氰基取代亚甲基自由基的氧气氧化: 新颖Criegee中间体NCC(H)OO顺、反异构体的红外光谱探测

本文采用基质隔离红外光谱分别对15.0 K温度下的HC(N₂)CN/O₂/N₂和HCCNCO/O₂/N₂混合物(1/50/1000)的激光光解过程开展了实验研究. 结果表明：两者在紫外激光光照下均可产生Criegee中间体NCC(H)OO的顺、反两种构象异构体. 对NCC(H)OO的红外光谱解析得到了氧同位素(¹⁸O)标记实验和BP86/6-311++G(3df,3pd)理论计算结果的支持. 实验发现NCC(H)OO在紫外光照下可进一步与氧气分子发生二次反应,生成氰基甲醛和臭氧,而未得到被理论所预测的能量较低的双环氧乙烷异构体cyclic-NCC(O₂)H.     

Synthesis of thermally stable HfO_xN_y as gate dielectric for AlGaN/GaN heterostructure field-effect transistors

In this paper, we adopted thermally stable HfO_xN_y as gate dielectric for TiN/HfO_xN_y/AlGaN/GaN heterostructure field-effect transistors(HFETs) application. It demonstrated that the surface morphologies, composition, and optical properties of the HfO_xN_y films were dependent on oxygen flow rate in the O_2/N_2/Ar mixture sputtering ambient. The obtained metal–oxide–semiconductor heterostructure field-effect transistors by depositing HfO_2 and HfO_xN_y dielectric at different oxygen flow rates possessed a small hysteresis and a low leakage current. After post deposition annealing at 900℃, the device using HfO_xN_y dielectric operated normally with good pinch-off characteristics, while obvious degradation are observed for the HfO_2 gated one at 600℃. This result shows that the HfO_xN_y dielectric is a promising candidate for the self-aligned gate process.     

区间自适应遗传算法优化无约束非线性规划问题

针对无约束非线性规划传统优化方法存在的问题,将区间自适应遗传算法引入无约束非线性规划优化中,算法可以利用当前进化信息,自适应移动搜索区间,找到全局最优解,故可缩短搜索区间长度,提高编码精度,降低算法计算量,解决了传统遗传算法处理优化问题时,给定区间必须包含最优解这一问题,这也是本算法有别于其他优化算法的独特优势,为某些最优解所在区间难以估计的无约束非线性规划问题的优化提供了一条有效可行的途径.系统阐述了区间自适应遗传算法的原理,给出了算法优化无约束非线性规划问题的步骤,以MatlabR2016b仿真方式对算法进行了实例测试,结果表明,方法是一种计算稳定、正确、有效、可靠实用的无约束非线性规划优化方法.     

高强度泵浦碱金属蒸气激光器的光参量振荡器

以电光调Q的Nd:YAG激光器为泵浦源,以磷酸氧钛钾（KTP）为非线性晶体,搭建了调谐范围为750~800 nm的光参量振荡器。信号光在中心波长780.2 nm处获得单脉冲能量113 mJ、脉宽15.43 ns、光斑直径5.5 mm的输出。用光栅单色仪测量信号光光谱宽度（FWHM）为0.38 nm。信号光通过120 ℃的铷蒸气池,观察到清晰的荧光轨迹。证明信号光能有效泵浦铷蒸气,可为铷激光器提供峰值功率7 MW的高强度脉冲泵浦源,进而研究铷激光器在高强度泵浦条件下的动力学过程和基础物理机制。     

Studies on the Aero-optical Phenomena of Free-vortex Aerodynamic Window′s Jet

The concept of the free-vortex aerodynamic windows(FADW) is one of the best effective methods taking the place of the conventional beam output crystal windows of high power laser. An experimental model of the supersonic free-vortex aerodynamic window has been designed and made in our latest study. This paper studies the aero-optical phenomena of the FADW′s supersonic jet to study the laser optical quality degradation caused by the free-vortex jet, and to find out the relation of output laser beam quality through the FADW to the structure of the FADW′s supersonic jet. First it studies the beam quality using the methods of far-field beam profile measurement and lateral shearing interferometry, and then it uses the principle of matrix-optics interpreting the large-scale phase distortion in detail. At last the structure of FADW′s jet has been studied by means of shadowgraphy.     

单渥拉斯顿稜镜激光差分干涉仪

激光具有高度的时间和空间相干性,如果用它作为光源,可用一块渥拉斯顿稜镜(Wollaston Prism)代替纹影系统中的刀口机构,这样就形成了一台所谓的单渥拉斯顿稜镜(以下简称W稜镜)激光差分干涉仪。根据实验结果,...     

快照式成像光谱仪检测印染废水的研究

建立了一种快照式成像光谱仪快速检测印染废水的方法.配制单一组分以及混合组分的模拟印染废水,优化了实验条件,以白光LED阵列光源为检测光源,用实验室研发的成像光谱仪采集样品的图像,获得样品400~800 nm范围的光谱信息,建立了样品吸光度与浓度的线性关系.单一组分的罗丹明B和橙黄G的线性范围为1~50 mg/L,线性相关系数均大于0.99,回收率为93%~114%,相对标准偏差(RSD)为7.5%和1.3%;利用多元线性回归模型对混合样品的检测,相关系数均为0.999,各组分的测量相对误差均有改善.实验结果表明,本方法具有快速、准确和重复性好等优点,可以作为印染废水现场检测和应急检测的方法.     

高纯度四氟化碳的制造法

低温致冷剂四氟化碳,由于用作蚀刻剂,需要量不断增加。但用四氯化碳和氟化氢制造时,第四个氟原子的置换极为困难,且产物中混有氯化物,不易精制。     

F－P滤波窗在半导体光孤子源中的作用

利用光谱窗滤波法对增益开关半导体激光器输出光脉冲消啁啾进行了理论分析，在线性啁啾近似下得到了啁啾光脉冲经Ｆ－Ｐ后的谱宽表达式，给出了经Ｆ－Ｐ后光脉冲的宽度、波形以及自相关测量时的波形因子与Ｆ－Ｐ参数的关系曲线．实验结果与理论分析基本一致．