面心立方晶体外延膜沉积生长中失配位错的结构与形成过程

用分子动力学方法对5%负失配条件下面心立方晶体铝薄膜的原子沉积外延生长进行了三维模拟.铝原子间的相互作用采用嵌入原子法(EAM)多体势计算.模拟结果再现了失配位错的形成现象.分析表明，失配位错在形成之初即呈现为Shockley扩展位错，即由两个伯格斯矢量为〈211〉/6的部分位错和其间的堆垛层错组成，两个部分位错的间距、即层错宽度为1.8 nm,与理论计算结果一致；外延晶体薄膜沉积生长中，位错对会发生滑移，但其间距保持稳定.进一步观察发现，该扩展位错产生于一种类似于“局部熔融-重结晶”的表层局部无序紊乱- 关键词： 失配位错 外延生长 薄膜 分子动力学 铝     

级联三能级介质中非线性光学信号的增强

揭示非最大相干可能比最大相干产生更有效的非线性频率转换. 为此以三能级级联系统(没有最大相干)为例计算其非线性光学信号的强度, 并与三能级Λ型系统(具有最大相干)进行比较. 利用非微扰方法计算表明, 在双光子共振和相同参数的条件下, 级联系统产生的非线性光学信号的最大强度约是Λ系统的两倍. 利用缀饰态表象分析表明, 两个系统中耦合跃迁的自发辐射及其介入的不可逆三光子过程具有相反的作用. 它们在级联系统中加强非线性转换, 而在Λ系统中削弱非线性转换. 关键词： 电磁感应透明 非线性光学过程 双光子共振     

SiOx纳米管的制备及其发光特性

以液态金属镓为媒介,利用热蒸发法合成大量非晶SiOx纳米管,这些纳米管管径均匀分布,平均约80 nm,长度大于10μm,且管内外径比例较小．分析发现,在实验过程中,熔入金属镓液滴中的硅元素和氧元素结合并从液滴的表面饱和析出,形成以镓为中心的非晶SiOx纳米管状结构．在室温中,利用260 nm的激发光源激发SiOx纳米管,发现在蓝光波段附近发出强而稳定的PL谱线,这可能与样品中的氧缺陷和空位有关．     

High-throughput screening of fuel cell electrocatalysts

The drawbacks of our earlier report of preparing fuel cell catalyst arrays by borohydride reduction of inkjet prepared arrays of metal salts are discussed along with the need for inclusion of state-of-the-art metrics in all array screening. An alternative method for screening of hydrogen/air cathode catalysts, direct methanol fuel cell (DMFC) anode catalysts, and catalyst loading studies is provided. State-of-the-art Johnson Matthey catalysts were used in control experiments to demonstrate the utility of the array fuel cell for high throughput screening of fuel cell catalysts in the 3-4 mg/cm² range. This report lays out hard learned rules for high throughput screening and demonstrates that the array fuel cell can be used for very precise screening of libraries of membrane electrode assembly (MEA) components without the pitfalls discussed in the introduction.     

双纠缠原子在耗散腔场中的纠缠动力学

研究了能量损耗腔中,两纠缠二能级原子与单模辐射场相互作用过程中原子的纠缠动力学.结果表明:双纠缠原子的纠缠度演化特性决定于初始两原子间的纠缠度、纠缠形式、腔场的平均光数、腔场的衰变系数.当原子初始处于一特定纠缠态时,其纠缠度可以放大,并且不受腔场损耗的影响. 关键词： 二能级原子 纠缠度 密度算符 单模辐射场     

On completely irreducible operators

Let T be a bounded linear operator on Hilbert space H, M an invariant subspace of T. If there exists another invariant subspace N of T such that H = M + N and M ∩ N = 0, then M is said to be a completely reduced subspace of T. If T has a nontrivial completely reduced subspace, then T is said to be completely reducible; otherwise T is said to be completely irreducible. In the present paper we briefly sum up works on completely irreducible operators that have been done by the Functional Analysis Seminar of Jilin University in the past ten years and more. The paper contains four sections. In section 1 the background of completely irreducible operators is given in detail. Section 2 shows which operator in some well-known classes of operators, for example, weighted shifts, Toeplitz operators, etc., is completely irreducible. In section 3 it is proved that every bounded linear operator on the Hilbert space can be approximated by the finite direct sum of completely irreducible operators. It is clear that a completely irreducible operator is a rather suitable analogue of Jordan blocks in L(H), the set of all bounded linear operators on Hilbert space H. In section 4 several questions concerning completely irreducible operators are discussed and it is shown that some properties of completely irreducible operators are different from properties of unicellular operators. __________ Translated from Acta Sci. Nat. Univ. Jilin, 1992, (4): 20–29     

Propagation of the Hermite–Gaussian beams through misaligned optical system with a circular aperture

By means of expanding a hard-edged aperture into a finite sum of complex Gaussian functions, the approximate analytical formula of one kind of higher-order Gaussian beams called the Hermite–Gaussian beams (HGBs) passing through circular apertured and misaligned optical system is obtained in this paper. The result provides more convenience for studying its propagation than the usual way by using diffraction integral directly. Some numerical simulations are also given for illustrating the propagation properties of the HGBs through the circular apertured optical systems.     

用AD590自组数字温度计的设计实验

本介绍了用ADS90自组数字温度计实验，说明了实验步骤和数据处理等过程。     

一种不等带宽光学梳状滤波器

提出了一种新型—Michelson—三面镜FabryPerot型50GHz不等带宽光学梳状滤波器设计方案,分析和模拟表明:该器件将一路信道间隔为50GHz的输入信号分离成信道间隔为100GHz的奇偶两路输出信号,其中在3dB处,奇数信道带宽大于30GHz用于10Gb/s传输,偶数信道带宽大于60GHz用于40Gb/s传输对于将来的40Gb/s系统,该器件具有优势.     

Co-P非晶态合金电子性质和局域结构的理论研究

根据Co P非晶态合金结构的短程有序和结构中可能存在P -P相互作用的实验事实 ,选择了单磷原子簇模型ConP(n =1～ 5 )和双磷原子簇模型ConP2 (n =1～ 4 ) ,用密度泛函理论方法对其进行计算 .结果表明 ,在单磷Co2 P( 2 ) 、Co3 P( 1) 及Co4P( 2 ) 模型体系中 ,Co原子供给P原子电子 ,与电负性规则一致 ,同时Co和P之间具较强化学作用 ,可以形成稳定的原子簇 ;而在双磷和单磷原子簇Co5P( 1) 模型体系中 ,形成的原子簇不稳定 ,采用单磷Co2 P( 2 ) 、Co3 P( 1) 及Co4P( 2 ) 模型能较好地反映Co P非晶态合金的结构特点 .