氦等离子体处理对纳米二氧化硅溶胶涂覆T300碳纤维拉伸性能的影响

氦等离子体处理纳米二氧化硅溶胶涂覆T300碳纤维能构造出特定空间结构形态的纳米涂覆层.扫描电子显微镜照片显示,经氦等离子体处理后纳米二氧化硅溶胶涂覆T300碳纤维的纳米涂覆层在纤维表面分布均匀,起到填补纤维表面微观缺陷的功能.X射线光电子能谱及傅里叶变换红外光谱显示,纤维表面被引入了活性官能团,纳米二氧化硅涂覆层与碳纤维间有表面激活反应.形成纳米界面结构的T300碳纤维表面与纳米二氧化硅涂覆层间的相互作用符合艾琳方程,利用热激活体积可以对其相互作用进行定量分析.拉伸试验表明,屈服塑性变形导致纳米界面结构热激活,纳米微粒阻碍碳纤维表面大分子链形貌变化的热激活体积是纳米界面结构性能的重要表征. 关键词： 激活体积 溶胶涂覆 氦等离子体 纳米界面结构     

Plastic coating of glass fibers and its influence on strength

Abstract

Sodium borosilicate glass fibers pulled from the melt were plastic coated “on-line” to preserve the fiber strength. By the use of tapered nozzles within the coating applicator the coating could be made concentric around the fiber, and a 40-μm concentric coating was found to be sufficient for the fiber to withstand a mild abrasion test with no deterioration in strength. Strength measurements made in ambient conditions showed that the fiber had a uniform breaking strain of 4% elongation. The same fiber measured at liquid nitrogen temperatures had a breaking strain of 14%, even after extensive handling, which is close to the theoretical glass cohesive strength.     

氧等离子体处理对纳米二氧化硅溶胶涂覆高强、高模聚乙烯纤维拉伸性能的影响

基于艾琳方程,提出用于定量分析纤维表面和纳米涂覆层间的纳米界面结构的理论模型.实验结果表明,纤维高分子链段受力塑性变形时,纳米界面结构内纳米微粒阻碍其形貌变化产生热激活体积,该热激活体积是纳米界面结构性能的重要表征;氧等离子体处理对纳米二氧化硅溶胶涂覆高强、高模聚乙烯纤维有增韧作用.由不同处理样品的扫描电子显微镜图片和傅里叶变换红外光谱曲线对比分析可知,经氧等离子体处理纳米二氧化硅溶胶涂覆高强、高模聚乙烯纤维的纳米涂覆层纳米颗粒分布均匀,纳米颗粒还填补纤维表面微观缺陷,活性官能团被引入到纤维表面. 关键词： 激活体积 氧等离子体 高强、高模聚乙烯纤维 纳米界面结构     

一种简易的光纤光栅涂覆装置

阐述了对裸光纤光栅进行涂覆的原理和必要性。设计了一种简易可行的光纤光栅涂覆装置。该装置简单灵活,成本较低,尤其适合于长度较长的光纤光栅的一次性涂覆,涂层厚度灵活可调。以啁啾光纤光栅为例进行了涂覆实验,涂层光滑均匀,涂覆后的光栅强度得到了增强,抵抗机械应力的能力得到了提高,使用起来更方便。对光栅在涂覆前后分别作了特性参数测试。结果表明,光栅特性基本上不发生变化,性能未劣化,光纤光栅的涂覆简单易行。     

Characterization of coated optical fibers by Fourier-domain optical coherence tomography

Fourier-domain optical coherence tomography is used to image the cross sections of coated optical fibers. A standard single-mode fiber with a dual coating and a hard-clad silica fiber with a single thin low-index coating are studied. The individual coating dimensions, coated and uncoated fiber diameters, and the fiber coating's concentricity are retrieved from a single measurement.     

Optical properties of sol-gel fiber optic applicators for laser interstitial therapy

A new type of applicator for interstitial laser coagulation is proposed in this paper. The new fiber optic applicator is made by removing the original fiber cladding and replacing it with a sol-gel coating. The sol-gel coating was prepared from the silicate precursor TEOS (tetraethylorthosilicate), mixed with ethanol in acid, which catalyzes hydrolysis. The material is produced with the factor R = 20, where R denotes the number of solvent moles to the number of TEOS moles. In these studies, optical fibers were used from Laser Components (core diameter 400 μm, HCS, low OH). The external jacket was mechanically removed, leaving a remaining 2-cm length of bare fiber. The modified dip-coating method was used to cover the bare fibers with sol-gel material. Two types of applicators were produced: pure sol-gel coated devices and applicators with sol-gel coating doped with photosensitive dyes. The photodynamic activity of chlorophyll-based Photolon and Protoporphyrin IX (PPIX) incorporated within the sol-gels was studied spectrophotometrically. It was demonstrated that sol-gel applicators are capable of performing laser interstitial coagulation using a semiconductor cw laser at 980 nm. It was also demonstrated that the incorporated photosensibilizers retain their photochemical activity. Original Text ? Astro, Ltd., 2006.     

New method for strength improvement of silica optical fibers

The reliability and the expected lifetime of optical fibers used in telecommunication technologies are closely related to the chemical environment action on the silica network. To ensure the long-term mechanical strength of the optical fibers, a polymer coating was applied onto the fiber surface during fiber fabrication. This external coating is vital to ensure a long optical fiber lifetime. Its protective action includes several functions, such as to protect glass fiber from any external damage, to limit chemical attack, in particular that of water, and finally to ensure fatigue protection and bending insensitivity, especially during handling and in-service installation. Since the mechanical strength of the fiber is controlled by its surface characteristics, we propose a new method for increasing fiber strength.The silica optical fibers used were 125 μm in diameter, with a 62.5 μm thick epoxy-acrylate coating. Fibers were rolled up around two similar cylinders. Using a screw, these cylinders moved away from one another and thus subjected the fibers to stretching. Submitted to this mechanical loading, the distended fibers were plunged into hot water at 65 or 85 °C and aged for several days. Then, the fibers were removed from the water and various weights were suspended on the fiber ends. Thus, the fibers were subjected to a tensile loading in static fatigue for several days. Just before fiber rupture, the fibers were unloaded and subjected to dynamic tensile tests at different velocities.Result analysis proved that the aging in hot water increased the fiber strength. The Weibull's diagram study shows a bimodal dispersion of defects on the fiber surface and the important role of polymer coating.     

Plastic coating of glass fibers and its influence on strength

Sodium borosilicate glass fibers pulled from the melt were plastic coated “on-line” to preserve the fiber strength. By the use of tapered nozzles within the coating applicator the coating could be made concentric around the fiber, and a 40-μm concentric coating was found to be sufficient for the fiber to withstand a mild abrasion test with no deterioration in strength. Strength measurements made in ambient conditions showed that the fiber had a uniform breaking strain of 4% elongation. The same fiber measured at liquid nitrogen temperatures had a breaking strain of 14%, even after extensive handling, which is close to the theoretical glass cohesive strength.     

一种高透过率光纤探针的制作

本文介绍了一种用于近场扫描光学显微镜(NSOM)中的高透过率光纤探针的制作方法。采用缓冲氢氟酸腐蚀低掺杂的普通单模石英光纤,选取适当比例的腐蚀液,可以得到直径、圆锥角均十分理想的针尖。这种方法不需要高掺杂的特殊光纤或是采用先熔拉后腐蚀的复合工艺。针尖经过镀膜后经测量为针尖直径100nm、透过率5.5×10^-4.     

双包层光纤激光器最大输出功率的估算

 通过热传导方程和边界条件得到高功率双包层光纤激光器温度分布的简化解析解，利用ANSYS模拟验证了简化的合理性，并以双包层的掺镱光纤激光器为例，把外包层的临界温度设定为80 ℃，计算了光纤激光器在自然对流、风扇制冷和水制冷条件下最大输出功率。计算结果表明：自然对流的情况下，对流传热系数为10 W·m^-2·Ｋ^-1时，光纤激光器的最大输出功率为105 W；风扇制冷的情况下，对流传热系数为80 Ｗ·m^-2·Ｋ^-1时，光纤激光器的最大输出功率820 W；要达到kW以上功率输出，必须对光纤进行主动水冷。     

170 Mb/s multilevel transmission over 115 m standard step-index plastic optical fiber using an integrated optical receiver

An optical receiver having a high linearity is used for multilevel communication over standard step plastic optical fiber. A large-diameter photodiode with an antireflection coating optimized for red light was integrated. These features enable the used optical receiver to be a promising plastic optical fiber receiver. An error free (< 10⁻⁸) 170 Mb/s data rate over 115 m standard PMMA step-index plastic optical fiber is achieved with four-level and eight-level pulse amplitude modulation.     

光纤涂料对光纤衰减的影响

分析光纤涂料的厚度、应力松驰、热处理及辐射等对光纤衰减的影响。提出应根据光纤技术要求选择既符合工艺条件又与光纤材料相匹配的涂料,并严格控制涂料厚度和同心度,以保证光纤质量。     

Silver-coated near field optical scanning microscope probes fabricated by silver mirror reaction

In this paper, a silver-coated fiber optic nanoprobe is fabricated using silver mirror reaction. Effects of different coating conditions on thickness, uniformity and optical properties of the coated nanoprobes are investigated. In comparison to thermal vacuum evaporation methods, the approach in this work is simpler, less expensive, more reproducible and particularly suitable for coating a long nanoprobe with a low taper angle. While the silver coating is characterized by high uniformity and good stability, the coated nanoprobe demonstrates great optical properties and capability of [Ca²⁺] detection in a single smooth muscle cell, rendering promising potential applications for optical biosensors in intracellular/intercellular biological substrate detection for single cell analysis. PACS  07.79.Fc; 87.85.Rs; 87.85.Ox     

E-glass fibers coated with nickel phosphorous by electroless deposition technique

The nickel phosphorous catalyst coating was studied on the E-glass fiber by electroless deposition using sodium hypophosphite as a reducing agent in alkaline medium. The effects of deposition time, deposition temperature, pH of the solution, and amount of stabilizer used in the solution on the coating efficiency were investigated by X-ray diffraction (XRD), energy dispersive X-ray analysis (EDAX), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and differential thermal analysis (DTA). The XRD indicates the presence of amorphous and crystalline phases of Ni and nickel–phosphorous (NiP). From TGA, it is evident that the NiP coating increases the thermal stability and magnetic properties of the glass fiber. The bath temperature of 80 °C, pH of 9 to 9.5, and stabilizer concentration of 25 g/l are optimum to get a good and uniform coating of NiP on glass fiber. Carbon nanotubes were successfully coated on NiP coated glass fiber at a temperature of 700 °C.     

Mode attenuation in microstructured optical fibers with absorbing coating

The characteristics of leaky modes in microstructured fibers with finite-thickness absorbing coatings are studied theoretically and experimentally. It is shown that, if the thickness of the coating is constant, the fiber has a quasi-periodic transmission spectrum. The period and depth of modulation of the spectrum are determined by resonance coupling between the modes of the fiber and coating. Since the constants of mode propagation in the coating are very sensitive to environmental parameters, the discovered effect seems to be promising for sensor applications.     

Investigation of cladding and coating stripping methods for specialty optical fibers

Fiber optic sensing technology is used extensively in several engineering fields, including smart structures, health and usage monitoring, non-destructive testing, minimum invasive sensing, safety monitoring, and other advanced measurement fields. A general optical fiber consists of a core, cladding, and coating layers. Many sensing principles require that the cladding or coating layer should be removed or modified. In addition, since different sensing systems are needed for different types of optical fibers, it is very important to find and sort out the suitable cladding or coating removal method for a particular fiber. This study focuses on finding the cladding and coating stripping methods for four recent specialty optical fibers, namely: hard polymer-clad fiber, graded-index plastic optical fiber, copper/carbon-coated optical fiber, and aluminum-coated optical fiber. Several methods, including novel laser stripping and conventional chemical and mechanical stripping, were tried to determine the most suitable and efficient technique. Microscopic investigation of the fiber surfaces was used to visually evaluate the mechanical reliability. Optical time domain reflectometric signals of the successful removal cases were investigated to further examine the optical reliability. Based on our results, we describe and summarize the successful and unsuccessful methods.     

Compact Two-Color Pr3+-Doped ZBLAN Fiber Lasers

Two-color laser simultaneous oscillation in compact trivalent praseodymium ion (Pr³⁺)-doped ZrF₄-BaF₂-LaF₃-AlF₃-NaF (ZBLAN) fiber lasers is investigated. Fiber pigtails by coating high-reflective visible dielectric films are utilized as fiber mirrors (FMs) to construct compact all-fiber laser cavity. Reflectance/transmittance of FMs is intentionally designed to balance net gains and reduce gain competition of different lasable wavelengths in the constructed fiber lasers. By using two selected FMs with high reflectivity at green-light and low reflectivity at red-light, simultaneous green and red laser emission in all-fiber Pr³⁺-doped ZBLAN fiber laser is obtained. Moreover, simultaneous orange and red laser emission is also achieved with another selected FM of high reflectivity at orange-light and low reflectivity at red-light. Our work will provide an effective and easy method to construct compact special fiber (e.g.,ZBLAN fiber, chalcogenide fiber) lasers.     

Microstructure and properties of TiB2–TiB reinforced titanium matrix composite coating by laser cladding

TiB₂ particle and TiB short fiber reinforced titanium matrix composite coatings were prepared utilizing in situ synthesized technique by laser cladding on the surface of Ti6Al4V alloy. Through the experiment, it was found that the surface of the single-track coatings appeared in the depression, but it can be improved by laser track overlapping. With the increase of laser power density, the amount of TiB short fiber was increased, and the distribution of TiB₂ and TiB became more uniform from the top to bottom. The micro-hardness of TiB₂/TiB coating showed a gradient decreasing trend, and the average micro-hardness of the coatings was two-fold higher than that of the substrate. Due to the strengthening effect of TiB₂ particle and TiB short fiber, the wear volume loss of the center of the coating was approximately 30% less than that of the Ti–6Al–4V substrate, and the wear mechanism of the coating was mild fatigue particle detachment.     

SiC纤维增强Ti17合金复合材料轴向残余应力的拉曼光谱和X射线衍射法对比研究

准确测量和分析SiC纤维增强Ti合金复合材料(SiC_f/Ti)中残余应力状态对优化复合材料的成型工艺和理解其失效模式具有重要意义,但其残余应力的实验测量和分析仍是一个挑战.石墨C涂层作为SiC纤维与Ti17基体合金之间必需的扩散障涂层,承载了由纤维与基体之间热不匹配引入的残余应力.本文采用显微拉曼光谱法对比测量纤维表面C涂层在复合材料中和去掉基体无应力态下G峰的峰位,通过石墨C涂层应力态下峰位移动计算出SiCf/C/Ti17复合材料中SiC纤维受到～705.0 MPa的残余压应力.采用X射线衍射方法测量了不同方向上该复合材料中基体钛合金的晶面间距以获取其空间应变,根据三轴应力模型分析了复合材料中基体钛合金沿轴向方向的残余应力为～701.3 MPa的张应力,并通过线性弹性理论转化为SiC纤维的残余压应力为～759.4 MPa.两种测试方法都确定了SiC纤维在成型过程中受到残余压应力,且获得的应力值较为接近,都可以用于对SiC_f/Ti复合材料的残余应力测量.