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131.
132.
Controlled synthesis of nonspherical microparticles using microfluidics 总被引:11,自引:0,他引:11
Dendukuri D Tsoi K Hatton TA Doyle PS 《Langmuir : the ACS journal of surfaces and colloids》2005,21(6):2113-2116
The controlled synthesis of nonspherical microparticles using microfluidics processing is described. Polymer droplets, formed by shearing a photopolymer using a continuous water phase at a T-junction, were constrained to adopt nonspherical shapes by confining them using appropriate microchannel geometries. Plugs were obtained by shearing the polymer phase at low shear rates, while disks were obtained by flattening droplets using a channel of low height. The nonspherical shapes formed were permanently preserved by photopolymerizing the constrained droplets in situ using ultraviolet light. Monodisperse plugs and disks of different lengths and diameters were obtained by varying the flow rates of the two phases. 相似文献
133.
Ditsch A Laibinis PE Wang DI Hatton TA 《Langmuir : the ACS journal of surfaces and colloids》2005,21(13):6006-6018
The clustering and stability of magnetic nanoparticles coated with random copolymers of acrylic acid, styrenesulfonic acid, and vinylsulfonic acid has been studied. Clusters larger than 50 nm are formed when the coatings are made using too low or too high molecular weight polymers or using insufficient amounts of polymer. Low-molecular-weight polymers result in thin coatings that do not sufficiently screen van der Waals attractive forces, while high-molecular-weight polymers bridge between particles, and insufficient polymer results in bare patches on the magnetite surface. The stability of the resulting clusters is poor, but when an insufficient polymer is used as primary coating, and a secondary polymer is added to coat remaining bare magnetite, the clusters are stable in high salt concentrations (>5 M NaCl), while retaining the necessary cluster size for efficient magnetic recovery. The magnetite cores were characterized by TEM and vibrating sample magnetometry, while the clusters were characterized by dynamic light scattering. The clustering and stability are interpreted in terms of the particle-particle interaction forces, and the optimal polymer size can be predicted well on the basis of these forces and the solution structure and hydrophobicity of the polymer. The size of aggregates formed by limited polymer can be predicted with a diffusion-limited colloidal aggregation model modified with a sticking probability based on fractional coating of the magnetite cores. 相似文献
134.
本文在文献[3]的基础上作了优化计算的改进,利用气固两相流[1]和系统的优化计算模型编制程序,从最佳面积比、喷射个数和套筒尺寸之间的紧密联系出发,获得了优化设计速冻喷射系统的方法,用于设计速冻系统的套筒、喷嘴的结构尺寸。本文还将理论计算结果与试验数据进行比较,获得了满意的结果。 相似文献
135.
136.
研究了大型汽轮发电机定子端部固定绕组的压板松动时,位于两侧压板间某段绕组的振动问题.首先,采用分离变量法,给出了发电机运行时定子端部绕组区域的磁感应强度表达式,并给出了绕组所受电磁力及与松动压板间摩擦力的计算式.其次,建立了研究绕组非线性振动问题的力学分析模型,采用多尺度法对主共振情形进行了解析求解,推得了稳态运动下的幅频响应方程,并对定常解的稳定性及分岔奇异性进行了研究,得到了稳定性的判定条件及分岔方程的转迁集.最后,针对工程实际问题进行了计算,给出了相应的幅频响应曲线图,并进行了分析讨论. 相似文献
137.
Wilkins SB Hatton PD Roper MD Prabhakaran D Boothroyd AT 《Physical review letters》2003,90(18):187201
We have conducted the first soft x-ray diffraction experiments from a bulk single crystal, studying the bilayer manganite La2-2xSr1+2xMn2O7 with x=0.475 in which we were able to access the (002) Bragg reflection using soft x rays. The Bragg reflection displays a strong resonant enhancement at the L(III) and L(II) manganese absorption edges. We demonstrate that the resonant enhancement of the magnetic diffraction of the (001) is extremely large, indeed so large that it exceeds that of the nonresonant Bragg diffraction. Resonant soft x-ray scattering of 3d transition metal oxides is the only technique for the atomic selective measurement of spin, charge, and orbital correlations in materials, such as high temperature superconductors, colossal magnetoresistance manganites, and charge stripe nickelates. 相似文献
138.
139.
Janus magnetic nanoparticles (~20 nm) were prepared by grafting either polystyrene sodium sulfonate (PSSNa) or polydimethylamino ethylmethacrylate (PDMAEMA) to the exposed surfaces of negatively charged poly(acrylic acid) (PAA)-coated magnetite nanoparticles adsorbed onto positively charged silica beads. Individually dispersed Janus nanoparticles were obtained by repulsion from the beads on reversal of the silica surface charge when the solution pH was increased. Controlled aggregation of the Janus nanoparticles was observed at low pH values, with the formation of stable clusters of approximately 2-4 times the initial size of the particles. Cluster formation was reversed, and individually dispersed nanoparticles recovered, by restoring the pH to high values. At intermediate pH values, PSSNa Janus nanoparticles showed moderate clustering, while PDMAEMA Janus nanoparticles aggregated uncontrollably due to dipolar interactions. The size of the stable clusters could be controlled by increasing the molecular weight of the grafted polymer, or by decreasing the magnetic nanoparticle surface availability for grafting, both of which yielded larger cluster sizes. The addition of small amounts of PAA-coated magnetic nanoparticles to the Janus nanoparticle suspension resulted in a further increase in the final cluster size. Monte Carlo simulation results compared favorably with experimental observations and showed the formation of small, elongated clusters similar in structure to those observed in cryo-TEM images. 相似文献
140.
超声兰姆(Lamb)波在结构缺陷检测方面愈来愈受到重视,但目前Lamb波的应用局限于单信号源激励,单通道接收的方法,容易受到噪声干扰,其后续的信号分析处理也比较复杂。本文旨在采用多通道Lamb波对板状结构中的裂纹进行定量分析与诊断。在铝板的表面凿刻出不同深度的凹槽作为裂纹,通过线阵换能器采集在一定传播距离内的多通道Lamb波信号,并采用二维傅里叶变换分析在不同深度的裂纹下,Lamb波模式能量的变化规律。结果表明,相对于完好铝板中的Lamb波信号,裂纹的存在会使Lamb波发生模式转换现象,并且转换模式能量百分比随裂纹深度的增加而线性增加。其结果为Lamb波评价板状结构中的裂纹状况提供了一种可能的方法。 相似文献