全文获取类型
收费全文 | 477篇 |
免费 | 23篇 |
专业分类
化学 | 361篇 |
晶体学 | 6篇 |
力学 | 2篇 |
数学 | 20篇 |
物理学 | 111篇 |
出版年
2021年 | 4篇 |
2020年 | 4篇 |
2019年 | 3篇 |
2018年 | 9篇 |
2017年 | 2篇 |
2016年 | 8篇 |
2015年 | 16篇 |
2014年 | 13篇 |
2013年 | 28篇 |
2012年 | 30篇 |
2011年 | 32篇 |
2010年 | 16篇 |
2009年 | 12篇 |
2008年 | 32篇 |
2007年 | 33篇 |
2006年 | 33篇 |
2005年 | 31篇 |
2004年 | 24篇 |
2003年 | 19篇 |
2002年 | 21篇 |
2001年 | 15篇 |
2000年 | 8篇 |
1999年 | 6篇 |
1998年 | 5篇 |
1997年 | 8篇 |
1996年 | 4篇 |
1994年 | 3篇 |
1993年 | 4篇 |
1991年 | 6篇 |
1989年 | 10篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1986年 | 8篇 |
1985年 | 6篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 4篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1974年 | 4篇 |
1973年 | 4篇 |
1970年 | 3篇 |
1968年 | 2篇 |
1967年 | 1篇 |
1966年 | 1篇 |
1938年 | 2篇 |
排序方式: 共有500条查询结果,搜索用时 15 毫秒
71.
Lee V. Ya. Gapurenko O. A. Minkin V. I. Horiguchi S. Sekiguchi A. 《Russian Chemical Bulletin》2016,65(4):1139-1141
Russian Chemical Bulletin - [2+2] Cycloadduct of the titanium silylidene Cp2Ti(thf)=Si[Si3(SiMeBut 2)4] and acetylene was readily prepared, isolated, and characterized by NMR spectroscopy and... 相似文献
72.
73.
74.
75.
Osamu Sekiguchi Takuya Masuda Susumu Tajima Nico M. M. Nibbering 《Journal of the American Society for Mass Spectrometry》1998,9(10):1029-1034
The metastable decompositions of trimethylsilylmethanol, (CH3)3SiCH2OH (MW: 104, 1) and methoxytrimethylsilane, (CH3)3SiOCH3 (MW: 104, 2) upon electron ionization have been investigated by use of mass-analyzed ion kinetic energy (MIKE) spectroscopy and D labeling. The metastable ions of 1 ·+ decompose to give the fragment ions m/z 89 (CH 3 · loss) and 73 (·CH2OH loss), whereas those of 2 ·+ only yield the fragment ion m/z 89 (CH 3 · loss). The latter fragment ion is generated by loss of a methyl radical from the trimethylsilyl group via a simple cleavage reaction as shown by D labeling. However, the fragment ions m/z 89 and 73 from 1 ·+ are generated following an almost statistical exchange of the original methyl and methylene hydrogen atoms in the molecular ion as shown also by D labeling. This exchange indicates a complex rearrangement of the molecular ion of 1 ·+ prior to metastable decomposition for which as key step a 1,2-trimethylsilyl group migration from carbon to oxygen is suggested. A different behavior is also found between the source-generated m/z 89 ions from 1 ·+ which decompose in the metastable time region to give ions m/z 61 by loss of ethylene and those from 2 ·+ which decompose in the metastable region to yield ions m/z 59 by elimination of formaldehyde. 相似文献
76.
77.
Masaaki Ichinohe Tadahiro Matsuno Akira Sekiguchi 《Angewandte Chemie (International ed. in English)》1999,38(15):2194-2196
Red-orange crystals of cyclotrisilene 3 were obtained by the reaction of the dibromotrisilane 1 and the tribromodisilane 2 with sodium in toluene [Eq. (1)]. The X-ray crystal structure of 3 shows that the three-membered ring is almost an isosceles triangle and has a twisted Si−Si double bond with a length of 2.138(2) Å. 相似文献
78.
A protocol for searching the most probable phase‐retrieved maps in coherent X‐ray diffraction imaging by exploiting the relationship between convergence of the retrieved phase and success of calculation 下载免费PDF全文
Yuki Sekiguchi Saki Hashimoto Amane Kobayashi Tomotaka Oroguchi Masayoshi Nakasako 《Journal of synchrotron radiation》2017,24(5):1024-1038
Coherent X‐ray diffraction imaging (CXDI) is a technique for visualizing the structures of non‐crystalline particles with size in the submicrometer to micrometer range in material sciences and biology. In the structural analysis of CXDI, the electron density map of a specimen particle projected along the direction of the incident X‐rays can be reconstructed only from the diffraction pattern by using phase‐retrieval (PR) algorithms. However, in practice, the reconstruction, relying entirely on the computational procedure, sometimes fails because diffraction patterns miss the data in small‐angle regions owing to the beam stop and saturation of the detector pixels, and are modified by Poisson noise in X‐ray detection. To date, X‐ray free‐electron lasers have allowed us to collect a large number of diffraction patterns within a short period of time. Therefore, the reconstruction of correct electron density maps is the bottleneck for efficiently conducting structure analyses of non‐crystalline particles. To automatically address the correctness of retrieved electron density maps, a data analysis protocol to extract the most probable electron density maps from a set of maps retrieved from 1000 different random seeds for a single diffraction pattern is proposed. Through monitoring the variations of the phase values during PR calculations, the tendency for the PR calculations to succeed when the retrieved phase sets converged on a certain value was found. On the other hand, if the phase set was in persistent variation, the PR calculation tended to fail to yield the correct electron density map. To quantify this tendency, here a figure of merit for the variation of the phase values during PR calculation is introduced. In addition, a PR protocol to evaluate the similarity between a map of the highest figure of merit and other independently reconstructed maps is proposed. The protocol is implemented and practically examined in the structure analyses for diffraction patterns from aggregates of gold colloidal particles. Furthermore, the feasibility of the protocol in the structure analysis of organelles from biological cells is examined. 相似文献
79.
结合氢在GaN中的扩散特性,运用阴极荧光(CL)谱,对氢化前后低能电子束辐照下GaN带边发光强度的演变进行了研究.实验发现,氢化前GaN在低能电子束辐照下带边发光强度呈现衰减的趋势,而氢化后带边发射强度先上升后衰减,而且氢化后的衰减比氢化前弱.1 h辐照过程中,氢化后GaN带边发光强度的变化比氢化前要小很多.另外,实验中发现经过氢化处理的GaN在辐照后20 h内没有观察到带边发射强度的恢复.研究表明氢原子在GaN中可以钝化缺陷来增强发光,但这种钝化缺陷的作用必须通过克服高的扩散势垒来实现,而低能电子束可以
关键词:
阴极荧光
低能电子束
氢化
演变 相似文献
80.
Ryuta Nishida Katsuyoshi Kakinuma Hanako Nishino Takeo Kamino Hisao Yamashita Masahiro Watanabe Hiroyuki Uchida 《Solid State Ionics》2009,180(14-16):968-972
Aiming at SOFC anode applications, we have synthesized nanometer-sized nickel catalysts supported on hollow spherical particles of samaria-doped ceria (Ni/SDC) by spraying a mixed solution of nickel, samarium, and cerium nitrates into an atmospheric pressure plasma. The as-prepared particles consisted of SDC (average diameter dSDC = ca. 0.8 µm) and uniformly dispersed nanometer-sized NiO particles. When reduced in H2 at 800 °C or 1000 °C, Ni nanoparticles (average diameter dNi = 34 nm) were found to be embedded uniformly into the SDC surface. 相似文献