硫酸分离–火试金重量法测定碲化铜中的金和银

建立了用硫酸分离-火试金重量法测定碲化铜中的金和银含量的方法。用硫酸溶解碲化铜样品,过滤,除去铜和碲,得到含金、银的沉淀物,沉淀物经灰化、配料、高温熔融制得铅扣。将铅扣灰吹,得到金银合粒,用硝酸溶解分离金,用重量法测定金含量。用金银合粒的质量扣除金粒的质量和分金液、洗液中杂质的质量即为银含量。采用灰皿、残渣熔融法补正,或用含碲、铜物料做基体加入纯金、纯银同试样方法测定,根据金、银的回收率加以补正,从而得到试样中的碲含量。实验结果表明,浓硫酸的加入量为30 mL,残余量应不少于15 mL。火试金中硅酸度为1左右,试样进炉温度以900℃为宜。该方法金、银测定结果的相对标准偏差分别为0.33%~1.97%,0.28%~1.27%(n=9)。金的回收率为98.5%~100.2%,银的回收率为95.5%~101.4%。该法满足生产控制检测和贸易结算的要求。     

新型联苯四氮唑沙坦类化合物的合成

以3-甲基-4-硝基苯甲酸为原料,经酯化、还原、硝化等10步反应合成了4个新型的联苯四氮唑沙坦类化合物,其结构经1H NMR,13C NMR和MS表征。     

新型BT-BMT-xBNT无铅高储能密度陶瓷研究

本文采用传统固相反应法,成功制备了新型无铅弛豫铁电陶瓷(1-x)[0.9BaTiO₃-0.1Bi(Mg_0.25Ta_0.5)O₃]-xBi_0.5Na_0.5TiO₃。结果表明,较高居里温度的Bi_0.5Na_0.5TiO₃的引入,使得材料体系中建立了更多的以Bi—O耦合为主的极性纳米区域,弥补了因Bi(Mg_0.25Ta_0.5)O₃的加入导致的宏观极化强度的减少,提高了材料的饱和极化强度,实现了较高储能密度的同时具有更好的温度稳定性。在245 kV/cm电场强度下,x=0.2样品的储能密度约为4.01 J/cm³,储能效率约为84.86%,同时该组分在20~170 ℃储能密度的变化率小于5%,储能效率的变化率小于6%,表现出优异的温度稳定性。     

气相色谱-质谱法分析树苔浸膏的成分

采用分子蒸馏法对树苔浸膏进行分级分离,用气相色谱-质谱法对各级馏分进行定性和定量分析。结果表明:三级馏分共鉴定出55种成分,主要成分是苔黑酚单甲醚、分歧扁枝衣素单甲醚、扁枝衣酸乙酯、柔扁枝衣酸甲酯、β-苔黑酚羧酸甲酯、赤星衣酸乙酯、苔黑酚羧酸乙酯、柔扁枝衣酸乙酯、棕榈酸乙酯、油酸乙酯、亚麻酸乙酯和亚油酸乙酯。     

基于主成分的改进雷达图及其在综合评价中的应用

本文从可视化角度出发,在总结传统可视化方法因优点与不足的基础上,将主成分分析、因子分析与雷达图结合,改进了传统的可视化方法。并将新的可视化方法引入到综合评价中,提出了一种基于雷达图面积的综合评价模型,实例验证该种方法切实有效。     

Polaron in Bose-Einstein-Condensation System

We consider the motion of an impurity in a Bose-Einstein condensate system at T = 0 K with the contact interaztions for boson-boson and boson-impurity. Under the forward-scattering approximation, we obtain a Fr6hlich-like Hamiltonian for this system, which means that a polaron can be formed. The effective mass, the phonon number and the energy to form a polaron are obtained. We also discuss the validity of the forwardscattering approximation for this system.     

高强度聚焦超声软组织损伤超声监控成像与评价方法

提出基于超声射频信号的数字减影损伤区域成像方法,并根据成像结果采用对数谱差衰减系数估计法对高强度聚焦超声引起的软组织损伤程度进行评价。通过离体牛肉和牛肝组织实验,获得了绝对差值法、绝对差值求和法以及平方差值求和法的数字减影结果,分析了这些算法的性能以及阈值和窗宽的选取对算法的影响。在此基础上,比较了用于损伤程度评价的三种声衰减估计参量,证实了采用超声换能器带宽范围内的平均衰减系数的改变△(?)进行组织损伤程度评价的有效性。     

The Crystallization of Poly (3-dodecyltbiophene) in an Oriented Solidification Environment

Poly (3-alkylthiophenes) (P3ATs) have made up of a family of conductive polymerswhich are soluble, fusible and processable, since the introduction of flexible alkyl sidechains"'. It is generally accepted that P3ATs can form similar layered structures. inwhich the thiophene rings possess planarity and the side chains act as spacers'-'. Whenthe number. of 'carbon atoms of alkyl side chains is more than 10, some orderlyarrangements will occur for side chains betWeen the' layers'. It has been w…     

Ti扩散铌酸锂光波导特性的热固定技术

在Ti扩散铌酸锂光波导中,因光致折变效应而导致光波导特性漂移.在光波相干性的导波光学器件中,光致折变效应的影响尤为严重.本文报道了稳定光致折变效应的热固定技术实验结果;并提出在光波导特性的热固定过程中,不是H~+离子起主导作用这一看法.     

Hopf Bifurcation and Stability of Periodic Solutions of Differential-difference and Integro-differential Equations

Periodic solutions bifurcating from a steady state of differential-differenceand integrodifferential equations are studied. An algorithmfor determining the asymptotic orbital stability, directionof bifurcation, period, and asymptotic form of these solutionsis presented. This algorithm is applied to the Hutchinson-Wrightequation and to an equation with two delays. Finally some integro-differentialequations, modelling two and three trophic level competition,introduced by May, are discussed. Some numerical work supportingthe theory is described.