双原子正方晶格光子晶体边界模式的光传输特性

利用平面波展开法,发现双原子正方晶格光子晶体中ΓM方向边界面存在着快慢两类边界模式,并且通过计算色散关系和电场分布研究了边界参量对这两类边界模式传输特性的影响.依据两种模式的色散关系,计算了群指数和群速度色散参量,结果表明边界参量的变化对第一类边界模式传输特性的影响较小,该模式的平均群指数始终维持在5.0左右;第二类边界模式与第一类模式明显不同,边界参量的变化能够有效地影响到这种模式的传输特性,该模式的最大平均群指数可达178左右.利用时域有限差分法记录了不同时刻电场强度在边界附近的分布及监测点处的电场幅度变化情况,结果表明,两类模式都能够被限制在边界附近并向前传播,时域有限差分法得到的群速度与平面波展开法的结果完全吻合.     

新型环状聚(ε-己内酯-co-γ-三乙基硅氧基-ε-己内酯)的合成

设计合成了具有精确分子结构的聚合物对深入了解其结构与性能之间的关系起着至关重要的作用。研究了一种合成带有三乙基硅氧侧基的环状无规共聚酯的新方法。功能性单体γ-三乙基硅氧基-ε-己内酯(γ-Et3SiOεCL)和ε-己内酯(ε-CL)在环状引发剂2,2-二丁基-2-锡-1,3-二氧环庚烷(DSDOP)的作用下,进行活性开环聚合反应以制备活性环状无规共聚酯(LCP(εCLcoγEt3SiOεCL))前体,当单体完全转化后,以该活性环状前体作为大分子引发剂,引发反应性单体α-(1-丙烯酰氧乙基)-ε-己内酯(αAEεCL)进行嵌段聚合反应,合成了在活性中心附近带有不饱和双键的功能性环状嵌段共聚酯,即活性环状聚(ε-己内酯-co-γ-三乙基硅氧基-ε-己内酯)-b-(α-(1-丙烯酰氧乙基)-ε-己内酯)。最后该活性环状嵌段共聚酯在紫外光照射下,反应性单体结构单元中的双键发生分子内交联反应,从而制得稳定的不含有机锡的新型环状无规共聚酯cP(εCLcoγEt3SiOεCL)(Mn,NMR=28500)。采用SEC、1H NMR以及DSC等技术手段对聚合物的结构和性能进行表征。该方法的突出特点是能够高效地合成带有功能性侧基的高相对分子质量的环状无规共聚酯。     

三维荧光法测定水中的4-氯苯酚

对三维荧光法测定水中的4-氯苯酚进行了研究,并与传统的比色法进行了比较。4-氯苯酚的三维荧光光谱图中荧光特征峰位于λex/λem=280 nm/310 nm处,在pH 1~8时,荧光较强且稳定。4-氯苯酚质量浓度为0.01~2.0 mg/L时,荧光强度与浓度的线性相关系数R2为0.9997,检出限为0.0096 mg/L。方法可用于自来水及地表水中的4-氯苯酚的测定,回收率在94.3%~106.0%。     

预镀铋膜修饰碳糊电极差分脉冲伏安法测定废水中铅和镉

采用预镀铋膜法制得铋膜修饰碳糊电极,当沉积时间为540s得到最优铋膜。采用差分脉冲伏安法(DPV)实现了对痕量Pb2+、Cd2+的同时测定。优化了DPV测定条件,当富集时间为150s、富集电位为-1.25V、HAc-NaAc缓冲底液的pH为4.5时,Pb2+、Cd2+的峰电流最大。在最优的实验条件下,Pb2+和Cd2+的峰电流与其浓度呈良好的线性关系,线性相关系数R分别为0.9912和0.9937,线性范围分别为1~10μmol/L和5~50μmol/L,Pb2+和Cd2+的检出限分别为0.32μmol/L和2.01μmol/L。对实际废水样品进行了加标回收实验,其中Pb2+和Cd2+的回收率分别为98.4%~102.6%和95.4%~104.6%。     

Pt/TiO2-Al2O3整体式催化剂的制备及甲醛废气催化氧化

以Al₂O₃-TiO₂混合物为载体,采用过量浸渍法负载Pt制备出催化剂涂层,再将其涂覆到堇青石蜂窝载体上制备了整体式催化剂,利用N₂吸附/脱附、XRD、NH₃-TPD、SEM-EDS表征。研究了催化剂涂层中TiO₂含量和Pt负载量对甲醛去除率的影响。结果表明：TiO₂的含量为5wt%,Pt的负载量为1wt%的整体式催化剂在室温（5~35 ℃）、甲醛气体进口浓度为50~300 mg·m^-3和体积空速为10000 h^-1的条件下,甲醛去除率达98.4%以上。连续反应150 h之后催化剂仍可保持良好催化活性。      

CRISPR-Cas System for RNA Detection and Imaging

The system of clustered regularly interspaced short palindromic repeats(CRISPR)and CRISPR-associated endonucleases(Cas)have been widely used in gene editing,disease treatment,molecular diagnosis and chromosome imaging.On account of the programmable target recognition of CRISPR-Cas system and the specific targeting function toward RNA of type Ⅵ class Ⅱ Cas proteins,CRISPR-Cas system has been deployed as RNA recognition and detection tools,exhibiting promising application potentials in the field of RNA detection and imaging.In this review,we summarize the latest research progresses as well as development prospects of CRISPR-Cas system in RNA diagnosis and live cell RNA imaging.     

Tuning the mechanical properties and degradation properties of polydioxanone isothermal annealing

Polydioxanone (PPDO) is synthesized by ring-opening polymerization of p-dioxanone, using stannous octoate as the catalyst. The polarized optical micrograph (POM) shows thes pherulite growth rate of PPDO decreases with an increase in the isothermal crystallization temperature. PPDO is compression-molded into bars, and PPDO bars are subjected to isothermal annealing at a range of temperatures (Ta = 50, 60, 70, 80, 90, and 100 °C), and correspond to three different annealing times (ta = 1h, 2h, 3h). The effect on PPDO is investigated by using differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), X-ray diffraction (XRD), and scanning electron microscopy (SEM). With an increase in Ta and ta, the grain size and the degree of crystallinity also increase. Meanwhile, the tensile strength is significantly improved. The PPDO bars (90 °C, 2 h) reach the maximum crystallinity (57.21%) and the maximum tensile strength (41.1 MPa). Interestingly, the heat treatment process does not result in serious thermal degradation. It is observed that the hydrolytic degradation of the annealed PPDO is delayed to some extent. Thus, annealed PPDO might have potential applications, particularly in the fields of orthopedic fixation and tissue engineering.     

Birthrates and delay times of Type Ia supernovae

Type Ia supernovae (SNe Ia) play an important role in diverse areas of astrophysics, from the chemical evolution of galaxies to observational cosmology. However, the nature of the progenitors of SNe Ia is still unclear. In this paper, according to a detailed binary population synthesis study, we obtained SN Ia birthrates and delay times from different progenitor models, and compared them with observations. We find that the Galactic SN Ia birthrate from the double-degenerate (DD) model is close to those infe...     

湿工况下平直翅片对流传热传质数值研究

建立了湿空气流经平直翅片通道并伴有凝结现象发生的三维对流传热传质的数值模型,在空气进口雷诺数Re为190～3770,进口相对湿度φ_(in)为50%～90%的范围内,对干湿两种工况,平直翅片通道内的换热流动进行了对比研究。结果表明:湿工况换热系数为干工况换热系数的2.8～3.1倍,干工况翅片效率比湿工况翅片效率高35.8%～41.9%。当翅片为部分湿工况时,翅片效率随进口相对湿度的增大而增大,换热系数随进口相对湿度的增大而减小;当翅片为全湿工况后,进口相对湿度对翅片效率和换热系数的影响微弱。     

Particle-number-conserving analysis of multiquasiparticle bands in ~(177)Lu

The experimental one-, three-, and five-quasiparticle bands in ~(177)Lu are analyzed by the particle-number conserving (PNC) method for treating the cranked shell model with pairing interaction, in which the blocking effects are taken into account exactly. The experimental moments of inertia are reproduced very well by PNC calculations with us free parameter.