单晶LiNbO3:Mn2+的ESR谱研究

用室温电子自旋共振(ESR)实验研究单晶LiNbO3中Mn2+的精细结构和超精细结构.对ESR谱的分析得出,零磁场的能级分裂数值:自旋角动量能级|±1/2>与|±3/2>之间的间隔为△ε1=-587×10-4cm-1,而|±3/2>与|±5/2>之间的能级间隔为△ε2=-2633×10-4cm-1;其各向异性朗德因子g//=2.1810,g⊥=2.0937;精细结构常数D=-536×10-4cm-1;超精细结构常数A//=88.36×10-4cm-1,A⊥=81.20×10-4cm-1,即精细结构相互作用要比超精细结构相互作用大得多.另外,特别值得提到的是实验中还发现两组明显的禁戒跃迁,|-3/2> |1/2>和|-1/2> |5/2>.     

非晶锂离子导体B_2O_3-Li_2O—LiCl一Al_2O_3中VO~(2+)的电子自旋共振

两种非晶锂离子导体B_2O_3-0.7Li_2O-0.7LiCl-xAl_2O_3-0.1V_2O_5(x=0.05和0.15)的电子自旋共振谱研究表明:(i)ESR线型是高斯型,证实V_2O_5添加量适当;(ii)超精细结构来源于VO~(2+)络离子,具有四角对称性,属C_(4v)群。越精细耦合张量的平行分量平均值A_∥=0.0175cm~(-1),垂直分量A_⊥=0.0063cm~(-1)。由g_∥(g_⊥)求出其基态~2B_(2g)与第一激发态~2E_g的能级间距△_1=2.46×10~4cm~(-1),基态与第二激发态~2B_(1g)的能级间距△_2=3.03×10~4cm~(-1);(iii)变温实验证实:Al_2O_3组分较少(x=0.05)的非晶ESR强度比x=0.15的非晶高3倍至2倍,而Al_2O_3组分越多则ESR强度随温升下降越小。     

141Pr+波长56908 nm谱线超精细结构测量

利用共线快离子束-激光高分辨光谱学测量了141Pr+波长为56908nm谱线的超精细结构光谱，由此得到超精细相互作用常数和参与跃迁激发态、亚稳态能级的超精细能级分裂-与已有的数据比较，在实验误差范围内一致，但测量精度提高了一个数量级- 关键词： 超精细结构 快离子束-激光光谱学 磁偶极矩和电四极矩超精细作用常数     

~(143,145)Nd~+4f~45d~6K_(9/2)→(23229.991)_(9/2)~o跃迁超精细结构光谱

利用共线快离子束 激光光谱学方法测量了1 4 3 ,1 4 5Nd+6K9/ 2 → (2 32 2 9.991 ) o9/ 2 跃迁的超精细结构光谱 ,得到了上、下能级的超精细相互作用常数 .     

LaⅡ5d2 1G4→4f5d 1F3超精 细结构光谱测量

利用少有的共线快离子激光光谱学方法研究了LaⅡ的超精细结构,测量了5d² < sup>1G₄态→4f5d ¹F₃态的超精细结构光谱,分 别得出了相应的磁偶极矩和电四极矩的超精细相互作用常数. 关键词： 共线快离子束激光光谱学 超精细结构 共振激发     

钫原子磁偶极超精细结构常数及其同位素的磁偶极矩的理论计算

应用基于B样条基组的相对论耦合簇理论方法,计算了~(212)Fr原子的n S (n=7—12), n P (n=7—12)和n D (n=6—11)态的磁偶极超精细结构常数.与精确实验值的比较说明这套理论方法能精确计算出磁偶极超精细结构常数,其中7P态的磁偶极超精细常数的理论值与实验值之间的差异小于1%.在忽略场移效应对Fr原子7P态超精细结构常数的影响下,通过结合实验值进一步定出了~(207-213,220-228)Fr核磁偶极矩μ,这些值与已有的测量值具有非常好的一致性.本文报道了12S, n P (n=9—12)和n D (n=10—11)态的磁偶极超精细结构常数.     

143,145Nd+ 4f45d6K\-9/2→(23229.991)o\-9/2跃迁超精细结构光谱

利用共线快离子束-激光光谱学方法测量了143,145Nd+ 6K\-9/2→(23229.991)o\-9/2跃迁的超精细结构光谱,得到了上、下能级的超精细相互作用常数.     

铯原子7S1/2态磁偶极超精细常数的测量

在室温下的原子气室中, 基于铯原子6S_1/2-6P_3/2-7S_1/2(852.3 nm+1469.9 nm) 阶梯型能级系统, 利用电光调制器的主频和±1级边带分别产生的三套双共振吸收光谱, 当驱动电光调制器的信号源频率严格等于7S_1/2态超精细分裂的能级间隔时, 三套谱线中的一些超精细跃迁谱线重叠且线宽最窄, 利用这一现象很好地避免了激光器频率扫描时非线性效应的影响, 测量出了7S_1/2 态超精细分裂能级间隔: 2183.72 MHz±0.23 MHz, 并计算出该态的磁偶极超精细常数: A_hfs= 545.93 m MHz±0.06 MHz, 与文献中报道的测量结果一致.     

~(159)TbII超精细结构光谱测量

利用具有光谱高分辨和选择性激发等特点的共线快离子束激光光谱学方法研究了159Tb II亚稳态 4 f95 d7H08和激发态 4 f96 p3 / 2 ( 1 5 /2 ,3/2 )的超精细结构光谱 ,所有光谱线可以很好地分辨 ;并由实验测量到的高分辨超精细结构光谱 ,给出了相应能级的超精细结构常数     

超精细结构对激光与二能级原子相互作用的影响

应用半经典理论建立了一个简化模型,对157Gd原子在激光作用下17795267cm-1(9D3)←→532977cm-1(9D4)的能级跃迁进行计算并给出了计算结果,提出相应的理论解释,分析了超精细结构对激光与二能级原子相互作用的影响 关键词： 超精细结构 原子蒸气激光同位素分离 二能级原子 钆原子     

SrTiO3金属-绝缘体-半导体结构的介电与界面特性

采用金属有机分解法在p型Si衬底上制备了SrTiO3（STO）薄膜.研究了STO薄膜金属 绝缘体 半导体(MIS)结构的介电和界面特性.结果表明，STO薄膜显示出优异的介电性能，在10kHz处的介电常数约为105，损耗低于001，这来源于多晶结构和良好的结晶性；MIS结构中的固定电荷密度Nf和界面态密度Dit分别约为15×1012cm-2和(14—35)×1012cm-2eV-1，这主要与Si/STO界面处形成的低介电常数界面层有关. 关键词： SrTiO3薄膜 MIS结构 介电性能 Si/STO界面     

非晶Fe89.7P10.3合金纳米线阵列的磁性研究

利用电化学沉积方法在阳极氧化铝模板中制备了Fe_89.7P_10.3非晶 合金纳 米线阵列.利用x射线衍射仪、透射电子显微镜、振动样品磁强计和穆斯堡尔谱仪研究了样品的结构和磁性,发现纳米线阵列是非晶结构，且拥有垂直磁各向异性和高的矫顽力，H_c =304×10⁴A/m.纳米线内部的平均超精细场和平均同质异能移分别为2 15×10⁶ A/m和007 mm/s；而纳米线末端的平均超精细场（233×10⁶ A/m ）大于内 部的值，平均同质异能移（004 mm/s）小于内部的值.另外，纳米线内部Fe原子磁矩与线轴的夹角约为16°，而在纳米线末端Fe原子磁矩与线轴的夹角约为28°.这些结果表明，由于形状各 向异性，在纳米线中实现了无序非晶合金磁矩的有序排列. 关键词： 非晶合金 纳米线阵列 垂直磁各向异性 穆斯堡尔谱     

Electron paramagnetic resonance in the system CaO-SiO2-Al2O3 containing sulfur

An EPR absorption was detected in the system CaO-SiO₂-Al₂O₃ doped with sulfur. The signal consisted of six isotropic hyperfine lines and demonstrated isotropic fine structure and forbidden doublets. The signal was attributed to an Mn²⁺ impurity displacing Ca²⁺ in fine CaS crystallites formed in the matrix of the ternary system. The spectrum was well accounted for with the parameters g = 2.0021 ± 0.0001 and A = ?77.1 ± 0.6 × 10^?4 cm^?1. Sample preparation conditions did not affect the hyperfine splitting, although the fine structure and forbidden lines proved to be dependent on the conditions of preparation. It is suggested that the appearance of the fine structure is a result of the second effect of the hyperfine structure when the cubic field parameter a approaches zero and, consequently, the structure is free of superposition caused by an anisotropic shift determined by a. We ascribe the change in fine structure to the variation in a and discuss the nature of the energy splitting of the ${}^6\text{S}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$ state in a cubic field. We also note a correlation between the fine structure and the forbidden lines. This finding suggests that a is not necessarily specific to the host lattice and, furthermore, that the consideration of superposition of axial or lower symmetry upon the original cubic field of the central Mn²⁺ ion is vital for the determination of a.     

977nm抽运下掺铒碲酸盐基氧卤玻璃的光谱特性

研究了掺铒TeO2-ZnO-PbCl2碲酸盐基氧卤玻璃在977nm激光二极管抽运下的发光和上转换发光特性，结果发现除红外153μm4I13/2→４I15/2发光外（荧光半高宽高达69nm），该玻璃还存在很强的２Ｈ11/2→４I15/2（527nm），４Ｓ3/2→４I15/2（549nm）和４Ｆ９／２→４Ｉ１５／２（666nm）可见上转换发光.应用Judd-Ofelt理论计算得到玻璃强度参数Ωt（t=2，4，6）分别为Ω2=587×10-20cm2，Ω4=208×10-20cm2，Ω6=116×10-20cm2，计算了铒离子跃迁振子强度、自发辐射概率、荧光分支比、荧光寿命等光谱参量.应用McCumber理论计算得153μm处的玻璃受激发射截面可达875×10-21cm2实验结果表明，与硅酸盐玻璃、磷酸盐玻璃、氟化物玻璃等比较，掺铒碲酸盐基氧卤玻璃在宽带掺铒光纤放大器和上转换激光器中有着极大的研究和应用潜力. 关键词： 掺Er3+ 碲酸盐玻璃 氧卤玻璃 Judd-Ofelt理论 光谱性质     

掺铒铋酸盐玻璃的光谱性质和热稳定性研究

测试了铋酸盐玻璃(85-x)Bi2O3-(10+x)B2O３-5Na2O(x=0，5，10，15，20，25 mol%)中Er3+离子的吸收光谱、荧光光谱、荧光寿命及热稳定性.应用Judd-Ofelt理论计算了铋酸盐玻璃中Er3+离子的强度参数(Ω2=(352—386)×10-20cm2,Ω4=(138—152)×10-20cm2,Ω6=(093—117)×10-20cm2),应用McCumber理论计算了Er3+离子的受激发射截面(σe=(70—95)×10-21cm2)及Er3+离子4I13/2→4I15/2发射谱的荧光半高宽(FWHM=57—79nm)，测得了Er3+离子４I13/2能级荧光寿命(τm=265—159ms)，分析了玻璃的热稳定性能.研究了Er3+离子各种光谱参数对成分的依赖性，发现随着玻璃中B2O3含量的增加，强度参数Ωt(t=2,4,6)、荧光半高宽(FWHM)、热稳定性均相应增加，而测得的荧光寿命却减小.比较了不同基质玻璃中Er3+离子的光谱特性，结果表明掺铒铋酸盐玻璃更适合于掺Er3+光纤放大器实现宽带和高增益放大. 关键词： 铋酸盐玻璃 光谱性质 成分依赖性 Er3+离子     

Low temperature ESR of K2Pt(CN)4Br0.3. 3.2 H2O

Electron spin resonance has been observed in high purity single crystals of K₂Pt(CN)₄Br_0.3·3.2H₂O, (KCP), in the temperature range of 4.22–80 K. Two types of paramagnetic species are found to dominate the spectrum. One of these is an inhomogeneously broadened line showing no resolved hyperfine splitting and having g_∥ = 1.946 ± 0.003 and g⊥ = 2.340 ± 0.003. The second paramagnet is identified as a Cu²⁺ impurity center with g_∥ = 2.231 ± 0.003, g⊥ = 2.079 ± 0.002 and hyperfine tensor A_∥ = 467 MHz, A_⊥ = 70 MHz.     

ESR study of Fe3+ and Mn2+ ions on trigonal sites in ilmenite structure MgTiO3

Electron spin resonance has been observed for Fe³⁺ and Mn²⁺ ions occupying sites with trigonal symmetry in undoped and doped Verneuil-grown crystals of the ilmenite type compound MgTiO₃. At 300 K, the fine structure parameters in the spin Hamiltonian are (in 10^?4cm^?1) D = +844 (± 1), (a? F) = +118 (± 1), a = 69 (± 7) for Fe³⁺ and D = +164 (± 1), (a ? F) = +10.2 (± l), a = 7.0 (± 1) for Mn²⁺. These values are compared with literature data for Fe³⁺ and Mn²⁺ in other oxides, especially Al₂o₃, with particular reference to the recent “superposition” theory of the effect of a trigonal distortion. From the orientation of the axes of cubic pseudosymmetry of the spin Hamiltonian, and with the assumption that a has the same sign for both ions, it is proposed that Fe³⁺ and Mn²⁺ occupy the same octahedral site, namely the Mg²⁺ site. Anomalous line splittings observed for one sample were attributed to twinning on (0001) or {1120} planes.     

ESR of V3+ in zinc oxide single crystals

Electron spin resonance has been investigated in zinc oxide single crystals containing vanadium. Several groups of ordinary and forbidden transitions can be observed. The experimental results are interpreted with the aid of the spin Hamiltonian, for which the following parameters were determined:g∥=1.945; ⊥=1.937; ¦D¦=750×10^?4 cm^?1, ¦A¦=68 × 10^?4 cm^?1; ¦B ¦=93×10^?4 cm^?1; ¦A?P¦=65×10^?4cm^?1.     

Electron paramagnetic resonance of 61Ni+ in CuGaS2

EPR of ⁶¹Ni⁺ doped CuGaS₂ at 4.2 K leads to the following experimental data: $\text{g = 1.918 ± 0.006 A  < 12 × 10}{}^{-4}\text{cm}{}^{-1}\text{, g}{}_{\mathrm{\perp }}\text{= 2.328±0.006 A}{}_{\mathrm{\perp }}\text{= (65±2) × 10}{}^{-4}\text{cm}{}^{-1}$. High axial field splitting of ²T₂ state stabilizes the center against Jahn-Teller interaction. Covalency reduction factor k is 0.76.     

High-resolution spectroscopy of SO2 using a frequency-doubled,continuous-wave dye laser

The SO₂ molecule is of considerable interest in the context of atmospheric pollution, and in many laser monitoring techniques the ultraviolet absorption band at 300 nm is used to determine SO₂ concentrations in the atmosphere. Recent laboratory experiments with a resolution of 2 × 10^-3 nm showed that variations could occur in absorption cross-section measurements made with different laser bandwidths due to unresolved fine structure. We have investigated absorption spectra with a line width of 3 × 10^-6 nm, using a frequency-doubled continuous-wave dye laser, and have confirmed the existence of fine structure in the absorption even when collisionally broadened with an atmosphere of nitrogen. These measurements provide a data base from which valid absorption cross sections may be calculated for all monitoring laser bandwidths. We estimate the pressure broadening coefficient for nitrogen in this wavelength region as 83 ± 38 kHz Pa^-1 (11 ± 5 MHz torr^-1). The temperature dependence of the absorption cross-section was also investigated.