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101.
The influence of hydrogen bonds on the physical and chemical properties of hydrogen bonding fluid system of A a D d type is investigated from two viewpoints by the principle of statistical mechanics. In detail, we proposed two new ways that can be used to obtain the equilibrium size distribution of the hydrogen bonding clusters, and derived the analytical expression of a relationship between the hydrogen bonding free energy and hydrogen bonding degree. For the nonlinear hydrogen bonding systems, it is shown that the sol-gel phase transition can take place under proper conditions, which is further proven to be a kind of geometrical phase transition rather than a thermodynamic one. Moreover, several problems associated with the geometrical phase transition and liquid-solid phase transition in nonlinear hydrogen bonding systems are discussed. 相似文献
102.
103.
104.
105.
Fang Yao 《Journal of multivariate analysis》2007,98(1):40-56
The estimation of a regression function by kernel method for longitudinal or functional data is considered. In the context of longitudinal data analysis, a random function typically represents a subject that is often observed at a small number of time points, while in the studies of functional data the random realization is usually measured on a dense grid. However, essentially the same methods can be applied to both sampling plans, as well as in a number of settings lying between them. In this paper general results are derived for the asymptotic distributions of real-valued functions with arguments which are functionals formed by weighted averages of longitudinal or functional data. Asymptotic distributions for the estimators of the mean and covariance functions obtained from noisy observations with the presence of within-subject correlation are studied. These asymptotic normality results are comparable to those standard rates obtained from independent data, which is illustrated in a simulation study. Besides, this paper discusses the conditions associated with sampling plans, which are required for the validity of local properties of kernel-based estimators for longitudinal or functional data. 相似文献
106.
Charge density fluctuation of low frequency in a dusty plasma 总被引:2,自引:0,他引:2
The charge density fluctuation of low frequency in a dusty plasma, which is derived from the longitudinal dielectric permittivity
of the dusty plasma, has been studied by kinetic theory. The results show that theP value, which describes the relative charge density on the dust in the plasma, and the charging frequency of a dust particle
Ω
c
, which describes the ratio of charge changing of the dust particles, determine the character of the charge density fluctuation
of low frequency. For a dusty plasma ofP≪1, when the charging frequency Ω
c
, is much smaller than the dusty plasma frequency ωd, there is a strong charge density fluctuation which is of character of dust acoustic eigenwave. For a dusty plasma ofP≫1, when the frequency Ω
c
, is much larger than ω
d
there are weaker fluctuations with a wide spectrum. The results have been applied to the ionosphere and the range of radius
and density of dust particles is found, where a strong charge density fluctuation of low frequency should exist. 相似文献
107.
在电流及温度分布满足“不变性”原理的基础上,本文分析了等离子体中心热区的能量平衡,求出了电子热传导系数,根据实验数据拟合出HL-1装置电子热传导系数的定标关系为X_e=6.8(n_(eq1))~(-1.2)。此关系与其他托卡马克装置的结果类似。 相似文献
108.
Photoluminescence spectra of a series of MBE-grown Hg1-xCdxTe samples with the same mole fraction of about x≈0.39 have been measured at different temperatures from 5 to 100 K. By aid of the temperature and exciting laser power dependence of photoluminescence peak energy and relative intensity, as well as of the comparison with other measurements, four main structures dominating in the photoluminescence spectra are attributed to band to band, DoX, AoX and DoAo transitions. A deep donor state level located at about 8.5meV below the bottom of the conduction band has been observed and is determined to be due to the arsenic-occupied mercury vacancies. Two acceptor levels located at about 14.5 meV and about 31.5 meV above the top of the valance band have also been found from the measuements, which are identified as the mercury vacancies and As in anion site, respectively. 相似文献
109.
MicrostructureEvolutioninLaserRSCo-baseMetastableAlloyWANGAnan;CHENGShunqi;GUOZhiyao(KunmingUniversityofScienceandTechnology,... 相似文献
110.