巯基乙酸锑配合物的合成与X射线粉末衍射数据指标化

一些锑和铋的配合物可以应用于医药研究[1,2 ] ,已合成了许多锑的有机配体配合物[3～ 7] ,但其中大多数没有生物活性。因此 ,研究锑或铋离子的配合物不仅对主族元素化学、生物无机化学而且对医药都有着非常重要的意义。我们用三氯化锑与巯基乙酸液相反应法合成的二巯基乙酸锑 (Ⅲ)配合物 ,其组成为ＨＳｂ(ＳＣＨ2 ＣＯＯ) 2 ,用Ｘ射线粉末多晶衍射数据指标化来研究配合物晶体结构[8] 。1　实验部分1 1　仪器与试剂ＥＡ - 1 1 0 6型元素分析仪 (意大利卡拉欧巴公司制造 ) ,Ｄ Ｍａｘ -ＹＢ型多晶Ｘ射线粉末衍射仪(日本理学 ,ＣｕＫα射线 ,…     

The limits of hamiltonian structures in three-dimensional elasticity,shells, and rods

Summary This paper uses Hamiltonian structures to study the problem of the limit of three-dimensional (3D) elastic models to shell and rod models. In the case of shells, we show that the Hamiltonian structure for a three-dimensional elastic body converges, in a sense made precise, to that for a shell model described by a one-director Cosserat surface as the thickness goes to zero. We study limiting procedures that give rise to unconstrained as well as constrained Cosserat director models. The case of a rod is also considered and similar convergence results are established, with the limiting model being a geometrically exact director rod model (in the framework developed by Antman, Simo, and coworkers). The resulting model may or may not have constraints, depending on the nature of the constitutive relations and their behavior under the limiting procedure. The closeness of Hamiltonian structures is measured by the closeness of Poisson brackets on certain classes of functions, as well as the Hamiltonians. This provides one way of justifying the dynamic one-director model for shells. Another way of stating the convergence result is that there is an almost-Poisson embedding from the phase space of the shell to the phase space of the 3D elastic body, which implies that, in the sense of Hamiltonian structures, the dynamics of the elastic body is close to that of the shell. The constitutive equations of the 3D model and their behavior as the thickness tends to zero dictates whether the limiting 2D model is a constrained or an unconstrained director model. We apply our theory in the specific case of a 3D Saint Venant-Kirchhoff material andderive the corresponding limiting shell and rod theories. The limiting shell model is an interesting Kirchhoff-like shell model in which the stored energy function is explicitly derived in terms of the shell curvature. For rods, one gets (with an additional inextensibility constraint) a one-director Kirchhoff elastic rod model, which reduces to the well-known Euler elastica if one adds an additional single constraint that the director lines up with the Frenet frame. This paper is dedicated to the memory of Juan C. Simo This paper was solicited by the editors to be part of a volume dedicated to the memory of Juan Simo.     

质量控制图原理在股票投资组合中的应用研究

质量控制图是用来控制生产过程质量的一种统计方法。其基本理论方法应用到股票投资组合中,可以降低投资风险,提高投资组合的收益率。通过实证研究表明:利用质量控制图原理来确定投资组合的选股、买点和卖点,可以使投资组合获得明显高于大盘指数的收益率,从而验证了质量控制图的基本理论方法完全可以应用于股票投资决策,并且具有显著的实际应用价值。     

Modification to the Fringe Component of Diffraction Coefficient in TD-EEC Method

A modified formulation for fringe component of diffraction coefficient is implemented to TD-EEC method. An example of diffraction by perfectly conducting plate is used to illustrate our scheme. Comparing with the FDTD results we observe that the improved expression for fringe component is more accurate than that of Michaeli's formulation. This high frequency time domain technique is available for treating the bistatic scattering problems for millimeter waves.     

Circuit analysis of the compound quasi-optical power combiner

In 1991, we developed a new type of quasi-optical power combiner, called a compound quasi-optical power combiner, at Ka-band. In this paper, the circuit of such a compound quasi-optical power combiner is analysed. Its equivalent circuit model is proposed. The circuit equations, the balance condition, the injection locking and the stabilized condition of the compound quasi-optical power combiner are studed by the equivalent circuit model. As an example, a compound quasi-optical power combiner which consists of two single—cavity, two—device power combiners is analysed     

三维内肋管内插入螺旋扭带的强化传热实验

本文分别以水和乙二醇为工质，在Ｒｅ数范围为：６００～４００００，Ｐｒ数范围为：５．５～１１０之间，对四根分别插入三种不同扭率螺旋扭带的三维内助管内的换热和流阻特性进行了实验研究。结果表明：三维内肋管内加装扭带的强化传热技术适用于低Ｒｅ数下高Ｐｒ数工质的管内对流换热强化。根据实验值得到了流阻和换热关联式。     

Studies on toxicological mechanisms of gas-phase cigarette smoke and protection effects of GTP

Gas-phase cigarette smoke (GPCS) was able to induce lipid peroxidation in lecithin liposomes, rat liver microsomes, and rat lung cells (RLC), and change the membrane fluidity of RLCs. Lipid free radicals were trapped in a GPCS-treated microsomal suspension by using 4-POBN as the spin trap. In addition, it was found that GPCS-peroxidized liposomes in appropriate degree of lipid peroxidation had the ability to increase the generation of superoxide anions in rat peritoneal neutrophils (RPN). Effects of green tea polyphenols (GTP) on the GPCS-induced damages were investigated The results showed that GTP was capable of inhibiting the GPCS-induced damages.     

关于修正的Baskakov算子的Stechin-Marchaud型不等式

利用K-泛函研究了修正的Baskakov型算子的Stechin-Marchaud型不等式,由此不等式,我们得到了关于ω2φλ的逆结果.     

动态光散射实验

动态光散射技术是测量纳米及亚微米颗粒粒径的有效方法．本文介绍了动态光散射实验的原理、实验装置及方法，并测量了粒径为85nm的聚苯乙烯水溶液的粒径，分析了实验产生误差的原因．     

催化动力学测定痕量砷(Ⅲ)

在醋酸介质中,发现痕量砷(Ⅲ)能灵敏地催化高碘酸钾氧化靛红la褪色的指示反应,研究了该催化反应的最佳条件与动力学参数,建立了一种新的测定痕量砷(Ⅲ)的方法。该法的线性范围0.0-40μg/LAs(Ⅲ),检测限为1.92×10-6g/L,用于环境水样中砷(Ⅲ)的测定,获得了满意的结果。