番红花红T敏化的新型光致聚合物全息存储材料

制备了一种以番红花红T为光敏剂的新型全息存储材料,实验结果表明,该材料具有较高的衍射效率、曝光灵敏度和较大的折射率调制度等,最大衍射效率约38.5%,折射率调制度为0.547×10－3,在存储介质膜中存储了模拟全息图像,再现图像有较好的保真度,说明该材料适合用作高密度体全息存储介质。     

含双引发剂的光致聚合物全息特性研究

制备了一种三乙醇胺与N-苯基苷氨酸为共同引发剂的丙烯酰胺基光致聚合物全息存储材料,并用He-Ne 激光器633 nm波长的光对样品进行曝光测试.实验表明,与单引发剂的光致聚合物相比,薄膜的质量有一定的提高,在曝光灵敏度变化不大的情况下,衍射效率有很大提高.优化两种引发剂浓度后,此种共同引发的光致聚合物材料呈现的衍射效率达到54%,曝光灵敏度为1.85×10－2cm2/mJ.还研究了此种光致聚合物的透过率随曝光时间和曝光强度的变化,说明此种光致聚合物材料内部均匀性好,对光的散射小.     

一种核黄素敏化的宽带全息记录材料

制备了一种核黄素敏化的以聚乙烯醇为基质的新型全息存储材料,并研究了材料的全息特性.用Ar+激光器激发的488 nm的蓝光对材料曝光,结果表明该材料具有较高的衍射效率和曝光灵敏度,衍射效率高达53%,灵敏度为3.3 cm2/J,折射率调制度为4.5×10－4.研究了材料的透过率与随时间和入射角度变化的关系,说明在曝光记录过程中有噪音光栅生成.在存储介质膜中存储了全息图像,再现图像较为清晰,说明该材料适合用作高密度全息存储介质.     

绿敏光致聚合物的制备及其光全息存储性能研究

报导了一种新型的对绿光敏感的光致聚合物材料。该材料以丙烯酰胺为单体，由光引发剂，共引发剂，成膜物等组成。本材料记录的全息图衍射效率可达55％。在光聚物上采用角度复用技术存储了10幅图像，得到的再现像信噪比较高。说明该材料适合于大容量体全息存储。     

吖啶橙敏化的光致聚合物及其数字全息存储研究

制备了一种吖啶橙敏化的光致聚合物材料,并研究了材料的全息特性.用Ar+激光器三种波长的光对材料进行记录.结果表明,该材料具有较高的衍射效率、较高的曝光灵敏度和较大的折射率调制度,最大衍射效率均大于40%.将计算机二进制文件经过编码生成的二值图像存入样品,其再现图像较为清晰,译码后能够准确地还原出原文,表明该光致聚合物适合数字全息存储.     

番红花红T光敏感光致聚合物全息存储材料

制备了一种以番红花红T为光敏剂的新型全息存储材料,主要用Ar⁺激光器的514.5nm波长的绿光研究材料的全息特性.研究表明,该材料具有较高的衍射效率、曝光灵敏度和较大的折射率调制度,衍射效率近40%,灵敏度为7.22×10^-4cm²/mJ,折射率调制度为3.65×10^-4,同时,在读出时必须考虑布拉格偏移对全息存储的影响.在介质膜中存储了全息图像,再现图像较为清晰,说明该材料适合用作高密度全息存储介质. 关键词： 全息存储 光致聚合物 衍射效率 布拉格偏移     

一种全可见光敏感的光致聚合物全息特性研究

制备了一种对整个可见光波段都敏感的光全息存储材料,并研究了该材料的透过率、衍射效率、灵敏度等全息特性.用He-Ne激光器633 nm和Ar+ 激光器514 nm,488 nm,476 nm四种波长的光曝光,材料的饱和衍射效率最大为66%,最小为48%;最高灵敏度为8.06×10－3 cm2/mJ.最高折射率调制度为4.22×10－4.用多波长存储时,不同波长的光可存储多幅全息图,且再现图像清晰.结果表明,该材料是较好的高密度数字全息存储材料.     

基于丙烯酰胺为单体的红敏光致聚合物衍射效率增强的研究

目前以丙烯酰胺为单体的光聚物体系在高分辨力下衍射效率不高。从光聚物聚合机理出发．探讨了其主要原因。从单体聚合难易程度角度提出了加入新成分丙烯酸、使用聚合度低的成膜物、增加膜的厚度和优化凉板时间等四种促进单体聚合的措施并从实验上加以了验证。结果表明：在一定条件下。成膜物使用聚合度为341的聚乙烯醇比聚合度为1750的聚乙烯醇体系衍射效率提高了约60％;加入丙烯酸后衍射效率也提高了10％左右,且使用聚合度低的成膜物和加入丙烯酸后体系更不易结晶;厚度和凉板时间均有一个最佳范围。经过优化实验后得到了空间频率在2000lp／mm时衍射效率大于90％,3000lp／mm时大于55％的结果,且利用制备出的材料拍摄出透射和平面反射全息网,说明该材料适合于日益发展的全息显示。     

全息存储用光致聚合物材料的暗增长现象研究

根据光致聚合物中光栅形成机制,应用数学模型与实验相结合的方法,研究了一种新型光致聚合物在全息记录中的暗增长现象.研究表明,应用不同写入光强使衍射效率达到相同的饱和程度后,前期的写入光较弱则对应后期的暗增长程度较强.为了利用暗增长过程提高衍射效率,设计并实施了非连续曝光实验,使曝光与暗增长过程交替进行.并且通过暗增长过程的实验数据拟合出该材料的扩散时间常量为21 s,据此设定非连续曝光的周期.结果表明,相同记录条件下,非连续曝光比连续曝光可以获得更高的衍射效率.     

Holographic behavior of a photopolymer at high thicknesses and high monomer concentrations: mechanism of photopolymerization

One of the main problems involved in the development of holography is that of the recording material used. In this study the behavior of a photopolymer is analyzed when thicknesses greater than 100 μm are used. The photopolymer is made up of acrylamide as monomer, triethanolamine as radical generator, yellowish eosin as sensitizer and polyvinyl alcohol as binder. The main problem is that an increase in thickness produces more scattering and consequently a decrease in the diffraction efficiency. In this study we analyzed the influence of the concentration of monomer on scattering and found that an increase in the concentration reduces scattering. The behavior of the material varies as the concentration of acrylamide is increased. Two polymerization mechanisms compete and so the behavior of the photopolymer is not linear, the reaction is slower and the expected maximum efficiency is not reached. It has been demonstrated experimentally that when the recording intensity is reduced the photopolymer behaves in a linear way. Received: 28 January 2000 / Revised version: 25 July 2000 / Published online: 13 December 2000     

掺杂TiO2纳米颗粒的抗缩皱光致聚合物全息特性的研究

报道了一种掺杂亲水性TiO₂纳米颗粒的丙烯酰胺基光致聚合物厚膜的全息特性.实验结果表明,掺杂TiO₂纳米颗粒后的聚合物材料不仅在曝光过程中厚度缩皱有了明显的降低,而且衍射效率和其他性能参数都有了一定的改善,同时存在一个最佳的掺杂浓度,使得材料的最大衍射效率可以达到92.3%,最大折射率调制度达到2.09×10^-3,体积缩皱降低至0.80%. 关键词： 全息 光致聚合物 衍射效率 布拉格偏移     

Dynamic analysis of holographic gratings in amulti-wavelength visible light sensitive photopolymer

A dynamic theoretical model of photochemistry and hologram formation in holographic photopolymer is established, and the dynamic development process of holographic gratings in the photopolymer is discussed with the model. A novel multi-wavelength visible light sensitive photopolymer for holographic storage is prepared. The influence of exposure wavelength on holographic storage characteristics is analysed. By fitting the experimental data of transmittance and diffraction efficiency to a function of time with different exposure intensities and wavelengths, the variations of dynamic parameters of photochemistry and photopolymerization diffusion are presented.     

非水溶性红敏光致聚合物全息性能的改善及其应用研究

为使非水溶性红敏光致聚合物材料的全息性能得到改善,采用复合光敏增感、复合引发和复合单体的方法反复对比实验,改善后体系的灵敏度为0.02 cm2/mJ,衍射效率高达83%,计算得到材料的最大折射率调制度为4.1×10-3.实验结果和理论分析表明,利用该材料制作的新型全息光栅具有损耗低、通道宽度窄、衍射效率高等优点,适于制作光通信中的波分复用器及各种光学元件.     

碱性品红敏化的光致聚合物在441nm短波长的全息存储特性研究

制备了一种以碱性品红为光敏剂的新型全息存储材料,且使用波长为441nm的He—Cd激光器成功研究了材料的全息特性。研究表明,该材料在短波长处仍具有较高的衍射效率、曝光灵敏度和较大的折射率调制度,衍射效率近60％,灵敏度为2．93×101c群／mJ,折射率调制度为8．85×10．。。在存储介质膜中存储了全息图像,再现图像较为清晰,对比度与保真度较为理想,说明该材料具有较好的全息存储性能,适合作为高密度全息存储介质。     

Hologram multiplexing in acrylamide hydrophilic photopolymers

Unslanted diffraction gratings are recorded in a 900 μm thick acrylamide photopolymer by means of peristrophic multiplexing. A solid state Nd:YAG (λ = 532 nm) laser is used as the recording beam, with a total incident intensity of 5 mW/cm², and a He-Ne laser as the reconstruction beam. The dye concentration in the photopolymer is optimized so that it does not limit the dynamic range. Nine holograms are recorded using constant exposure time scheduling and variable exposure time scheduling. From the results obtained it may be deduced that optimization of the dye allows us to work in the linear response region of the photopolymer and at the same time obtain high values of diffraction efficiency for each hologram. An exponential increase in exposure time as the number of holograms increases enables the values of diffraction efficiency to be homogenized with regard to the case of constant exposure scheduling. In this way, better use is made of the dynamic range of acrylamide hydrophilic photopolymer.     

Fabrication and characterization of poly(methyl methacrylate) photopolymer doped with 9,10-phenanthrenequinone (PQ) based derivatives for volume holographic data storage

We present our studies on the photopolymer of poly(methyl methacrylate) (PMMA) doped with 9,10-phenanthrenequinone based derivatives for volume holographic storage. By introducing different functional groups on the side-chain of 9,10-phenanthrenequinone molecule, the holographic characteristics of the material can be modified. The photoreaction involved with the holographic recording in the samples was investigated by measuring UV-Vis absorption spectrum and mass spectrum. The experimental results show that the similar behaviors were exhibited in these photopolymers. It is found that phase hologram recording in our PQ derivatives doped PMMA photopolymer involves a structure change of the quinone based molecule, which induces a strong change of the refractive index. Experimental characterizations on holographic data storage, including material sensitivity, dynamic range (M#) and bit-error-rate have been performed. We found that, by selecting appropriate functional groups, an improvement in sensitivity and M# for holographic data storage can be achieved.     

光致聚合物中单体及粘结剂对全息性能的影响

研究了单体及粘结剂等成份对全息光致聚合物薄膜光存储性能的影响。在相同引发条件下．以丙烯酰胺作为单体时，光聚物的衍射效率明显高于以丙烯酸和N羟甲基丙烯酰胺作为单体时光聚物的衍射效率。向丙烯酰胺中加入少量N-羟甲基丙烯酰胺，可以改善膜表面的光学质量．降低散射光强度，并提高膜的保存时间。在聚乙烯醇膜中单体聚合程度明显优于在聚乙烯吡咯烷酮中的程度，在大分子量的聚乙烯醇中的衍射效率及感光灵敏度高于在小分子量中的衍射效率和感光灵敏度，而且大分子量的聚乙烯醇能够制备厚膜，这是实现全息海量存储的一个重要因素。     

Holographic storage of three-dimensional image and data using photopolymer and polymer dispersed liquid crystal films

We present holographic storage of three-dimensional(3D) images and data in a photopolymer film without any applied electric field.Its absorption and diffraction efficiency are measured,and reflective analog hologram of real object and image of digital information are recorded in the films.The photopolymer is compared with polymer dispersed liquid crystals as holographic materials.Besides holographic diffraction efficiency of the former is little lower than that of the latter,this work demonstrates that the photopolymer is more suitable for analog hologram and big data permanent storage because of its high definition and no need of high voltage electric field.Therefore,our study proposes a potential holographic storage material to apply in large size static 3D holographic displays,including analog hologram displays,digital hologram prints,and holographic disks.     

Holographic properties of Fe3O4 nanoparticle-doped organic–inorganic hybrid photopolymer

An organic–inorganic hybrid photopolymer doped with sodium-citrate-coated Fe₃O₄ nanoparticles was fabricated. The experimental results showed that the maximum diffraction efficiency could be increased from 69 to 90%, and the maximum refractive index modulation improved from 1.386 × 10⁻³ to 2.083 × 10⁻³. It also found that the volume shrinkage during holographic exposure was noticeably suppressed without affecting the optical quality of the photopolymer.     

Effect of the incorporation of N,N′-methylene-bis-acrylamide on the multiplexing of holograms in a hydrophilic acrylamide photopolymer

The behaviour of a hydrophilic acrylamide photopolymer, with and without crosslinker (N,N′-methylene-bis-acrylamide), in solid layers 700 μm thick is analyzed. Slanted diffraction gratings are multiplexed at constant and variable exposure. Variable exposure time scheduling, with increased exposure time by steps is used in order to determine the effect on the dynamic range and the homogenization of diffraction efficiency values. This scheduling results in a greater dynamic range compared with constant time multiplexing. For crosslinked photopolymer, those exposure times are excessive (higher energetic sensitivity) and there is overlapping of the individual angular response curves for each stored diffraction grating.