We study the detailed structure of a finite group under the assumption that all minimal subgroups of the generalized Fitting subgroup of some normal subgroup of are well-suited in .
Conversion of N-alkyl lactams to the corresponding alpha-phosphono lactams has been investigated through procedures that involve formation of the lactam enolate and reaction with a phosphorus electrophile. With N-octylpyrrolidinone, the enolate could be trapped efficiently on oxygen by reaction with diethyl phosphorochloridate, and the resulting vinyl phosphate rearranges smoothly to the desired phosphonate upon treatment with additional LDA. Attempts to apply the same protocol to N-farnesyl lactams met with limited success. Studies with an isolated alpha-phosphono N-farnesyl lactam have shown that the farnesyl group is not stable to the excess of strong base required for rearrangement of a vinyl phosphate. However, a series of N-farnesyl lactams and imides was converted to the desired phosphonates through formation of the lactam enolate, reaction with diethyl phosphorochloridite, and subsequent oxidation of the phosphorus intermediate to the P(V) state. 相似文献
The coal samples were collected from Yima coal district, China. The pyrolysis experiments were carried out in a simulated bed quartz reactor with a heating rate of 20 °C/min. The 44 elements in raw coal and chars were determined by inductively coupled-plasma mass spectrometry instrument (ICP-MS). The release and enrichment behavior of 44 trace elements during coal pyrolysis of Yima coal was studied.
According to the transformation behaviors, chemical features and thermal features under different pyrolysis temperatures, the 44 elements can be categorized to 4 groups: light elements (Li and Be), nonmetal elements (Se, As, B, etc.), heavy metal elements (including 24 elements, Cu, V, Co, etc.) and rear earth elements (REE) (14 elements). The results showed that (1) the higher pyrolysis temperatures, the higher release ratio and release ratio of REE are very low; (2) the enrichment ratios of the elements in chars increase by the sequence of nonmetal elements < light elements < heavy metal elements < REE. The nonmetal elements, light elements and a few heavy metal elements will be emitted out from coal during coal pyrolysis and they will pollute environment. 相似文献
A proposed computer model for predicting aerosol particle dispersion in indoor spaces was validated with experimental data found in the literature, and is then used to study the effect of the area and point source locations on particle dispersion in displacement ventilation (DV) rooms. The results show that aerosol source location has a strong impact on the spatial distribution and removal rate of indoor particles. Particle removal performance depends strongly on ventilation efficiency and particle deposition rate on indoor surfaces. Important consideration for both relative ventilation efficiency and deposition rate consists of the position of the aerosol source relative to the main airflow pattern and the occupied zone. 相似文献