Mn4Si7使介电函数、折射率、吸收系数及光电导率等光学性质增加.     

Effect of sound wave stress on antioxidant enzyme activities and lipid peroxidation of Dendrobium candidum

The effect of sound wave stress on important medicinal plant, Dendrobium candidum Wall. ex Lindl, was investigated, including the responses on malondialdehyde (MDA) content, the activities change of superoxide dismutase (SOD), catalase (CAT), peroxidase (POD) and ascorbate peroxidase (APX). Results were found that the activities of SOD, CAT, POD and APX enhanced totally in different organs of D. candidum, as leaves, stems and roots, in response to the stress. Furthermore there happened similar shift of antioxidant enzymes activities, which increased in the initial stimulation and decreased afterwards. Data showed SOD, CAT, POD and APX activities ascended to max at day 9, 6, 9 and 12 in leaves, at day 9, 6, 12 and 9 in stems, and at day 12, 6, 9 and 9 in roots, respectively. As a lipid peroxidation parameter, MDA content in different organs increased in the beginning, dropped afterward, and increased again in the late. Anyway the total trend was the rise of MDA level compared to the control. It was interesting that the MDA content appeared the lowest levels almost when the antioxidant enzymes activities were up to the highest. Our results demonstrated the different organs of D. candidum might produce accumulation of active oxygen species (AOS) under initial treatment of sound wave stress. Later AOS might start to reduce due to the enhancement of antioxidant enzymes activities treated by the stress. The data revealed that the antioxidant metabolism was to be important in determining the ability of plants to survive in sound stress, and the up regulation of these enzymes activities would help to reduce the build up of AOS, which could protect plant cells from oxidative damage. Moreover, different cell compartments might activate different defensive system to reduce excessive amount of AOS. Finally the mechanism of this action was also discussed simply.     

碳酸盐岩钙同位素化学分离方法改进及其在青藏高原地质样品中的应用前景

本文报导了在前人基础上改进的碳酸盐岩(白云石－方解石)地质样品钙同位素化学分离方案。通过对比云南永善桧溪剖面白云岩－灰岩过渡岩性在不同浓度盐酸下淋洗结果,确定了4N浓度盐酸能有效富集白云石－方解石体系中的钙元素,且热电离质谱(TIMS)测试结果显示4N盐酸与1.6N盐酸淋洗方案处理后钙同位素测试结果一致,表明在相同测试精度的情况下,针对白云石－方解石体系下碳酸盐岩地质样品化学分离方案能提高化学分离效率。本文进一步结合青藏高原研究热点问题,对钙同位素在青藏高原地质样品的应用前景进行了分析,分析表明,钙同位素在青藏高原隆升前古海洋环境重建、隆升期构造活动恢复及隆升后火成岩来源示踪上具有广泛应用前景。     

醇存在下R,S-1,1′-2-联萘酚对映体的环糊精手性识别研究

以R,S-1,1′-2-联萘酚对映体为手性客体分子, 采用荧光探针法详细研究了各种醇对β-环糊精/(R或S)-1,1′-2-联萘酚对映体的手性包络和手性荧光猝灭等性质的影响, 结果表明, 醇的存在可显著影响R,S-1,1′-2-联萘酚对映体与β-环糊精形成包络物的包络形式和包络常数. 通过与该对映体的β-环糊精手性固定相高效液相色谱拆分法比较研究结果表明, 醇等第三客体分子可显著影响环糊精对对映体化合物的手性选择性和分离度.     

静压沉桩挤土机理探讨及有限元分析

针对预制桩在静压沉桩过程中出现的挤土现象,从土体小主应力方向加载的角度考虑,视浅层土体的隆起为小主应力方向(水平向)加载引起大主应力(垂直向应力)增加所致.在已有的柱形小孔扩张理论基础上,通过引入考虑位移的土压力计算方法提出了桩周土体隆起分界面表达式.利用该表达式分析浅层土体的隆起量,并利用Randolph提出的深层土体径向位移解析公式给出深层土体的变形量.最后运用有限元数值模拟计算与本文的数值解答进行对比分析,结果相近.     

Electrorheological Moment Amplifier

An electrorheological moment amplifier is developed and its work principle and structure characteristics are explained. Then, we research the effects of structural parameters on performance of mechanism and present optimization design methods and control methods. With a view of enhancing the amplification coefficient or increasing the speed of dynamic response, the expectation values of objectives and the weight are obtained and the amplifier with good performance could be designed. In this paper, the parabolic relation between moment amplified and electric field is decided by experimental fit method. And step and pulse electric field signals are used to study the dynamical properties of the device. As the result of experiments, it is confirmed that the electrorheological moment amplifier has good dynamic performance through optimization design methods.     

红外InGaAsP光电阴极研究

本文主要对阈值波长可达1.25μm的InGaAsP光电阴极进行了详细的研究。在国内首次实现了在0.5μm～1.25μm波段范围内具有光电响应的半导体光电阴极。用Cs和O₂激活后得到的光电阴极在1.06μm处的反射式光电灵敏度为3.4mA/W,量子效率为0.4%。本文还对激活表面及热清洁工艺进行了系统地分析,确定出了最佳的表面清洁温度及时间。     

各向异性介质的布儒斯特角

对以折射率椭球的主轴为坐标轴的特定取向的各向异性晶体，导出起偏角的表示式，说明布儒斯特定律已不适用于各向异性的介质；并根据材料中极化矢量Ｐ′的方向进一步阐明对任意取向的各向异性材料通常不存在能产生线性偏振反射光的起偏角