大一学生化学实验室安全基础知识调查研究*

为考察大一学生化学实验室安全基础知识,对天津理工大学化学化工学院大一学生警示标识、危险化学品性质、废弃物处理及意外处置等安全知识进行问卷调查。结果表明:60.4%的学生将易燃标识与氧化剂标识混淆;在危险化学品性质和酸/碱撒漏处理方面有待加强。基于以上结果,在后续安全教育过程中,普及GHS标识及MSDS,对相关知识进行针对性的查漏补缺;充分利用线上资源,弥补线下教育因时间有限、容量有限导致的不足。     

The spreading behaviour of perfluoropolyether droplets on solid surfaces

The spread of perfluoropolyether （PFPE） droplets on solid surfaces has been measured from the top-down view through a microscope system. Effects of substrates, molecular weight and end-group functionality on spreading of the PFPE droplets have been studied experimentally and the results were compared with those by molecular dynamics （MD） simulations. Silicon wafer and diamond-like carbon （DLC） substrates were used to study the effect of substrates on spreading. Two types of PFPE, Z-dol and Z-tetraol, with the same chain structure and various molecular weights （2000 and 4000 g/mol） were employed in experiments. Effect of molecular weight has been investigated through comparing the spreading of Z-dol 2000 and Z-dol 4000, and it is found that the increase of molecular weight will decrease the mobility of PFPE. Comparison between spreading of Z-dol and Z-tetraol of the same molecular weight proved that functional end group plays a significant role on the spreading of PFPE, which confirmed the MD simulation results.     

Carriers recombination processes in charge trapping memory cell by simulation

We have evaluated the effects of recombination processes in a charge storage layer, either between trapped electrons and trapped holes or between trapped carriers and free carriers, on charge trapping memory cell＇s performances by numerical simulation. Recombination is an indispensable mechanism in charge trapping memory. It helps charge convert process between negative and positive charges in the charge storage layer during charge trapping memory programming/erasing operation. It can affect the speed of programming and erasing operations.     

The dynamics of triple-well trapped Bose-Einstein condensates with atoms feeding and loss effects

In this paper, we consider the macroscopic quantum tunnelling and self-trapping phenomena of Bose-Einstein condensates （BECs） with three-body recombination losses and atoms feeding from thermal cloud in triple-well potential. Using the three-mode approximation, three coupled Gross-Pitaevskii equations （GPEs）, which describe the dynamics of the system, are obtained. The corresponding numerical results reveal some interesting characteristics of BECs for different scattering lengths. The self-trapping and quantum tunnelling both are found in zero-phase and ：r-phase modes. Furthermore, we observe the quantum beating phenomenon and the resonance character during the self-trapping and quantum tunnelling. It is also shown that the initial phase has a significant effect on the dynamics of the system.     

Search for exotic state 1-+ π1(1400) at BESⅢ

The J/ψ hadronic decays provide good laboratory to search for the hybrid states with exotic quantum numbers. A full Partial Wave Analysis (PWA) is performed to the generated Monte Carlo J/ψ→ pηπ data, based on the design of BESⅢ detector, to study the sensitivity of searching for a possible exotic state at BESⅢ.     

太阳直射光谱和天空光谱的测量与分析

在海拔9600m高空测量并获得了大气上界直射太阳光谱和天空光谱，测量了成都、丽江和玉龙雪山地表直射太阳光谱和天空光谱.结果表明：(西昌段)大气上界直射太阳光谱能量最大峰值对应的波长位于482.1nm，天空光谱能量分布相对于直射太阳光谱能量分布明显紫移，0.41—0.42μm波段成为天空光谱能量第一主峰区；地表晴天天空光谱中的能量分布与直射太阳光谱的能量分布区别很大，而有云时天空光谱中的能量分布和直射太阳光谱能量分布的差别比较小；玉龙雪山山峰积雪雪面在可见光波段对不同波长有不同的反照率. 关键词： 太阳直射光谱 天空光谱 大气上界     

基于周期极化LiTaO3晶体的高增益简并啁啾脉冲参量放大

根据准相位匹配理论计算了周期极化LiTaO₃(PPLT)晶体中0类准相位匹配过程(e+e→e)的增益曲线.在此基础上，使用数百μJ的低抽运能量获得了～10⁶的增益和～10.3%的转换效率，实现了中心波长位于1064nm的基于简并光学啁啾脉冲参量放大(OPCPA)技术的高增益放大，为产生超短超强激光脉冲提供了新的技术手段.实验结果与理论预期基本符合.     

石墨炉原子吸收光谱法测定土壤中离子交换态的镉

本文研究了石墨炉原子吸收光谱法测定土壤中离子交换态的镉的适宜条件.试样经MgCl2溶液震荡提取离心后,以10%的磷酸二氢铵做基体改进剂,方法检出限为0.03840 μg/L,相对标准偏差(n=6)为0.9231%.本方法具有准确、简便之优点,可用于土壤样品中镉的测定.     

High-Sensitivity Sensor Based on Surface Plasmon Resonance Enhanced Lateral Optical Beam Displacements

We present a new optical sensor based on surface plasmon resonance （SPIt） enhanced lateral optical beam displacements. Compared with the traditional SPIt methods, the new method provides higher sensitivity to the sensor system. Theoretical simulations show that the refractive index （RI） detection sensitivity of the SPR sensor based on the displacement measurement has a strong dependence on the thickness of the metal film. When the optimal thickness of the metal film is selected, the RI resolutlon of the SPIt sensor is predicted to be 2.2 × 10^-7 refractive index units （RIU）. Furthermore, it is found that the incidence angle can be used as a parameter to adjust the operating range of the sensor to different refractive index ranges.     

两相颗粒多孔材料导热系数研究

对固-气两相颗粒多孔材料导热系数的预测,尚未见以实验数据对其各预测模型进行分析及验证其准确度的相关文献。本文利用断电热线法测定石英砂、碳化硅、工程沙以及煤灰的导热系数;将模型预测结果与实验数据进行对比分析,结果表明,Kunii and Smith模型误差小;考虑孔隙率的影响,利用实测数据对Kunii and Smith模型进行修正,给出新的预测模型;通过与国外学者给出的实测导热系数的对比,验证了本文给出的修正模型的准确性。