高温超导混合配对态与磁通涡旋格子

建立在对基于Gor’kov方法而导出的微观GinzburgLandau方程的分析揭示了高温超导体YBa2Cu3O7配对态对称性和磁通涡旋格子结构.分析指出,存在一个格子转变温度T,当温度高于T时,超导基态显示dx2-y2波对称性特征;低于该温度s波沟道幅值成为可观的量级;超导基态为混合s-dx2-y2态.对应单分量波函数磁通涡旋格子为三角的结构;而稳定的斜格子反映出混合波特征.s与d沟道间耦合约束了磁场下dx2-x2波对称性自由度,而对高温超导反常输运行为如上临界磁场温度曲线上翘现象所负责 关键词： 高温超导 GinzburgLandau理论 磁通涡旋     

高温超导隧道电流及旋光效应与混合配对态

给出了s+id波混合配对态前提下，有关YBa₂Cu₃O₇ Josephson隧道实验现象的分析支持了这类混合配对态提法的合理性.结合对超导体旋光现象的分析，显示了Γ₁+Γ₄表象的可取性.对分数磁通的存在性问题也展开了讨论. 关键词：     

自对耦无序分布随机链Potts模型的临界普适性研究

以蒙特卡罗模拟方法对自对耦分布二维随机链q态Potts模型的短时临界行为进行了数值研究.利用初始非平衡演化阶段存在的普适幂指数和有限体积标度行为，数值模拟了在不同形式随机分布时q＝3和q＝8态Potts模型磁临界指数η和动力学临界指数z.计算结果发现η不依赖于自对偶无序分布的具体形式， 从而以数值方法给出了一个关于淬火掺杂自旋系统的临界普适行为的验证. 关键词： 随机链Potts模型 动力学蒙特卡罗模拟 临界普适性     

量子态统计测量电路探讨

本文讨论了超导隧道结(SIS)从零电压态跃迁到正常态过程的量子特征.对SIS结的临界电流的统计分布测量的可行性作了探讨.由于SIS结的临界电流是温度敏感的量,并且,其量子跃迁的电流变化很小, 因此,对温度的稳定性和测量的精度均要求很高.我们提出了一种改进的以测量时间间隔的方法取代直接测量临界电流的方法的测量方案,去测量SIS结从零电压态跃迁到正常态过程临界电流变化的统计分布.电路的计算机模拟表明,这种方法较直接法有更好的精度. 实验上的测量在准备中.     

超导隧道结中的电流相位关系

计算了等自旋配对超导隧道结中的直流Josephson电流.结果表明,当两侧超导体中配对势的轨道对称性分别属于磁点群D₄的A不可约表示和 ²E不可约表示的情况下,电流相位关系是I∝sin4φ. 关键词： 超导隧道结 Josephson电流     

基于标记配对相干态光源的诱骗态量子密钥分配性能分析

从有效性、稳定性和可行性三个方面, 对基于标记配对相干态光源的诱骗态量子密钥分配的性能进行了全面分析. 采用四组实验数据对基于标记配对相干态光源的三强度诱骗态方案的密钥生成效率、量子比特误码率和最优信号态强度与安全传输距离之间的关系进行了仿真和分析; 考虑到光源涨落, 对方案的稳定性进行了讨论和仿真; 并对基于标记配对相干态光源设计简单易实现方案的可行性进行了分析. 结论表明: 基于标记配对相干态光源的诱骗态方案性能在安全传输距离和密钥生成效率两方面都优于现有基于弱相干态光源和预报单光子源的诱骗态方案; 在光源强度涨落相同条件下, 标记配对相干态光源的稳定性逊于预报单光子源, 而优于相干态光源. 但是标记配对相干态光源在有效性上的优势可弥补其在稳定性上的不足; 且标记配对相干态光源的双模特性为设计简单易实现的被动诱骗态方案提供了条件. 关键词： 量子光学 量子密钥分配 标记配对相干态光源 性能     

表面活性剂SDS/TX-100混合体系的NMR研究

用NMR测量了不同比例的SDS/TX-100混合溶液中质子化学位移,结合表面活性剂溶液的两态交换模型,分析了质子化学位移随浓度的变化趋势, 求出了不同比例混合溶液中两种表面活性剂各自的临界胶束浓度及混合胶束的临界胶束浓度. 依据理想混合溶液理论,预测了混合胶束的临界胶束浓度,计算了溶液中SDS与TX-100之间的相互作用参数和SDS在混合胶束中的摩尔分数. 根据所得参数讨论了混合胶束的形成过程. 利用文中和文献中混合体系的实验数据验证了协同作用理论改进前后的适用性,表明改进后的协同作用理论完善一些.     

双层结构铁磁-超导隧道结的直流Josephson电流

通过求解Bogoliubov_de Gennes(BdG)方程得到铁磁超导共存态(FS)的自洽方程，在考虑结 界面的粗糙情形下，由推广的Furusaki_Tsukada(FT)的电流公式计算了铁磁超导态/ 绝缘层 / 铁磁超导态(FS/I/FS)结的直流Josephson电流，讨论了FS/I/FS结的直流Josephson临界 电流随磁交换能、温度的变化情况.研究表明：当结界面势垒散射强度和粗糙势垒散射强度 比较弱时磁交换能总是抑制FS/I/FS结的直流Josephson临界电流，而当结左右两边FS中铁 关键词： FS/I/FS超导隧道结 铁磁超导共存态 直流Josephson电流 粗糙势垒散射     

用外磁场控制电流感应磁化翻转效应中的临界电流方法

应用基于磁动力学方程的宏观唯象模型,研究了弱外磁场下纳米尺度赝自旋阀结构的电流感应磁化翻转效应.在统一考虑铁磁/非磁界面的自旋相关散射以及铁磁层中的自旋积累和弛豫过程后,给出了赝自旋阀结构在弱外磁场下的磁化翻转条件和临界电流.对该效应的数值计算解释了弱外磁场下赝自旋阀结构的电阻-电流回线的偏移,并给出了用外磁场控制电流感应磁化翻转效应中的临界电流方法. 关键词： 电流感应磁化翻转 外磁场 临界电流 赝自旋阀     

含InAs自组装量子点肖特基二极管的关联放电效应

制作了含自组织量子点的金属半导体金属双肖特基势垒器件,研究了器件的电流输运特性.在量子点充放电造成的电流迟滞回路的基础上,观察到了电压扫描过程中的电流由低态到高态的跳跃现象.这种电流跳跃来源于充电量子点的关联放电效应.根据量子点系统的哈密顿量,分析了充电量子点关联放电的原因.这种关联放电效应起源于量子点与2DEG的相互作用,当一个量子点放电时通过量子点和2DEG电流的变化会影响其他的量子点,从而促使其放电,这种过程在整个系统中放大导致所有的量子点放电 关键词： 关联效应 自组装量子点     

GINZBURG-LANDAU THEORY AND VORTEX LATTICE OF HIGH-TEMPERATURE SUPERCONDUCTORS

The thermodynamics of the vortex lattice of high-temperature superconductors has been studied by solving the generalized Ginzburg-Landau equations derived microscopically. Our numerical simulation indicates that the structure of the vortex lattice is oblique at the temperature far away from the transition temperature T_c, where the mixed s-d_x²-y² state is expected to have the lowest energy. Whereas, very close to T_c, the d_x²-y² wave is slightly lower energetically, and a triangular vortex lattice recovers. The coexistence and the coupling between the s and d waves would account for the unusual dynamic behaviours such as the upward curvature of the upper critical field curve H_C2(T), as observed in dc magnetization measurements on single-crystal YBa₂Cu₃O₇ samples.     

Superconducting plate in a transverse magnetic field: New state

A model is proposed for describing Cooper pairs near the transition (in temperature and magnetic field) point when their spacing is larger than their size. The essence of the model is as follows: the Ginzburg-Landau functional is written in operator form in terms of field operators of the Bose type so that the average value of the density operator gives the concentration of Cooper pairs, and the same Ginzburg-Landau expression is obtained for the Bose condensate. The model is applied to a superconducting plate with a thickness smaller than the size of a pair in a transverse magnetic field near its upper critical value H _c2. A new state is discovered that is energetically more advantageous in a certain interval in the vicinity of the transition point as compared to the Abrikosov vortex state. The wavefunction of the system in this state is of the type of the Laughlin function used in the fractional quantum Hall effect (naturally, as applied to Cooper pairs as Bose particles in our case) and corresponds to a homogeneous incompressible fluid. The energy of this state is proportional to the first power of quantity (1 ? H/H _c2) in contrast to the energy of the vortex state containing the square of this quantity. The interval of the existence of the new state is the larger, the dirtier the sample.     

Measurements of chemical diffusion coefficients of mixed conducting solids using point electrodes-investigations on Cu2S

The use of point electrodes for measuring chemical diffusion coefficients of mixed conducting solids with prevailing electronic conductivity is described and applied to low temperature Cu₂S. The electrochemical cell consist of the sequence of phases Pt/mixed conductor/Pt-point electrode. Applying small dc voltages to the cell leads to a steady state composition gradient within characteristic times that depend on the radius of the point electrode and on the chemical diffusion coefficient. The composition change after changing electrical voltage or current is followed by measuring the ohmic resistance change as a function of time, using ac nethods in the case of switching off. The method requires that the electronic conductivity depends on the usually small, but variable deviations of the composition of the solids from a definite stoichiometric composition. The measurements on the low temperature phase of Cu₂S give chemical diffusion coefficients ranging between 6.10^-6 cm²/s and 1.10^-7 cm²/s at 60°C.     

Some CNDO Calculations and Structural Spectroscopic Studies of Paracetamol Complexes

Through complete neglect of differential overlap (CNDO) calculations of the electronic energy among different possible structures of paracetamol (PA) molecule, it has been concluded that its structure has C_s point group symmetry of the cis‐form in which the methyl group has a restricted free rotation around its bond with the carbon atom of the amide group. The electronic spectra of PA compound were studied in different polar and nonpolar solvents. The temperature effect on the electronic spectra confirms the presence of one conformer only. The hydrogen bonding and the orientation energies of the polar solvents were determined from the studies of mixed solvents. Complexes of PA with metal ions M(II) (Cu⁺⁺, Zn⁺⁺, or Fe⁺⁺) of ratio 2:1, respectively, were prepared, and their structure has been confirmed by elemental analysis, atomic absorption spectra, IR spectra, and ¹H‐NMR spectra. It has been concluded that the structure of the complexes has C_2h point group symmetry in which two PA molecules are chelated to any one of the metal ions Cu⁺⁺, Zn⁺⁺, and Fe⁺⁺.     

Breakdown of the superheated Meissner state and spontaneous vortex nucleation in type II superconductors

The theory of local stability of the superheated Meissner state presented in an earlier paper is supplemented by an investigation of global stability in two dimensions. We conclude that flux penetration cannot be delayed beyond the fieldH _s1 where local instability sets in. Various new two-dimensional Ginzburg-Landau solutions, obtained numerically, are discussed. These include the lowest saddle point separating the Meissner from the normal and vortex state and a solution resembling the “nascent vortex state” whose existence was postulated recently by Walton and Rosenblum. Using these solutions the process of spontaneous vortex nucleation is discussed.     

Theory of core photoemission spectra in CeO2

By using the Anderson model with a filled valence band, we calculate the core photoemission spectra of CeO₂, and compare them with experimental results. It is shown that in the ground state of CeO₂ the 4?⁰ and 4?¹ configurations are mixed strongly due to the large hybridization between the 4? states and the valence band. In the final state of the photoemission, the 4?¹ and 4?² configurations are also mixed strongly due to the final state interaction coming from a core hole potential and the large hybridization. The fractional intensity of the 4?⁰ photoemission peak is considerably different from the weight of the 4?⁰ configuration in the ground state because of the strong final state interaction.     

On the equivalence of the first and second order equations for gauge theories

We prove that every solution to the SU(2) Yang-Mills equations, invariant under the lifting to the principle bundle of the action of the group, O(3), of rotations about a fixed line in ⁴, with locally bounded and globally square integrable curvature is either self-dual or anti-self dual. In other words we prove, under the above assumptions, that every critical point of the Yang-Mills functional is a global minimum.We prove also that every finite extremal of the Ginzburg-Landau action functional on ², with the coupling constant equal to one, is a solution to the first order Ginzburg-Landau equations. The relationship between the Ginzburg-Landau equations and the O(3) symmetric, SU(2) Yang-Mills equations on ² ×S ² is established.This work supported in part through funds provided by the National Science Foundation under Grant PHY 79-16812.     

2H NMR studies for the examination of methyl group rotations between their classical and quantum mechanical limits

²H NMR spectra of copper acetate monohydrate [Cu(CD₃CO₂)₂]·H₂O, hexamethylbenzene-d₁₈ and acetone-d₆ were analyzed to characterize methyl group rotations between their classical and quantum mechanical limits. The temperature dependent spectra show the three different possible developments of the lineshapes. Hexamethylbenzene is typical of compounds with small but resolvable tunnelling frequencies. Characteristic splittings in the spectra of copper acetate monohydrate reveal the temperature dependence of tunnelling frequencies that are slightly larger than the quadrupole coupling constant. While the tunnelling frequency of acetone is already too large to be specified from²H NMR lineshape analysis at temperatures low enough that quantum effects influence the spectra, the temperature dependent spectra deviate characteristically from those found for classical rotation. Additionally to these experimental results, we outline how from an NMR point of view mixed classical and quantum rotations can be described by a single complex frequency.     

The probabilities of triplet-singlet transitions in aromatic hydrocarbons and ketones

Calculations have been performed on the probabilities of triplet-singlet transitions in benzene and acetone in connection with the decay times of the phosphorescence. The transition probability was determined from the extent to which excited singlet states are mixed with the triplet state. The assumption that in benzene the phosphorescent state has ³ B_2u properties—so that the ¹ B_1u singlet state is mixed with it-—yields the best agreement with the experimental data. In the case of acetone the phosphorescence was considered as a triplet-singlet transition in which only the electrons of the CO group are involved. In both cases the agreement with experiment is as satisfactory as in other calculations on transition probabilities, the figures for the decay times being 190 and 7 seconds for benzene and 7·8 and 0·6 milliseconds for acetone. The ratio of the calculated decay times is in good agreement with the experimental result (2·4×10⁴ and 1·2×1O⁴).