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991.
Lin Yu Leiyang Lv Zihang Qiu Zhangpei Chen Ze Tan Yu‐Feng Liang Chao‐Jun Li 《Angewandte Chemie (International ed. in English)》2020,59(33):14009-14013
We have developed an unprecedented Pd‐catalyzed formal hydroalkylation of alkynes with hydrazones, which are generated in situ from naturally abundant aldehydes, as both alkylation reagents and hydrogen donors. The hydroalkylation proceeds with high regio‐ and stereoselectivity to form (Z)‐alkenes, which are more difficult to generate compared to (E)‐alkenes. The reaction is compatible with a wide range of functional groups, including hydroxy, ester, ketone, nitrile, boronic ester, amine, and halide groups. Furthermore, late‐stage modifications of natural products and pharmaceutical derivatives exemplify its unique chemoselectivity, regioselectivity, and synthetic applicability. Mechanistic studies indicate the possible involvement of Pd‐hydride intermediates. 相似文献
992.
Hai‐Dong Xia Zhong‐Liang Li Qiang‐Shuai Gu Xiao‐Yang Dong Jia‐Heng Fang Xuan‐Yi Du Li‐Lei Wang Xin‐Yuan Liu 《Angewandte Chemie (International ed. in English)》2020,59(39):16926-16932
We describe a photoinduced copper‐catalyzed asymmetric radical decarboxylative alkynylation of bench‐stable N‐hydroxyphthalimide(NHP)‐type esters of racemic alkyl carboxylic acids with terminal alkynes, which provides a flexible platform for the construction of chiral C(sp3)?C(sp) bonds. Critical to the success of this process are not only the use of the copper catalyst as a dual photo‐ and cross‐coupling catalyst but also tuning of the NHP‐type esters to inhibit the facile homodimerization of the alkyl radical and terminal alkyne, respectively. Owing to the use of stable and easily available NHP‐type esters, the reaction features a broader substrate scope compared with reactions using the alkyl halide counterparts, covering (hetero)benzyl‐, allyl‐, and aminocarbonyl‐substituted carboxylic acid derivatives, and (hetero)aryl and alkyl as well as silyl alkynes, thus providing a vital complementary approach to the previously reported method. 相似文献
993.
Kai Wu Liang‐Liang Wu Cong‐Ying Zhou Chi‐Ming Che 《Angewandte Chemie (International ed. in English)》2020,59(37):16202-16208
A transition‐metal‐free C(sp2)?C(sp2) bond formation reaction by the cross‐coupling of diazo quinones with catechol boronic esters was developed. With this protocol, a variety of biaryls and alkenyl phenols were obtained in good to high yields under mild conditions. The reaction tolerates various functionalities and is applicable to the derivatization of pharmaceuticals and natural products. The synthetic utility of the method was demonstrated by the short synthesis of multi‐substituted triphenylenes and three bioactive natural products, honokiol, moracin M, and stemofuran A. Mechanistic studies and density functional theory (DFT) calculations revealed that the reaction involves attack of the boronic ester by a singlet quinone carbene followed by a 1,2‐rearrangement through a stepwise mechanism. 相似文献
994.
Shan-Shan Guo Xue Pang Yang Wang Zhu-Feng Geng Ju-Qin Cao Jun-Yu Liang 《Natural product research》2020,34(18):2595-2601
AbstractOne new sesquiterpene (α-iso-cubebenol acetate, 8), together with 9 known compounds (1-7, 9, 10) were isolated from the stems of Schisandra chinensis (Turcz.) Baill. by repeated silica gel column chromatography. Based on the results of MS, NMR spectra and comparing with literature data, the six dibenzocyclooctadiene lignans were identified as schizandrin A to C (1-3), schizandrin (4), schisantherin A (5) and gomisin J (6), the two sesquiterpenes were identified as α-iso-cubebenol (7) and α-iso-cubebenol acetate (8), while the two triterpenic acids were identified as ganwuweizic acid (9) and kadsuric acid (10). The antifeedant activity of the 10 compounds against Tribolium castaneum adults was tested. Gomisin J (6) exhibited activity at 1500?ppm concentration with 40.3% antifeeding index percentages. As for the dibenzocyclooctene lignans (compounds 1–3, 6), the number of methylenedioxies and the position of hydroxyl groups were the main factors to affect their antifeedant activities. 相似文献
995.
Fang Yuanxing Zheng Yun Fang Tao Chen Yong Zhu Yaodong Liang Qing Sheng Hua Li Zhaosheng Chen Chuncheng Wang Xinchen 《中国科学:化学(英文版)》2020,63(2):149-181
Photocatalysis,which is the catalyzation of redox reactions via the use of energy obtained from light sources,is a topic that has garnered a lot of attention in recent years as a means of addressing the environmental and economic issues plaguing society today.Of particular interest are photosynthesis can potentially mimic a variety of vital reactions,many of which hold the key to develop sustainable energy economy.In light of this,many of the technological and procedural advancements that have recently occurred in the field are discussed in this review,namely those linked to:(1)photocatalysts made from metal oxides,nitride,and sulfides;(2)photocatalysis via polymeric carbon nitride(PCN);and(3)general advances and mechanistic insights related to TiO2-based catalysts.The challenges and opportunities that have arisen over the past few years are discussed in detail.Basic concepts and experimental procedures which could be useful for eventually overcoming the problems associated with photocatalysis are presented herein. 相似文献
996.
Guozhen Liu Long Cheng Guining Chen Feng Liang Gongping Liu Wanqin Jin 《化学:亚洲杂志》2020,15(15):2364-2370
Mixed matrix membranes (MMMs) made from inorganic fillers and polymers is a kind of promising candidate for gas separation. In this work, two‐dimensional MXene nanosheets were synthesized and incorporated into a polyether‐polyamide block copolymer (Pebax) matrix to fabricate MMM for CO2 capture. The physicochemical properties of MXene nanosheets and MXene/Pebax membranes were studied systematically. The introduction of MXene nanosheets provided additional molecular transport channels and meanwhile enhanced the CO2 adsorption capacity, thereby enhancing both the CO2 peremance and CO2/N2 selectivity of Pebax membrane. The optimized MXene/Pebax membrane with a MXene loading of 0.15 wt % displayed a high separation performance with a CO2 permeance of 21.6 GPU and a CO2/N2 selectivity of 72.5, showing potential application in CO2 capture. 相似文献
997.
Wenxin Xing Liang Zhou Bin Chen Juying Lei Lingzhi Wang Jinlong Zhang 《化学:亚洲杂志》2020,15(17):2749-2753
It's highly significant to develop a novel catalyst, which can be active at a wide range of pH, for an effective photo‐Fenton reaction. In this work, α‐FeOOH?MoO3 nanorod was prepared by a one‐step hydrothermal method and applied in photo‐Fenton degradation of organic pollutants. Benefit from the electron migration mechanism of Z‐scheme and excellent photoelectric performance, the catalyst exhibited superior photo‐Fenton activity in degradation of organic pollutants. In addition, the catalyst holds good stability after 5 recycles. These results demonstrated that this catalyst has wide application prospect in organic wastewater treatment. 相似文献
998.
收缩扩张管内液氮空化流动演化过程试验研究 总被引:1,自引:1,他引:0
本文基于低温空化试验平台研究了收缩扩张流道内液氮非定常空化流动的演化过程. 试验采用高时空分辨率的高速摄像机对77 K液氮在不同空化数σ下空穴结构的演变进行了精细化的分析和研究. 利用试验得到的空穴长度和面积等数据, 定量分析了液氮空化流动的非定常特性与时空演变规律. 研究结果表明: (1)在相似来流速度和温度条件下, 随着空化数的减小, 液氮空化流动呈现四种典型流型, 空穴长度在2.5 h以内为初生空化、空穴长度在2.5 h ~ 7.5 h之间为片状空化、空穴长度在7.5 h ~ 15 h之间为大尺度云状空化, 空穴长度超过15 h为双云状空化, 且在大尺度云状空化和双云状空化阶段均捕捉到了回射流现象; (2)液氮空化流动从初生空化到双云状空化, 脱落空穴的尺度逐渐增大, 空穴面积脉动的幅值和准周期均有所增加. 同时, 在大尺度云状空化与双云状空化阶段, 喉口处堵塞效应对空化流动的影响显著增强; (3)相比于初生空化, 片状空化、大尺度云状空化以及双云状空化中脱落空穴的移动距离依次增加了0.97倍、2.65倍与2.68倍, 溃灭时间依次增加了1.18倍、3.59倍与4.47倍, 但溃灭速度依次减小了0.10倍、0.20倍与0.30倍. 除此之外, 对于双云状空化阶段, 存在两种显著不同的脱落空穴演化过程. 相似文献
999.
Nonlinear Dynamics - This article investigates the issue of hybrid-triggered control for fuzzy Markov jump system under input saturation. First, a hybrid-triggered control scheme is presented,... 相似文献
1000.
Yi-Si Feng Hong-Xia Qi Wei-Cheng Wang Yu-Feng Liang Hua-Jian Xu 《Tetrahedron letters》2012,53(23):2914-2917
A novel synthetic protocol for 2-aminophenyl sulfide derivatives via the reactions of benzothiazole with aryl iodides was reported for the first time. The reactions were catalyzed by CuCl with tetrabutylammonium hydroxide as the base and water as the solvent without ligand at 50 °C or room temperature. A variety of aryl iodides underwent the C–S cross-coupling reaction with benzothiazole to afford smoothly the corresponding products in excellent yield. 相似文献