硫化锌掺钴对电子结构和光学性质的影响

根据密度泛函理论对钴掺硫化锌周围的品格进行了结构优化,计算得到了钴杂质周围的晶体结构、电子态密度分布和吸收光谱.计算结果表明,由于Co原子掺入ZnS晶格常数减小,导致晶格畸变;带隙变窄;吸收峰展宽至更长波长区域.     

Large second-order optical nonlinearities of s-triazine derivatives: View from micro molecules to macro crystals

Organic nonlinear optics (NLO) is also called mo-lecular nonlinear optics. In recent years organic mate-rials have been intensively studied because of their large NLO coefficients and structural diversities[1―3]. Second harmonic generation (SHG) is a bas…     

An attempt to differential Galois theory of second order polynomial system and solvable subgroup of M(o)bius transformations

By introducing the conception "relativistic differential Galois group" for the second order polynomial systems, we establish the relation between the conformal relativistic differential Galois group and the subgroup of M(o)bius transformations, and prove that the system is integrable in the sense of Liouville if its conformal relativistic differential Galois group is solvable with a derived length at most 2. Some omissions on the structures of solvable subgroups of M(o)bius transformations at the first author's article published in this journal in 1996 are refreshed in this paper.     

一种蓝色荧光材料的合成

本文设计和合成了一种带有吡唑啉侧链基因的低聚酰胺,可用作蓝色荧光材料。分子中特殊的氢键序列(AADADD)及芳酰胺链可与制着器件所用的高分子基材分子之间的形成较强的作用力,从而将发光基团“铆定”在功能膜中。     

铜基催化剂的结构、物性及其对混合碳四选择加氢反应的催化性能

 用XRD，XPS，SEM和H2－TPR等手段研究了铜基负载型催化剂的结\r\n构和物性及其对混合碳四加氢脱炔的催化性能．结果表明，在负载铜催\r\n化剂中加入一定量的Co可提高催化剂的加氢脱炔活性，而Co含量较少时\r\n加入少量的Ce也能提高催化剂的活性和选择性．Cu和Co之间存在着相互\r\n协同作用，使得活性组分在催化剂表面偏析，CuO在催化剂表面呈非晶\r\n相分散状态，催化剂颗粒粒径变小，催化剂更容易被还原，从而改善了\r\n催化剂的催化性能．     

SYNTHESIS, STRUCTURE AND ELECTROCHEMICAL STUDIES ON SINGLE MoFe_3S_4 AND WFe_3S_4 CUBANE-TYPE CLUSTER COMPOUNDS*

Single cubane-like clusters, MFe_3S_4(R_2dtc)_5 (M=Mo, R_2=—(CH_2)_4—, Bz_2; M=W, R_2=Me_2, —(CH_2)4—; dtc=dialkyldithiocarbamate) were synthesized by assembly reaction of (NH_4)_2MS_4 (M=Mo, W), FeCl_2 with R_2dtcNa (or NH_4) in DMF. The structure, IR, EPR and cyclic voltammogram are described and discussed. MoFe_3S_4(C_4H_8dtc)_5 was also obtained from the conversion of linear cluster Fe(DMF)_6[(FeCl_2)_2MoS_4] in the presence of C_4H_8dtc NH_4. Both clusters MoFe_3S_4(C_4H_8dtc)_4·2C_2H_5CN and WFe_3S_4(C_4H_8dtc)_5·2DMF crystallize in the monoclinic space group C2/c with a=12.544(2), (Mo-cluster), 12.533(4) (W-cluster); b=20.478(4), 20.121(6); c=19.582(7), 19.659(2);β=102.82(2), 102.96(3)°; and Z=4, 4. Their structures were refined to R=0.057 and 0.064 with use of 2690 and 2179 reflections (ι>3Q(I)), respectively. Many similarities in structure for Mo and W clusters indicate that both Mo and W play a very similar role in the clusters.     

伯溴代烷的微波快速合成法

198 6年Ｒ .Ｊ.Ｇｉｇｎｅｒｅ[1 ] 和Ｒ .Ｇｅｄｙｅ[2 ] 首次报道将微波用于有机合成反应以来 ,大量实验事实证明[3] 微波不仅能极大地提高某些化学反应速率 ,而且能使一些在常规加热条件下几乎不能进行的反应得以完成、获得满意的收率。用伯醇在溴化氢溶液中微波条件下发生反应制备了伯溴代烷。1　实验部分ＷｈｉｒｌｐｏｏｌＴ1 2 0Ｘ微波炉 (四川大学无线电系改装 ,可连续发射微波 ,功率连续可调 )、ＷＺＳ -Ｉ阿贝折光仪 (未校正 )。工业溴化氢 (Ｃ =40 % ,ｄ =1 38) ,其余试剂均为ＣＰ级。合成通法　将适量的醇、一定量的浓硫酸和过…     

梯度淋洗离子色谱法测定烟草中的苹果酸、柠檬酸和阴离子

研究了用10mmol／L的NaOH溶液超声波提取，离子色谱法同时检测烟草中有机酸和阴离子的分析方法。采用美国Dionex公司DX-500型离子色谱仪，用H2O、5mmol／L NaOH和100mmol／L NaOH梯度淋洗，流速为1．5mL／min，成功地测定了烟草中的苹果酸、柠檬酸、NO3^-1、NO2^-、Cl^-、SO4^2-等成份。这些成分在检测条件下有良好的线性关系，相关系数r^2〉0．99，检出限为0．005～0．2mg／L，相对标准偏差为0．52％。9．14％，回收率为93．5％～107．7％；实验表明该方法具有分析时间短、线性范围宽、灵敏和准确、简单快速、试剂用量少等优点。     

儿茶素活性成分分子印迹聚合物的固相萃取研究

以表没食子儿茶素没食子酸酯(Epigallocatechin-gallate,EGCG)为模板分子,α-甲基丙烯酸为功能单体,乙二醇二甲基丙烯酸酯为交联剂,在光冷引发条件下合成EGCG分子印迹聚合物,利用该聚合物制成分子印迹固相萃取柱,用于固相萃取茶叶提取物茶多酚,对萃取柱中的清洗液、洗脱剂、上载量等进行了选择.结果表明,在萃取柱上载样品之后,先用V(甲醇):V(水)＝1:9溶液进行清洗,再用V(甲醇):V(乙酸)＝9:1混合液进行目标分子的洗脱,可以得到比较纯的目标物质EGCG(色谱峰相对峰面积达92.4%),萃取柱在上载样品并进行清洗、洗脱之后,EGCG的回收率达69.3%.分子印迹柱具有较好的稳定性和耐用性能,使用20次后其选择性识别能力仍未降低,但空白印迹柱却没有这样的选择性识别能力.     

526例儿童指血微量元素检测结果分析

为了解吐哈油区婴幼儿体内钙、铁、锌、铜、镁的含量,使用多通道原子吸收光谱仪对门诊体查的526例0~7岁幼儿指血检测了钙、铁、锌、铜、镁。结果表明,各个年龄组中缺铁均居第一位,缺钙居第二位,缺锌居第三位,年龄越小,这3种元素含量越低。提示婴幼儿生长发育快,易缺钙,铁,锌元素,年龄越小,越易缺乏。