Electrochemical Reduction Characteristics of α-Nitronaphthalene inSulfuric Acid Solution

1-Amino-5-naphtholisanimportantintermediateproductfororganicsynthesis'.Itwastraditionallysynthesizedfroma-nityonaphthalenebychemicalmethod.HO:wever,thechemicalmethodneedstwostepsandproducesalargequantityofwastewater,indicatingthehigherenergyconsumptionandpollution.Inthispaper,theelectrochemicalreductionofa-nitronaphthalenetol-amino-5-naphtholwasfirstputforward,theelectrochemicalreductioncharacteristicsofa-nitronaphthalenetol-amino-5-naphtholwerestudiedandthereactionmechanismwasproposedaswell.…     

Novel soluble fluorinated poly(ether imide)s with different pendant groups: Synthesis,thermal, dielectric,and optical properties

Three types of new bis(ether dianhydride) monomers, [4,4′‐(2‐(3′‐methylphenyl)‐1,4‐phenylenedioxy)‐diphthalic anhydride (4a)], [4,4′‐(2‐(3′‐trifluoromethylphenyl)‐1,4‐phenylenedioxy)‐diphthalic anhydride (4b)], and [4,4′‐(2‐(3′,5′‐ditrifluoromethylphenyl)‐1,4‐phenylenedioxy)‐diphthalic anhydride (4c)] were prepared via a multistep reaction sequence. Three series of soluble poly(ether imide)s (PEIs) were prepared from the obtained dianhydrides by a two‐step chemical imidization method. Experimental results indicated that all the PEIs had glass transition temperature in the range of 200–230 °C and the temperature of 5% weight loss in the range of 520–590 °C under nitrogen. The PEIs showed excellent solubility in a variety of organic solvents due to introduction of the bulky pendant groups and were capable of forming tough films. The casting films of PEIs (80–91 μm in thickness) had tensile strengths in the range from 88 to 117 MPa, tensile modulus from 2.14 to 2.47 GPa, and elongation at break from 15 to 27%. The casting films showed UV‐Vis absorption edges at 357–377 nm, low dielectric constants of 2.73–2.82, and water uptakes lower than 0.66 wt %. The spin‐coated films of PEIs presented a minimum birefringence value as low as 0.0122 at 650 nm and low optical absorption at the optical communication wavelengths of 1310 and 1550 nm. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 3281–3289, 2010     

Expression and Emmprin Regulated Function of Aquaporinl in SMMC7221 Cells

<正>Herein lie the crosstalk and regulation between AQP1 and Emmprin in SMMC7221 cells by means of siRNA technology and deglycosylation method.Firstly,HAQP1,rather than hAQP3,was selectively upregulated in SMMC7221 cells by FBS,flollowed by the upregulated expression of Emmprin.Emmprin gene silencing caused a remarkable change in the expression of AQP1 gene,just like its downstream gene,MMP9,meanwhile the water permeability and cell migration were also descended prominently.Furthermore,when treated with tunicamycin, Emmprin was deglycosylated,which made the expression of AQP1 significantly declined,followed by remarkably decreased cell membrane water permeability and cell migration.Taken together,all the data indicates the expression level and the modification of Emmprin by glycosylation are the key factors in regulating the expression of AQP1.     

一类带有非线性源并以有限Borel测度为初值的非线性双曲方程的BV解

主要考虑以有限Borel测度为初值的非线性双曲方程的Cauchy问题ut (um)x=up,其中0＜m＜1,0＜p≤m是给定常数.特别地,得到了上述问题BV解的存在性.     

电源频率可调的单相旋转磁场实验仪

设计了电源频率可调的单相交流电产生的旋转磁场实验仪,应用该仪器可测量电感、损耗电阻、转速等     

基于半光滑方程的线性规划问题局部灵敏度分析

本文考虑线性规划的局部灵敏度问题.首先用非线性互补函数将线性规翊I问题的KKT系统转化为一个半光滑的方程组,然后利用半光滑函数的性质,得到一个能同时求所有变量(包括对偶变量)关于价值系数c,资源向量b,技术消耗系数aij的局部灵敏度的计算公式.该方法能处理任意特性的最优解(包括严格互补解和退化解)的局部灵敏度分析.具体算例说明了分析方法的应用.     

B-(p,r)-不变凸性下广义分式规划的一个鞍点最优性准则

对于一类目标函数中有无限个分式的广义分式规划,给出一个不完全Lagrange函数,并利用已有的最优性必要条件,在B-(p,r)-不变凸性的条件下,证明了鞍点最优性准则.     

DEA在投入产出表中的应用及其对建筑业的分析

将DEA(Data Envelopment Analysis)应用于投入产出表,这将有助于从投入产出表的使用和投入角度计算各个部门的相对效率,以此分析了经济系统各部门之间的相对依赖程度.为了证明这一点,本文从使用和投入的角度设定了五个目标对建筑业进行分析.结果表明建筑业对其他部门的使用相对依赖程度很小,而建筑产品的生产对其他部门的中间投入有很强的依赖性.此外,建筑业与制造业基本上是同相的.     

Toroidal李代数上的Poisson代数结构

非交换的Poisson代数同时具有结合代数和李代数两种代数结构,而结合代数和李代数之间满足所谓的Leibniz法则.文中确定了Toroidal李代数上所有的Poisson代数结构,推广了仿射Kac-Moody代数上相应的结论.