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81.
82.
Influence of buffer layer thickness on the structure and optical properties of ZnO thin films 总被引:1,自引:0,他引:1
A series of ZnO thin films were deposited on ZnO buffer layers by DC reactive magnetron sputtering. The buffer layer thickness determination of microstructure and optical properties of ZnO films was investigated by X-ray diffraction (XRD), photoluminescence (PL), optical transmittance and absorption measurements. XRD results revealed that the stress of ZnO thin films varied with the buffer layer thickness. With the increase of buffer layer thickness, the band gap edge shifted toward longer wavelength. The near-band-edge (NBE) emission intensity of ZnO films deposited on ZnO buffer layer also varied with the increase of thickness due to the spatial confinement increasing the Coulomb interaction between electrons and holes. The PL measurement showed that the optimum thickness of the ZnO buffer layer was around 12 nm. 相似文献
83.
在平均场理论架构下, 以含时金兹堡-朗道和Glauber动力学这两类动态模型为基础,研究 了受外场和温度共同驱动的Ising自旋体系的非平衡动态相变.确定了界定动态无序(动态顺 磁相P)和动态有序(动态铁磁相F)转变的动态相界.并根据动态序参量Q和Binder参数U随系统 温度t(r0)、驱动外场频率ω和振幅h0的变化规律,就上述两类模 型的动态相界上是否存在区分连续动态转变和非连续动态转变的三临界点这一引发争议的问 题做出了进一步分析说明.
关键词:
Ising自旋体系
非平衡动态相变
含时金兹堡-朗道模型
Glauber 动力学模型 相似文献
84.
I Cserpan M Kalman M L Tj?rnhammar A Simoncsits 《Acta chemica Scandinavica (Copenhagen, Denmark : 1989)》1991,45(3):265-272
A general method to convert single-stranded, chemically synthesized oligonucleotides into cloned duplexes is described. Oligonucleotides supplied with 3'-terminal extensions that are complementary to 3'-protruding ends obtained by certain restriction enzymes can be cloned either directly or with the help of an adapter molecule into double-stranded vectors. Two methods have also been developed for consecutive cloning applications. According to these methods, the synthetic oligonucleotides (and their enzymatically prepared complementary strands) are joined, one after the other, inside a cloning vector, each joining requiring one cloning step. Synthetic genes are thus built up from oligonucleotides corresponding to only one strand of the DNA. The sequential assembly of the cloned duplex takes place in the 5' to 3' direction. Each oligonucleotide is supplied with a four-nucleotide-long 3'-terminal extension, but this sequence is eliminated when the joining takes place, leaving no limiting sequence between the oligonucleotides. The two consecutive cloning methods, the adapter and the polycloning site methods, are illustrated by the assembly of short artificial genes. 相似文献
85.
Summary Glass formation in nature and materials science is reviewed and the recent recognition of polymorphism within the glassy state,
polyamorphism, is discussed. The process by which the glassy state originates during the continuous cooling or viscous slowdown
process, is examined and the three canonical characteristics of relaxing liquids are correlated through the fragility. The
conversion of strong liquids to fragile liquids by pressure-induced coordination number increases is discussed, and then it
is shown that for the same type of system it is possible to have the same conversion accomplished via a first-order transition
within the liquid state. The systems in which this can happen are of the same type which exhibit polyamorphism, and the whole
phenomenology can be accounted for by a recent simple modification of the van der Waals model for tetrahedrally bonded liquids.
The concept of complex amorphous systems which can lose a significant number of degrees of freedom through weak first-order
transitions is then used to discuss the relation between native and denatured hydrated proteins, since the latter have much
in common with plasticized chain polymer systems. Finally, we close the circle by taking a short-time-scale phenomenon given
much attention by protein physicists,viz., the onset of an anomaly in the Debye-Waller factor with increasing temperature, and showing that for a wide variety of liquids,
including computer-simulated strong and fragile ionic liquids, this phenomenon is closely correlated with the experimental
glass transition temperature. This implies that the latter owes its origin to the onset of strong anharmonicity in certain
components of the vibrational density of states (evidently related to the boson peak) which then permits the system to gain
access to its configurational degrees of freedom. The more anharmonic these vibrational components, the closer to the Kauzmann
temperature will commence the exploration of configuration space and, for a given configurational microstate degeneracy, the
more fragile the liquid will be.
Paper presented at the I International Conference on Scaling Concepts and Complex Fluids, Copanello, Italy, July 4–8, 1994. 相似文献
86.
Optical properties and microstructure of Ag film on glass substrate with Cr intermediate layer were studied by using spectrophotometer and XRD. The spectra results showed that introducing Cr intermediate layer reduced the surface roughness and promoted the reflectivity of Ag film. The XRD analysis showed that the crystalline grains increased and the stress decreased. The adhesion was also improved by using the tape test method. 相似文献
87.
The effect of γ-ray irradiation on the magnetic properties of NdFeB and Fe–Cr–Co permanent magnets has been investigated. The magnetic flux loss of two kinds of magnets before and after irradiation was measured. Results show that the effect of γ-ray irradiation on the magnetic properties of sintered NdFeB is not so obvious as that on Fe–Cr–Co magnet. Irradiation-induced damage from γ-ray for the Fe–Cr–Co magnets was characterized for the first time. The decline of permanent magnetic properties of Fe–Cr–Co magnet induced by γ-ray irradiation is reversible except for the maximum energy product (BH)max. The difference of coercivity mechanism between these two kinds of permanent magnets is responsible for the different dependence of magnetic properties loss induced by γ-ray irradiation. 相似文献
88.
Andrzej Wi?nicki 《Journal of Mathematical Analysis and Applications》2002,267(1):158-172
We use a newly introduced concept of neocompactness to study problems from metric fixed point theory. In particular, we give a sufficient condition for a superreflexive Banach space X to have the fixed point property and obtain shorter proofs of some well-known results in that theory. 相似文献
89.
90.
巯基乙酸锑配合物的合成与X射线粉末衍射数据指标化 总被引:2,自引:0,他引:2
一些锑和铋的配合物可以应用于医药研究[1,2 ] ,已合成了许多锑的有机配体配合物[3~ 7] ,但其中大多数没有生物活性。因此 ,研究锑或铋离子的配合物不仅对主族元素化学、生物无机化学而且对医药都有着非常重要的意义。我们用三氯化锑与巯基乙酸液相反应法合成的二巯基乙酸锑 (Ⅲ)配合物 ,其组成为HSb(SCH2 COO) 2 ,用X射线粉末多晶衍射数据指标化来研究配合物晶体结构[8] 。1 实验部分1 1 仪器与试剂EA - 1 1 0 6型元素分析仪 (意大利卡拉欧巴公司制造 ) ,D Max -YB型多晶X射线粉末衍射仪(日本理学 ,CuKα射线 ,… 相似文献