La2O3对CuO/CeO2水煤气变换反应催化剂微观结构及催化性能的影响（英文）

以La2O3为助剂,采用共沉淀法制备了具有良好催化活性和热稳定性的CuO/CeO2-La2O3水煤气变换反应催化剂,其中,当La2O3含量为2wt%时,催化剂的催化性能最为优异.同时运用X射线衍射、N2吸附-脱附、Raman光谱、程序升温还原等手段,研究了不同含量的La2O3对CuO/CeO2催化剂微观结构及催化性能的影响.结果表明,La2O3助剂进入了载体CeO2的晶格并对CuO/CeO2催化剂的微观结构和催化性能产生了直接影响,适量La2O3的添加可以抑制CuO和CeO2晶格的长大、增强CuO与CeO2间的相互作用、提高催化剂的比表面积、促进CeO2载体中生成更多的氧空位,CuO/CeO2催化剂的催化活性和热稳定性也明显改善.     

水下高速目标对转螺旋桨空化线谱频率理论预报

水下高速目标对转螺旋桨常工作在空化状态,其噪声线谱由前后桨相互作用及前后桨与船舶尾流场的相互作用引起。通过Goldstein的声相似方程,将空泡看作螺旋桨的一部分,对空化条件下水下对转螺旋桨的线谱频率进行了理论预报。推导出了远场条件下单极子源性质的声源所产生的声压表达式,得到了其线谱预报频率。对实测水下高速目标进行了线谱预报,通过比较发现预报值与实测线谱频率具有较高的吻合度。     

低光泽度印刷色谱色貌数据组的建立与评价

色貌预测是现代颜色科学领域的基本理论和技术。为了评价低光泽度彩色印刷色谱的色貌,以丽印胶版纸印制的彩色印刷色谱为研究对象,根据颜色科学和心理物理学相关实验,建立其色貌参数样本数据组。采用相对系数R2和差异系数CV等数理统计方法,评价这种印刷色谱中Y-M内页在三种不同的照明光源下色貌的视觉评估结果。实验数据分析表明,在D65、A和TL84三种光源中,人眼在A光源下对颜色的识别能力明显不同于D65和TL84光源;同样在这三种光源中人眼对明度和色调的评估准确度最高,彩度最差。     

Nickel-catalyzed C-H direct amination of benzoxazoles with secondary amines

In this article, a facile, efficient and practical method for Ni-catalyzed direct C-H amination of benzoxazole with secondary amines has been developed. This procedure requires Ni(OAc)(2)·4H(2)O as catalyst, TBHP as oxidant and acid as the additive. A variety of substituted benzoxazol-2-amines were synthesized in moderate to good yields.     

化学探究学习活动设计组织刍议

比较、分析关于"氯气与水的反应、氯水的成分"的2个化学探究学习活动设计与组织方案,阐述化学探究学习活动设计、组织的指导思想,设计组织策略、方法上应注意的问题.     

橡胶门尼粘度标准物质的研制

介绍橡胶门尼粘度标准物质的研制过程。该标准物质的均匀性、稳定性良好,定值准确可靠,符合JJG1006－94的要求。     

顶空气相色谱法测定甲氧苄啶中的残留丙烯腈

采用顶空进样模式,以HP-624毛细管色谱柱为分离柱,二甲亚砜为溶剂,氮气作载气,FID为检测器,用气相色谱法测定甲氧苄啶中的残留丙烯腈。丙烯腈的线性范围为0．25～200．10μg,相关系数为0．9999,检出限为0.05μg,测定结果的相对标准偏差为3．4％,平均回收率为100．5％。     

Cobalt(II)–catalyzed C8H alkoxylation of 1-naphthylamine derivatives with alcohols

An efficient protocol for cobalt (II)-catalyzed regioselective aryl C8H bond alkoxylation of 1-naphthylamine derivatives with readily available alcohols has been developed, demonstrating an efficient approach to 8-alkoxy-1-naphthylamine derivatives with good functional group tolerance. Note that the picolinamide moiety as a bidentate directing group may play a key role in this regioselective transformation.     

Manipulating electronic and magnetic properties of black phosphorene with 4d series transition metal adsorption

We carry out first-principles calculations within density-functional theory to investigate the structural, electronic and magnetic properties of 4d transition metal (TM) decorated monolayer black phosphorene (BP). The results indicate that the TM adsorption on BP can have dilute magnetic semiconductor (DMS) properties. The spin polarized semiconducting state is realized in BP by adsorption of Y, Nb and Ru, while a half-metal state is obtained by Tc adsorption. In the case of two same types of TMs adsorption on BP, only [email protected] shows DMS state. In particular, two different types of TMs decorated BP can induce magnetic moments, localized mainly on the 4d TMs and the neighboring P atoms. Furthermore, the 4d TMs may enrich the electronic properties of BP, such as half-metallic, metallic and semiconducting features. These findings suggest that the 4d TM adsorbed BP can be used as a potential next-generation spintronics and magnetic storage material.     

红外光谱法测定环氧树脂的环氧值

介绍了用红外光谱法测定环氧树脂的原理、试验条件和允许差,以及该方法在环氧树脂及其预浸料质量控制方面的应用。