具有精细结构的吸附与离子交换树脂

本文论述了某些具有精细化学，物理结构的离子交换树脂和吸附树脂的特性与应用。     

Syntheses,Crystal Structures and Catalytic Activities of Two Novel Mn_2Dy_2O_2 Complexes

Two novel heteronuclear manganese-dysprosium complexes have been synthesized and characterized, both of which contain a [Mn_2Dy_2O_2] core ligated by eight But CO_2-anions and four neutral ligands. In complex 1, [Mn_2Dy_2O_2(Bu~tCO_2)_8(Bu~tCO_2H)_4], all the four neutral ligands coordinated to Dy~(3+) are pivalic acids; Instead, two of these four pivalic acids have been replaced by ethanol in complex 2 [Mn2 Dy2 O2(Bu~tCO_2)_8(Bu~tCO_2H)_2(CH_3CH_2OH)_2]. The crystal of complex 1(C_(60)H_(112)Dy_2Mn_2O_(26), Mr = 1684.36) belongs to the orthorhombic system, space group Pbca with a =19.853(3), b = 18.565(3), c = 20.952(3) ?, V = 7723(2) ?3, Z = 4, Dc = 1.449 g/cm~3, S = 1.210, μ =2.302 mm~(-1), F(000) = 3448, the final R = 0.0802 and w R = 0.1570 for 8736 independent reflections.The crystal of complex 2(C_(54)H_(104)Dy_2Mn_2O_(24), Mr = 1572.25) belongs to the monoclinic system,space group C2/c with a = 27.814(6), b = 13.194(3), c = 22.912(5) ?, β = 124.89(3)o, V = 6897(3) ?3,Z = 4, Dc = 1.514 g/cm~3, S = 1.086, μ = 2.570 mm~(-1), F(000) = 3208, the final R = 0.0256 and wR =0.0592 for 7763 independent reflections. The cyclic voltammogram and catalytic activity measurements of complex 1 suggest that this type of complex can serve as a catalyst for oxygen-evolving reaction.     

A slope-based decoupling algorithm to simultaneously control dual deformable mirrors in a woofer–tweeter adaptive optics system

We propose a slope-based decoupling algorithm to simultaneously control the dual deformable mirrors(DMs) in a woofer–tweeter adaptive optics system. This algorithm can directly use the woofer's response matrix measured from a Shack–Hartmann wave-front sensor to construct a slope-based orthogonal basis, and then selectively distribute the largeamplitude low-order aberration to woofer DM and the remaining aberration to tweeter DM through the slope-based orthogonal basis. At the same moment, in order to avoid the two DMs generating opposite compensation, a constraint matrix used to reset tweeter control vector is convenient to be calculated with the slope-based orthogonal basis. Numeral simulation demonstrates that this algorithm has a good performance to control the adaptive optics system with dual DMs simultaneously. Compared with the typical decoupling algorithm, this algorithm can take full use of the compensation ability of woofer DM and release the stroke of tweeter DM to compensate high-order aberration. More importantly, it does not need to measure the accurate shape of tweeter's influence function and keeps better performance of restraining the coupling error with the continuous-dynamic aberration.     

V型三能级系统中五阶极化拍频的理论研究

从理论上研究了由于五阶极化强度间的干涉所导致的Ｖ型三能级系统相闰共轭超快调制光谱学，考虑了抽运光束为窄带线宽或宽带线宽的情形。发现能级分裂的测量精度决定于光学跃迁的均匀增宽，即这种技术在测量能级分裂时可得到消除多普勒增宽的精度。     

基于交叉型双气室空气互联悬架的全地形车侧倾特性研究

设计了一种采用囊式空气弹簧的交叉型双气室空气互联悬架 (PIS 悬架),并应用于侧翻事故发生率极高的全地形车上. 建立了交叉型双气室气体耦合 AMEsim 模型与全地形车整车动力学 ADAMS/Car 模型,通过将前者模型中的空气弹簧弹性力作为整车动力学模型的输入变量,将后者模型中的空气弹簧压缩伸张位移作为气体耦合模型的输入变量,建立了完整的机械-气体耦合多自由度动力学联合仿真模型. 通过 J 型弯高速典型仿真实验对搭载 PIS 悬架、双气室非互联悬架 (UN-PIS 悬架) 和普通螺旋弹簧悬架 (HS 悬架) 的全地形车进行侧倾特性对比研究. 研究结果显示,PIS 悬架若关闭互联管路,则会形成 UN-PIS 非互联状态,使悬架刚度瞬间大幅上升,平顺性瞬间变差,而具有相同垂向刚度的 PIS 悬架与 HS 悬架,前者能够提供更多的侧倾角刚度. 研究了气路系统 中影响动态侧倾特性的相关因子,包括连接管路管长、管径、附加气室容积. 研究表明,互联管路管长越小,越有利于提升全地形车侧倾特性,存在临界管径,管径小于或大于该值时,均会小幅度提升侧倾特性,附加气室容积越小,侧倾角刚度越大,为 PIS 悬架气路系统设计提供理论依据.      

催化科学发展史及其在中学化学教学中的价值*

催化科学的发展从早期催化技术的应用到概念和反应机理理论的完善,科学家的研究经历了从实践到猜想再到理论确立,从定性到定量,从宏观到微观水平的过程。通过厘清催化科学相关概念和理论的发展,论述了其中蕴含的教育价值。     

一种衍射测量条纹的方法

介绍一种基于Labview的虚拟仪器开发平台，采用美国国家仪器公司的PCI-6221数据采集卡对单缝衍射光强分布的数据采集和测量的方法。测量结果理论值基本吻合，说明运用Labview的测量方案切实可行。     

模糊质量设计的数学模型及解法

本文给出了模糊质量设计的数学模型 ,并给出了具有模糊约束、模糊约束函数值及双目标两层次的模糊质量设计模型的解法 .     

一道联考题的简解

湖北省部分重点中学2010届高三第一次联考昨天结束了,师生对数学试卷第20题第二问的解答大都感到太繁琐.为此,笔者给出两种创新的解题思路以飨读者.     

直流电场作用下生物柴油液滴的雾化特性和燃烧特性研究

设计搭建了电场作用下燃油液滴燃烧实验装置,对比了不同电压下生物柴油液滴的形态演变、变形程度、子液滴等行为,分析了不同电压下液滴火焰形貌演变、火焰尺寸等燃烧特性及最高液滴温度变化。结果表明,电压为3 k V和4 k V的电场会诱发生物柴油液滴产生锥射流,其破碎生成子液滴,尺寸范围为20～120μm,速度基本低于2.5 m·s^-1;受电场对火焰和液滴的综合影响,火焰变化主要表现为高度减小、宽度增大,纵横比减小;电压为1 k V和2 k V的电场降低了最高液滴温度,而当电压增加至3 k V和4 k V时最高液滴温度增加。