全文获取类型
收费全文 | 2890篇 |
免费 | 337篇 |
国内免费 | 204篇 |
专业分类
化学 | 2191篇 |
晶体学 | 29篇 |
力学 | 152篇 |
综合类 | 6篇 |
数学 | 282篇 |
物理学 | 771篇 |
出版年
2024年 | 9篇 |
2023年 | 109篇 |
2022年 | 137篇 |
2021年 | 153篇 |
2020年 | 183篇 |
2019年 | 203篇 |
2018年 | 175篇 |
2017年 | 129篇 |
2016年 | 196篇 |
2015年 | 186篇 |
2014年 | 210篇 |
2013年 | 262篇 |
2012年 | 295篇 |
2011年 | 279篇 |
2010年 | 181篇 |
2009年 | 141篇 |
2008年 | 151篇 |
2007年 | 126篇 |
2006年 | 88篇 |
2005年 | 53篇 |
2004年 | 30篇 |
2003年 | 15篇 |
2002年 | 26篇 |
2001年 | 6篇 |
2000年 | 15篇 |
1999年 | 10篇 |
1998年 | 11篇 |
1997年 | 7篇 |
1996年 | 8篇 |
1995年 | 8篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1990年 | 7篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1985年 | 4篇 |
1979年 | 1篇 |
排序方式: 共有3431条查询结果,搜索用时 69 毫秒
21.
Separation and determination of ephedrine alkaloids and tetramethylpyrazine in Ephedra sinica Stapf by gas chromatography-mass spectrometry 总被引:1,自引:0,他引:1
A simple, sensitive, and reliable method using gas chromatography (GC)-mass spectrometry (MS) is developed for the simultaneous determination of ephedrine alkaloids and 2,3,5,6-tetramethylpyrazine (TMP) in Ephedra sinica Stapf. The sample is extracted with ethyl ether and submitted to GC-MS for identification and quantitation without derivatization. The column used for GC is an HP-5 (30.0 m x 250 microm x 0.25 microm, 5% phenyl methyl siloxane), and the carrier gas is helium. The detection limits for ephedrine, pseudoephedrine, and TMP are 0.4 ng 0.7 ng, and 0.02 ng (signal-to-noise ratio of 3), respectively. The reproducibility of the total procedure is proved to be acceptable (RSD < 2%), and the recoveries are above 93%. 相似文献
22.
23.
Complete 1H and 13C NMR assignments of four new steroidal glycosides from a gorgonian coral Junceella juncea 总被引:2,自引:0,他引:2
Four new cholest-type steroidal glycosides, junceellosides A-D, isolated from the EtOH/CH(2)Cl(2) extracts of the South China Sea gorgonian coral Junceella juncea, were identified. Complete assignments of the (1)H and (13)C NMR chemical shifts for these compounds were achieved by means of one- and two-dimensional NMR techniques, including (1)H-(1)H COSY, HSQC, HMBC and NOESY spectra. 相似文献
24.
Mathematical Notes - The Boros–Moll polynomials $$P_m(a)$$ arise in the evaluation of a quartic integral. In the past few years, there has been some remarkable research on the properties of... 相似文献
25.
Transition metal-catalyzed carbene transfer reaction is one of the most notable advances for C-C bond formation reactionsduring the past decade,which has been widely employed in the preparation of C3-substituted indoles,Here,we described an efficient exa mple of catalyst-and metal-free aminobo ration of alkynes and C—C bond formation with diazo compounds to produce C3-substituted indoles,Diverse alkynyla nilines and diazo compounds ca n be utilized for this tandem transfo rmation under mild reaction conditions,re sulting in broad functional group co mpatibility.Additionally,this metal-free strategy can be extended to construct substituted benzofurans. 相似文献
26.
27.
28.
Bixing Fang Lina Dong Xingwei Ding YingZi Ren Zhongsheng Lv Kuan Liu Feng Zhang Wei Zhang Jianjian Deng Hongbo Xin Xiaolei Wang 《中国化学快报》2019,30(6):1178-1181
Black fungus aerogel (BFA) exhibited interesting double-faced properties. Weexplored the diverse properties of each side of the black fungus in three aspects:water contact angle measurements, liquid selective absorption capacity and air pollutant adsorption abilities. 相似文献
29.
Youheng Shi Zhihui Zhang 《Journal of inclusion phenomena and macrocyclic chemistry》1994,18(2):137-147
The interactions ofp-tert.-butylcalix[4]arene bearing polyoxyethylene chains (C3) with pyrene (Py), 1-anilino-8-naphthalenesulfonate (ANS) andN-phenyl-naphthylamine (NPN) in aqueous solution were studied by absorption and fluorescence measurements. Absorption spectral changes and fluorescence enhancements reveal that C3, which has a hydrophobic cavity, can include organic molecules and ions in aqueous solution and form 11 host-guest complexes with ANS and NPN. C3 forms inclusion complexes with Py at different stoichiometries depending on the host: guest molar ratio. Binding constants of 2.2×104, 2.0×104 and 3.6×105 dm3 mol–1 were calculated for the C3Py, C3ANS and C3NPN complexes (11), respectively, based on the Benesi-Hildebrand equation.Author for correspondence. 相似文献
30.
Xue-Chuan Lv Zhi-Cheng Tan Xiao-Han Gao Zhi-Heng Zhang Li-Ni Yang Jun-Ning Zhao Li-Xian Sun Tao Zhang 《Thermochimica Acta》2006,450(1-2):102-104
A metal-organic complex, which has the potential property of absorbing gases, [LaCu6(μ-OH)3(Gly)6im6](ClO4)6 was synthesized through the self-assembly of La3+, Cu2+, glycine (Gly) and imidazole (Im) in aqueous solution and characterized by IR, element analysis and powder XRD. The molar heat capacity, Cp,m, was measured from T = 80 to 390 K with an automated adiabatic calorimeter. The thermodynamic functions [HT − H298.15] and [ST − S298.15] were derived from the heat capacity data with temperature interval of 5 K. The thermal stability of the complex was investigated by differential scanning calorimetry (DSC). 相似文献