一种新型有机金属化合物纳秒时域饱和吸收特性研究

合成了一种新型有机金属配合物Cetyltrimethylammonium-bis(2-thioxo-1,3- dithiole- 4,5-dithiolato)-copper(简称CtCu)材料.采用单光束Z扫描测试技术,在波长为1 053 nm,脉宽为1 ns的条件下研究了该样品的三阶非线性光学性质.研究发现,该材料具有很强的饱和吸收特性,激发态的有效吸收截面为σeff＝1.10×10－19 cm2,与基态吸收截面的比值为1∶484.利用非线性透过率实验验证了材料的饱和吸收特性,并对其产生机理进行了分析.实验结果表明,该材料在近红外波段的激光脉冲压缩方面有潜在的应用前景.     

有机紫外滤波材料的紫外光谱性质研究

通过缩合反应合成了一种有机紫外滤波染料--2,7-二甲基-3,6-偶氮环庚-1,6-二烯高氯酸盐,并采用元素分析、红外光谱、紫外光谱等手段对其进行表征,着重讨论了不同浓度的染料溶液和染料掺杂的聚乙烯醇(PVA)薄膜的紫外光谱性质.实验表明,当染料浓度较低时,溶液的最大吸收波长为322 nm,薄膜的最大吸收波长为325 am.随着染料浓度的增加,溶液和PVA膜紫外截止通带宽度加宽,表现为285～345 nm区间为强吸收带,而在日盲紫外波段(240～285 nm)保持较高的透过率.利用染料溶液和染料掺杂的PVA膜的这种光谱特性,制作出日盲紫外滤波器.     

一种新型有机染料HEASPS在不同波长时的双光子吸收和频率上转换性质研究

报道了一种新型双光子吸收染料 ,即反式 - 4- [4′- (N-羟乙基 - N-乙基胺基 )苯乙烯基 ]- N-甲基吡啶对甲苯磺酸盐的非线性光学性质 ;测试了染料在 72 0～ 110 0 nm波段的非线性透过率曲线。结果发现 :双光子吸收最强波长相对线性吸收峰波长的两倍处有明显蓝移 ;计算出的相应波长的双光子吸收截面在 930 nm处染料有最大双光子吸收截面(2 .0 6× 10 - 4 7cm4·s/ photon) ;测量了染料在 90 0～ 110 0 nm波段的上转换效率 ,在 10 2 0 nm处有最高效率 (5 .1% ) ,最高激射效率的波长相对最强双光子吸收的波长有明显红移     

基于垂直层叠结构的可见/近红外双波段传感器研究

提出了基于垂直层叠结构的双波段传感器,该结构为同时对可见波段和近红外波段进行成像提供了可能。它的基本原理是利用不同波长的光在硅材料中穿透深度的非线性分布,即:短波长的可见光主要在表面被吸收,长波长的近红外光则主要在更深的位置被吸收。通过垂直层叠结构,抽取不同深度的光生载流子,即可以得到相应波段的成像信息。数值仿真分析表明,结构参量为D1=2μm,D2=18μm的结构能在400~1200 nm波长范围得到响应峰值波长为550 nm和1000 nm的最佳可见/近红外响应。     

高重复频率激光脉冲作用下KTP晶体中的灰迹

采用波长为1 064 nm/532 nm、脉宽6 ns(FWHM)的高重复频率调Q激光,研究了磷酸氧钛钾(KTP)晶体中灰迹的产生机理,以及色心密度对灰迹的影响。晶体透过率表征了色心密度,根据透过率与色心密度的关系以及色心密度对灰迹产生的决定作用,定义临界灰迹密度,当晶体透过率高于此值时可安全运行,而低于此值时,为避免晶体发生灾难性损伤应立即停止运行。实验结果表明:灰迹不仅大量吸收紫外及可见光能量,而且大量吸收近红外波段能量,这为灰迹的在线监测提供了一种监测方法。     

基于金纳米笼的1106 nm被动调Q Nd:GAGG激光器

成功制备了金纳米笼溶液并将其作为饱和吸收体,实现了中心波长为1106 nm的Nd:GAGG激光器的调Q运转。在输出镜透过率为3%的激光器中,在泵浦功率6.70 W下获得的最大平均输出功率为98 mW,此时对应的脉冲重复率为206 kHz,最短脉冲宽度为436 ns;在输出镜透过率为7%的激光器中,当泵浦功率为7.69 W时,得到的最大平均输出功率为121 mW,最短脉冲宽度为370 ns,对应的脉冲重复率为170 kHz。实验结果证明了金纳米笼在近红外波段激光器中用作饱和吸收体的巨大潜力。     

光学透明频率选择表面的研究

运用谱域Galerkin法对光学透明带通频率选择表面(FSS)进行了分析计算,研究了透明导电膜的电导率对光学透明带通FSS频率选择特性的影响. 计算及实验结果表明：在雷达波段,透明导电膜的电导率主要影响光学透明带通FSS在中心频率处的透过率,光学透明带通FSS在透可见反雷达波的同时,还具有选择性透过雷达波段的特性. 关键词： 频率选择表面 透明导电膜 电导率     

CdSe/ZnS核-壳结构量子点的非线性光学吸收

利用开孔Z扫描技术研究了吸收峰分别为553 nm和503 nm的两种尺寸CdSe/ZnS核-壳结构量子点溶液的非线性吸收性质.对于532 nm,6 ns激光脉冲,两种材料均表现出饱和吸收向反饱和吸收转化的现象.数值模拟结果表明：当吸收峰波长大于激光波长时,饱和吸收过程由快、慢两种机制组成,分别对应基态载流子被激发至不同的激发态,而强光下的反饱和吸收与快过程相关;当吸收峰波长小于激光波长时,饱和吸收主要由快过程机制引起,强光下的反饱和吸收源自激发态吸收和双光子吸收.我们的研究结果表明半导体量子点是研制光开关和光限制器件的理想候选材料.     

CdSe/ZnS核-壳结构量子点的非线性光学吸收

利用开孔Z扫描技术研究了吸收峰分别为553nm和503nm的两种尺寸CdSe/ZnS核-壳结构量子点溶液的非线性吸收性质.对于532nm,6ns激光脉冲,两种材料均表现出饱和吸收向反饱和吸收转化的现象.数值模拟结果表明:当吸收峰波长大于激光波长时,饱和吸收过程由快、慢两种机制组成,分别对应基态载流子被激发至不同的激发态,而强光下的反饱和吸收与快过程相关;当吸收峰波长小于激光波长时,饱和吸收主要由快过程机制引起,强光下的反饱和吸收源自激发态吸收和双光子吸收.我们的研究结果表明半导体量子点是研制光开关和光限制器件的理想候选材料.     

基于典型目标反射率的近红外场景仿真

利用积分球对近红外增强相机进行了可见、近红外波段的辐射定标,并采用该相机采集了典型目标的可见、近红外图像.利用便携式地物光谱仪采集了相同目标可见、近红外波段的光谱反射率曲线,并分析了目标在可见、近红外波段的光谱反射特性.通过寻找同一天气条件、同一时间段所拍摄的典型目标近红外图像灰度值与可见光图像灰度值及典型目标可见、近红外波段反射率之间的关系,提出一种基于可见光图像及目标反射率反演近红外图像的算法.在近红外图像反演过程中考虑了大气透过率的影响,反演结果表明,本文算法可以较好地体现典型目标近红外图像的全局特征,为后续不同天气条件下近红外场景仿真的实现提供参考.     

碳纳米管/二硒化钼有机玻璃的非线性吸收、非线性散射和光限幅特性

MoSe₂的禁带宽度较窄（1.1–1.5 eV）,且具有可调谐的激子光电效应,这样使其在光致发光、光电晶体管、太阳能电池和光学非线性等方面具有潜在的应用价值.然而,纯的MoSe₂的光生电子空穴复合率较高,限制了其在某些光学领域中的应用.通过设计MoSe₂的复合材料,可以降低材料的光生电子空穴复合率,从而扩展其应用领域.首先,通过热溶剂法合成CNT/MoSe₂复合材料;然后,通过浇铸法将其分散在甲基丙烯酸甲酯（MMA）中制备成有机玻璃,其中MMA会聚合成聚甲基丙烯酸甲酯（PMMA）,并利用改进的Z-扫描技术首次对CNT/MoSe₂/PMMA有机玻璃的非线性吸收、非线性散射和光限幅特性进行了研究.研究表明,随着输入能量的变化,通过调节输入能量,CNT/MoSe₂/PMMA有机玻璃表现出饱和吸收（SA）和从SA到反饱和吸收的转变.结合材料特性及应用条件要求,可以得到CNT/MoSe₂/PMMA有机玻璃在光学设备,如光学限制器和锁模/调Q激光器等方向具有较好的应用前景.     

2-μm mode-locked nanosecond fiber laser based on MoS_2 saturable absorber

We demonstrated a 2-μm passively mode-locked nanosecond fiber laser based on a MoS_2 saturable absorber(SA).Owing to the effect of nonlinear absorption in the MoS_2 SA, the pulse width decreased from 64.7 to 13.8 ns with increasing pump power from 1.10 to 1.45 W. The use of a narrow-bandwidth fiber Bragg grating resulted in a central wavelength and 3-dB spectral bandwidth of 2010.16 and 0.15 nm, respectively. Experimental results show that MoS_2 is a promising material for a 2-μm mode-locked fiber laser.     

(Cu,N)共掺杂TiO2/MoS2异质结的电子和光学性能:杂化泛函HSE06

在密度泛函理论的基础上,系统地研究了Cu/N（共）掺杂的TiO₂/MoS₂异质结体系的几何结构、电子结构和光学性质.计算发现,TiO₂/MoS₂异质结的带隙相比于纯的TiO₂（101）表面明显变小,Cu/N（共）掺杂TiO₂/MoS₂异质结体系的禁带宽度也明显地减小,这导致光子激发能量的降低和光吸收能力的提高.通过计算Cu/N（共）掺杂TiO₂/MoS₂的差分电荷密度,发现光生电子与空穴积累在掺杂后的TiO₂（101）表面和单层MoS₂之间,这表明掺杂杂质体系可以有效地抑制光生电子-空穴对的复合.此外,我们计算了在不同压力下TiO₂/MoS₂异质结的几何、电子和光学性质,发现适当增加压力可以有效提高异质结的光吸收性能.本文结果表明,Cu/N（共）掺杂TiO₂/MoS₂异质结和对TiO₂/MoS₂异质结加压都能有效地提高材料的光学性能.     

Tuning band alignment and optical properties of 2D van der Waals heterostructure via ferroelectric polarization switching

Favourable band alignment and excellent visible light response are vital for photochemical water splitting. In this work, we have theoretically investigated how ferroelectric polarization and its reversibility in direction can be utilized to modulate the band alignment and optical absorption properties. For this objective, 2D van der Waals heterostructures (HTSs) are constructed by interfacing monolayer MoS₂ with ferroelectric In2Se3. We find the switch of polarization direction has dramatically changed the band alignment, thus facilitating different type of reactions. In In₂Se₃/MoS₂/In₂Se₃ heterostructures, one polarization direction supports hydrogen evolution reaction and another polarization direction can favour oxygen evolution reaction. These can be used to create tuneable photocatalyst materials where water reduction reactions can be selectively controlled by polarization switching. The modulation of band alignment is attributed to the shift of reaction potential caused by spontaneous polarization. Additionally, the formed type-II van der Waals HTSs also significantly improve charge separation and enhance the optical absorption in the visible and infrared regions. Our results pave a way in the design of van der Waals HTSs for water splitting using ferroelectric materials.     

Electronic and optical properties of 3N-doped graphdiyne/MoS2 heterostructures tuned by biaxial strain and external electric field

The construction of van der Waals (vdW) heterostructures by stacking different two-dimensional layered materials have been recognised as an effective strategy to obtain the desired properties. The 3N-doped graphdiyne (N-GY) has been successfully synthesized in the laboratory. It could be assembled into a supercapacitor and can be used for tensile energy storage. However, the flat band and wide forbidden bands could hinder its application of N-GY layer in optoelectronic and nanoelectronic devices. In order to extend the application of N-GY layer in electronic devices, MoS₂ was selected to construct an N-GY/MoS₂ heterostructure due to its good electronic and optical properties. The N-GY/MoS₂ heterostructure has an optical absorption range from the visible to ultraviolet with a absorption coefficient of 10⁵ cm^-1. The N-GY/MoS₂ heterostructure exhibits a type-Ⅱ band alignment allows the electron-hole to be located on N-GY and MoS₂ respectively, which can further reduce the electron-hole complexation to increase exciton lifetime. The power conversion efficiency of N-GY/MoS₂ heterostructure is up to 17.77%, indicating it is a promising candidate material for solar cells. In addition, the external electric field and biaxial strain could effectively tune the electronic structure. Our results provide a theoretical support for the design and application of N-GY/MoS₂ vdW heterostructures in semiconductor sensors and photovoltaic devices.     

Passively mode-locked erbium-doped fiber laser via a D-shape-fiber-based MoS_2 saturable absorber with a very low nonsaturable loss

We report on the generation of conventional and dissipative solitons in erbium-doped fiber lasers by the evanescent field interaction between the propagating light and a multilayer molybdenum disulfide(MoS_2) thin film. The MoS_2 film is fabricated by depositing the MoS_2 water–ethanol mixture on a D-shape-fiber(DF) repetitively. The measured nonsaturable loss, saturable optical intensity, and the modulation depth of this device are 13.3%, 110 MW/cm~2, and 3.4% respectively.Owing to the very low nonsaturable loss, the laser threshold of conventional soliton is as low as 4.8 mW. The further increase of net cavity dispersion to normal regime, stable dissipation soliton pulse trains with a spectral bandwidth of 11.7 nm and pulse duration of 116 ps are successfully generated. Our experiment demonstrates that the MoS_2-DF device can indeed be used as a high performance saturable absorber for further applications in ultrafast photonics.     

Optical limiting in cobalt-doped polyvinylpyrrolidone

The results of optical limiting investigations of cobalt-doped polyvinylpyrrolidone solutions are presented. The optical limiting studies have shown that this process is due to self-defocusing at the wavelength of 1064 nm and also due to reverse saturable absorption and self-defocusing at the wavelength of 532 nm. The results of measurements on the non-linear optical characteristics of organometallic complexes are presented. Received: 10 July 2001 / Revised version: 15 October 2001 / Published online: 29 November 2001     

Linear optical characterization of chalcogenide glasses

A simple experimental method is used to obtain the evolution of both the refractive index and the linear absorption coefficient as a function of the optical wavelength in the near infrared range (from 900 up to 1700 nm with 10 nm resolution). Several chalcogenide glasses (As₂S₃, As₂Se₃, GeSe₄) are tested and the corresponding Cauchy coefficients are determined. Comparison of our results shows a good agreement with values available in the literature at some wavelength. Application of this method is used to estimate Cauchy coefficients of Ge₁₀As₁₀Se₈₀ for the first time to our best knowledge.     

Enhanced optical limiting performance of a novel molybdenum complex of fullerene

Reverse saturable absorption of a novel molybdenum complex of fullerene (η²-C₆₀) Mo(CO)₂(o-phen)(DBM)·2C₆H₆·C₅H₁₂ has been investigated under irradiation of 10 ns laser pulses at 532 nm. An enhancement of the optical limiting behavior was observed in comparison with C₆₀. An explanation based on the enhanced triplet-state absorption caused by the intra-molecular charge transfer was predicted. The relationship between the clamped laser fluence and low-intensity transmissivity, or the concentration of the solution, was also investigated and a linear dependence was revealed.     

MBE法制备VO2薄膜及其中红外调制深度测量

为了给VO₂薄膜在定向红外对抗系统防护方面的应用提供理论依据,我们用透过率调制深度表征VO₂薄膜在中红外波段的相变特性。本实验利用分子束外延法（MBE）制备VO₂外延单晶薄膜,经XRD、AFM表征,发现其具有（020）择优取向、纯度较高,薄膜表面平整、均匀且致密。经VU-Vis-IR测量发现其近红外透过率相变特性显著,但在紫外和可见光范围内透过率相变特性较不明显。然后我们对制备时间为30 min、40 min的两组薄膜分别进行25~70℃的升温和降温实验,观察其对波长为3 459 nm、脉宽50 ns、重频50 kHz、功率密度0.14 W/cm²的中红外激光的透过率变化,并比较两组薄膜的温滞曲线特性。实验发现它们对中红外透过率的调制深度均可达60%以上,前者比后者对中红外的调制深度高出约4%。这说明利用分子束外延法制备的VO₂单晶薄膜具有良好的中红外调制特性,且调制深度和膜厚有关。进一步表明了利用VO₂薄膜实现中红外激光防护具有一定的可行性。