Synthesis and properties of cocotriethoxylpropanediamine oxide

A new kind of amine oxide surfactant – cocotriethoxylpropanediamine oxide (CTPDAO) – was synthesized by a two-step process. The molecular structure was characterized by FTIR spectra and ¹H NMR. The new surfactant showed high surface activity in aqueous solution in the surface tension measurement. Emulsifying capacity and wetting ability were studied in comparison to dodecyldimethylamine oxide (DDMAO). The results indicate that this new surfactant could reach the lowest surface tension of 30.4?mN?m^?1 in aqueous solution with a critical micelle concentration (CMC) of 0.23?mmol L^?1. The wetting ability of DDMAO is better than that of CTPDAO. Compared with CTPDAO, DDMAO shows a greater capacity to emulsify soybean oil, although CTPDAO is a better emulsifying agent for liquid paraffin. The foaming properties and thickening function of DDMAO and CTPDAO mixed with alcohol ether sulfate (AES) and dodecylbenzene sulfonate (LAS) were also investigated. The results show that CTPDAO is a superior foam stabilizer than DDMAO while CTPDAO and DDMAO both have excellent thickening functions.     

Wash-free in-situ self-desalting and peptide enrichment by block copolymer analyzed with MALDI-TOFMS

A novel technique of simultaneous peptide enrichment and wash-free in-situ self-desalting for MALDI analysis is reported, where a newly synthesized block copolymer with a microphase-separated configuration is applied to embed salts with its hydrophilic domain of poly(ethylene oxide) and concentrate peptides with its hydrophobic domain of polysulfone.     

Two new diterpenoids from the buds of Wikstroemia chamaedaphne

Two new diterpenoids, wikstroelide Q (1) and prostratin Q (5), together with three known diterpenoids, pimelea factors P? (2), P? (3), and prostratin (4), and five known lignans, (+)-epipioresinol (6), (+)-isolariciresinol (7), (?)-lariciresinol (8), (+)-epi-sesaminone (9), and prestegane B (10), were isolated from the buds of Wikstroemia chamaedaphne Meissn. Their structures were elucidated by a combination of spectroscopic analyses. Compounds 1–10 were evaluated for their cytotoxicities against HL-60, SMMC-7721, A549, MCF-7, SW480, and BEAS-2B cell lines in vitro.     

基于高选择性氟液相传感膜的离子传感器

本文基于国外最新研究工作,系统总结了电位型传感器中的一种新型传感膜——氟液相传感膜。对构成氟液相传感膜的所有组分:氟溶剂、溶解在氟溶剂中的亲氟离子交换剂和亲氟离子载体以及对氟溶剂起支撑作用的惰性微孔支撑膜等进行了全面归纳,重点讨论了这4种因素对传感器性能的影响。指出目前使用的亲氟离子交换剂分子和亲氟离子载体分子均含有2—8根链长为6—10的全氟碳链。氟液相传感膜具有优于传统PVC膜的检测下限,其中通过三维有序大孔碳以固体接触方式构建的氟液相传感膜电位传感器对Ag⁺的探测下限可达3.8×10^-11 mol/L。氟液相传感膜还具有十分出色的选择性,无任何离子载体的空白氟液相传感膜的选择系数对数值log K_i,J^pot的跨越宽度达16—18,比无载体的PVC膜宽8个数量级。这类全新的氟液相传感膜构建的电位型离子传感器将以其独特的优势在环境监测、食品卫生,尤其是在医疗诊断、生物物质检测中展示出不可替代的作用。     

A novel time-division multiplexing fiber Bragg grating sensor interrogator for structural health monitoring

A novel fiber Bragg grating (FBG) sensor system for measurement of strain and temperature is proposed in this paper. The proposed sensor technique is based on time-division multiplexing (TDM). A semiconductor optical amplifier (SOA), connected in a ring cavity, is used to serve as a gain medium and switch. The SOA is driven by a pulse generator, which operates the SOA at different periods of time to select reflected pulses from a particular sensor. The FBG sensors have identical center wavelengths and can be deployed along the same fiber. This technique relieves the spectral bandwidth issue and permits the interrogation of up to 100 FBGs along a fiber, if the reflectivity of the individual sensors is sufficiently low to avoid shadowing effects. This system is particularly suitable for the application in structural health monitoring (SHM) where large numbers of sensors are required in wide measurement ranges.     

An Efficient and Environmentally Friendly Method for the Synthesis of Cellulose Carbamate by Microwave Heating

An efficient, solvent‐free, and catalyst‐free microwave synthesis of cellulose carbamate from a mixture of native cellulose and urea is reported. The structure of the samples are characterized by elemental analysis, FT‐IR spectroscopy, X‐ray diffraction, and NMR spectrometry. Cellulose carbamates with a nitrogen content of 0.651–2.427% are obtained by microwave heating at 255 W for 2–5 min. With the introduction of carbamate groups, the hydrogen bonding and crystalline structure of the native cellulose are partially destroyed. The products retain the cellulose I crystalline form of the native cellulose, and display good solubility in NaOH solutions.

     

尺寸可控氢氧化镧纳米棒的水热合成及表征

以硝酸镧为镧源、三乙胺为碱源和络合剂,通过简便的水热法成功合成了大量均一的氢氧化镧纳米棒。详细研究了三乙胺的用量、表面活性剂、反应温度和时间对产物形貌及尺寸的影响。基于实验结果,提出了氢氧化镧纳米棒的形成机理。同时制备了稀土掺杂的氢氧化镧纳米棒。利用X射线衍射（XRD）、透射电子显微镜（TEM）、选区电子衍射（SAED）和高分辨透射电子显微镜（HRTEM）对所得产物的物相、结构和形貌进行了表征分析。     

4维3元断链码的重量谱

GF(q)上[n,k;q]线性码C的重量谱为序列(d1,d2,…,dk),这里dr是C的r维子码的最小支持重量(1≤r≤k).用有限射影几何方法确定了满足含有2个邻接断点的断链条件的4维3元线性码的重量谱.     

基于GSI的锦屏地下厂房岩体参数研究

工程开挖卸荷后岩体参数研究一直是工程界关注的焦点,是稳定性评价的基础性工作。本文以锦屏地下厂房开挖工程为背景,通过对上下游边墙不同桩号段开挖揭露的岩体进行工程地质岩组划分,进行了开挖后岩体质量评价并对其进行分类,通过在GSI(Geological Strength Index)评价体系中引入Jv(节理数/m³),使评价体系相对合理化,经回归分析,对不同风化程度的岩体进行了力学参数求解,发现内聚力及内摩擦角的计算值与建议值吻合较好。