In situ Synthesis of Oligonucleotides on Plasma Treated Polypropylene Microporous Membrane

Polypropylene microporous membranes were treated with plasma in a mixture of N2 and H2 (1:2 in volume). Attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS) and ultra-violet (UV) spectra demonstrated the success of grafting amino groups. The density of the polar amino groups on the membrane surface is about 0.59 μmol/cm^2. The as-treated membranes were successively applied to the in situ synthesis of oligonucleotides and an average coupling yield was more than 98%. The surface feature of the treated membrane is suggested to be responsible for its advantage over a glass slide.     

卡尔曼滤波紫外光度法同时测定酱油、食醋中的山梨酸和苯甲酸

在酸性条件下，采用乙酸乙酯萃取、Na2HPO4溶液反萃取分离酱汪、食醋中的山梨酸、苯甲酸，卡尔曼滤波法计算结果，并与比值导数波谱法进行比较。结果表明，卡尔曼滤波法较地数波谱法有较高准确度和精密度，并能监测干扰物质存在与否。用于实际样品分析有更高的可靠性。     

两类记录值之和的中心极限定理

该文给出了Ｌｏｇｉｓｔｉｃ分布纪录值序列部分和的中心极限定理；对于Ｐａｒｅｔｏ分布纪录值序列的部分和T_n，获得了ｌｎT_n的中心极限定理．这一工作不仅具有概率论的极限理论方面的研究价值，而且在金融、保险等领域也具有相当重要的应用前景．     

Modeling synchronization and suppression of spontaneous otoacoustic emissions using Van der Pol oscillators: effects of aspirin administration

Many of the aspects of the interaction of spontaneous otoacoustic emissions with external tones (suppression and synchronization) can be qualitatively simulated by the behavior of a single driven Van der Pol oscillator. Analytical and numerical investigations of a model of spontaneous otoacoustic emissions based on such an oscillator (with appropriate parametric changes in the nonlinear and negative damping components) lead to predictions of the nature of the changes in suppression and synchronization (frequency-locking) tuning curves when the levels of spontaneous otoacoustic emissions are modified. Observations of the suppression and synchronization of spontaneous otoacoustic emissions by external tones of different frequencies and levels were obtained while the levels of spontaneous emissions were altered by aspirin administration. Modeling an emission as a single Van der Pol oscillator qualitatively accounts for: (1) the reduction of the level of an external tone required to suppress the emission by a decibel amount equivalent to the level reduction induced by aspirin administration; (2) the broadening of the frequency-locking tuning curve of an emission whose level is reduced; and (3) the pulling of the emission frequency by an external tone. It does not account for: (1) the observed asymmetry in the slopes of the external-tone suppression curves (more gradual for frequencies of the suppressor tone higher, rather than lower, than that of the emission); and (2) the frequency pushing of the emission by an external tone.     

基于CT算法的束团横向相空间测量

精确测量束团的发射度和横向相空间, 在高亮度电子束的产生和应用中具有重要意义. 传统测量方法在测量发射度时需要对束团在相空间内分布进行初始假设, 且只能给出相椭圆的twiss参数;基于CT(computerized tomography)算法的束团横向相空间测量方法无需先验假设, 能给出粒子在相空间内的真实分布, 测量结果更为精确. 介绍了基于CT算法的束团横向相空间测量的原理和初步实验结果, 并与四极透镜扫描法测量的结果进行了比较.     

一种新型手性功能单体的合成

以手性芳胺为母体,丙烯酰氯为酰化试剂,合成了新型手性功能单体(1)。用1合成了一系列手性分子印迹聚合物。1的结构经1H NMR,IR,MS及元素分析确证。     

乌骨鸡磷脂侧链脂肪酸的GC-MS分析

用氯仿:甲醇(2:1)超声提取乌骨鸡总磷脂,丙酮脱油精制后,经皂化、甲酯化处理,应用GC-MS联用技术对其侧链脂肪酸组成进行分析,并以面积归一法,计算各脂肪酸的相对百分含量.结果显示,乌骨鸡总磷脂中含有硬脂酸27.46%、花生四烯酸21.39%、油酸18.22%、亚油酸16.67%、棕榈酸12.13%、二十二碳六烯酸(DHA) 2.26%、二十碳三烯酸1.71%、棕榈油酸0.16%.不饱和脂肪酸和多不饱和脂肪酸的含量分别为60.41%和42.03%.乌骨鸡磷脂侧链脂肪酸中高比例的多不饱和脂肪酸和花生四烯酸含量是乌骨鸡磷脂的显著特征.     

Formation of long range ordered arrangement of quantum dots with the help of lateral centripetal flow

A simple “chimney” method was used to eliminate the voids in an arrangement of quantum dots sized 2 nm on a solid substrate, which resulted in a large well ordered superlattice of area in the order more than 1 μm². Based on the principle of speeding up the interparticle interaction of nanoparticles to overcome the particle-substrate one, a lateral centripetal force originated from a glass tube acting as a chimney in a simple evaporation device is imposed. This method allows the packing process to be controlled in a mechanical force field, that is, with the same nanogold dispersion different patterns on a substrate—from separate dots to an ordered compact monolayer or even a multilayer structure—could be easily obtained.     

海底掩埋物的目标强度和回声信混比

基于两种流体介质中声散射的修正的Kirchhoff近似,导出计算掩埋物回声的近似公式。应用回声计算的板块元方法和底质的地声模型,能够计算任意形状刚性掩埋物的回声特性。海底沉积层的影响主要反映在声波在底质中传播的衰减。界面的作用主要表现在声波经过两次折射或透射产生的损失。计算结果表明,用常规方式探测掩埋物时回声信混比总是很小, 探测是十分困难的。     

Dynamic behavior of discrete-time multiagent systems with general communication structures

In this paper, we discuss the dynamic behavior of networks of dynamic agents with general communication topologies. We first analyze the basic case: systems with communication topologies that have spanning trees, i.e., the systems that solve consensus problems. We establish an algebraic condition to characterize each agent's contributions to the final state. And we also study the influence of time-delays on each agent's contributions. Then, we investigate the general case: systems with weakly connected topologies. By using matrix theory, we prove that the states of internal agents will converge to a convex combination of boundary agents in the absence or presence of communication time-delays, and we also show that the coefficients of the convex combination are independent of time-delays even if the delays are time-varying. These results have broad applications in other areas, e.g., study of swarm behavior, formation control of vehicles, etc.