Fine structure and isotope shift of the 3s4d 3 D-3s3p 3 P, 3s5d 3 D-3s3p 3 P and 3p 2 3 P-3s3p 3 P Transitions of MgI

Summary We report the measurements of the³ D(3s4d)-³ P(3s3p)³ D(3s5d)-³ P(3s3p), and³ P(3p ²)-³ P(3s3p) transition frequency of MgI, the fine-structure separation and isotope shift between²⁴Mg and²⁶Mg. The measurements have been performed in a metastable atomic beam; a good agreement is found for data already existing in the literature. The accuracy of the measurements reported in this paper is mainly limited by the Doppler broadening of theI ₂ transitions used as a reference and by the precision in the knowledge of the related wavelengths.     

Er3+/Yb3+共掺LiNbO3晶体中Er3+的光谱特性分析

在室温下,测量了采用Czochralski方法生长的as-grown和经退火处理的Z切Er^3＋／Yb^3＋共掺同成分LiNbO3晶体的α偏振吸收光谱（300-1650nm）。运用Judd—Ofelt理论对该晶体中Er^3＋的光谱特性进行了分析。由所测得的吸收系数的积分计算得到了从基态到激发态的若干个主要的电子跃迁强度实验值。利用最小二乘法确定出Er^3＋／Yb^3＋共掺LiNbO3晶体中Er^3＋的Judd-Ofelt参数。进而确定了自发辐射概率,从激发态能级到其各个下能级的荧光分支比以及能级辐射寿命。此外,还讨论了Yb^3＋的共掺和退火处理对LiNbO3晶体中Er^3＋光谱特性的影响。     

（LaO）3BO3中Eu^3＋和Sm^3＋的光致发光

研究了紫外光激发下，（ＬａＯ）３ＢＯ３基质中Ｅｕ＾３＋和Ｓｍ＾３＋的光谱性质，Ｅｕ＾３＋和Ｓｍ＾３＋的电荷迁移激发带及发光强度随组成和结构变化的规律性，并探讨了Ｅｕ＾３＋和Ｓｍ＾３＋自身浓度猝灭的机理。     

Improvement of Photoluminescence of Perovskite CH_3NH_3Pb I_3 by Adding Additional CH_3NH_3I during Grinding

The organic-inorganic hybrid perovskite CH_3NH_3PbI_3 has been a good candidate for many optoelectronic applications such as light-emitting diodes due to its unique properties.Optimizing the optical properties of the CH_3NH_3PbI_3 material to improve the device performance is a hot topic.Herein,a new strategy is proposed to enhance the light emission of CH_3NH_3PbI_3 phosphor effectively.By adding the reactant CH_3NH_3I powder in an appropriate proportion and simply grinding,the emission intensity of CH_3NH_3PbI_3 is greatly improved.The advantages of the proposed method are swiftness,simplicity and reproducibility,and no requirement for a complex organic ligand.The mechanism of this phenomenon is revealed by x-ray diffraction,scanning electron microscopy,energy dispersive spectroscopy,photoluminescence,and temperature-dependent photoluminescence.This study offers a unique insight for optimizing the optical properties of halide perovskite materials.     

Symmetry breaking and the decays ψ′ → J/ψπ(η) and J/ψ → η(η′) γ

The theoretical mechanisms for the decays ψ′ → ψπ⁰ and ψ′ → ψη, which violate SU₂ and SU₃, respectively discussed. It is argued that symmetry breaking in the decay amplitudes may be as important as π⁰ −η −η′ mixing. The π⁰ −η mechanism ψ′ → ψν → ψπ⁰ leads to Γ(ψ′ → ψπ⁰) = (3.3±1.0) × 10⁻³ Γ(ψ′ → ψν), but this number may be enhanced by a factor as large as 12 by π⁰−η′ mixing and isospin violation in the decay amplitude. The related decays ψ → ηγ and ψ → η′γ are also discussed.     

The role of CeF3 in LaCl3 scintillation crystal

The properties of LaCl₃:CeF₃ crystal are investigated and its hydroscopic nature has a much more decrease than that of LaCl₃:CeCl₃ crystal. The scintillation properties of LaCl₃:CeF₃ maintain as excellent as that of LaCl₃:CeCl₃. The LaCl₃:CeF₃ crystal has a good optical transmittance without obvious optical absorption bands between 322 and 800 nm, and has the same absorption edge as the LaCl₃:CeCl₃ crystal (about 315 nm). Its emission spectra, decay time and light yield are the same as the LaCl₃:CeCl₃.     

Er3+,Yb3+共掺杂SrTiO3超细粉末的可见上转换发光

钛酸锶(SrTiO₃)具有高介电常数、良好的绝缘性质、优良的物理化学稳定性和在可见光范围内的优异的透明度等优点,是一种重要的无机功能材料。近年来,Al³⁺,Ga³⁺等离子共掺杂的SrTiO₃:Pr³⁺做为一种优异的红色场发射显示(FED)荧光粉引起了人们的兴趣。另外,SrTiO₃具有相对较小的声子频率,因而它可以作为一种有利于上转换发光的基质材料。以NaCl为助熔剂制备了Er³⁺,Yb³⁺共掺杂的SrTiO₃超细粉末。在980nm激发下,样品发出很强的来自于Er³⁺离子的²H_11/2→⁴I_15/2,⁴S_3/2→⁴I_15/2(绿光)和⁴F_9/2→⁴I_15/2(红光)跃迁的上转换发光。Yb³⁺离子的共掺杂对Er³⁺离子的上转换发光起明显的增强作用。研究了上转换发光强度与稀土离子浓度以及激发光强度之间的依赖关系,表明在Er³⁺单掺杂和Er³⁺,Yb³⁺共掺杂的样品中,绿光和红光都是被双光子激发过程激发的。还对上转换发光的机理做了初步分析。     

Experimental observation of the Σ hypernuclei, ΣH and ΣC

The hypernuclei _Σ⁶H and _Σ¹⁶C were observed by the (K⁻, π⁺) reaction on targets of ⁶Li and liquid O, respectively, at 713 MeV/c incident K⁻ momentum. Structure is seen in _Σ⁶H which may be interpreted in terms of particle-hole excitations similar to the previously observed states in _Λ⁶Li. The inablitity to resolve individual Σ hypernuclear levels in _Σ¹⁶C, due in part to the excitation of non-coherent states as a result of the large momentum transfer of about 130 MeV/c, precludes the extraction of the Σ-nucleus spin-orbit potential strength. The Σ-nucleus well depth appears to be 7 to 10 MeV less than that for the Λ.     

Ultrafast Terahertz Probes of Charge Transfer and Recombination Pathway of CH_3NH_3PbI_3 Perovskites

We use transient terahertz photoconductivity measurements to demonstrate that upon optical excitation of CH_3NH_3PbI_3 perovskite, the hole transfer from CH_3NH_3PbI_3 into the organic hole-transporting material(HTM)Spiro-OMe TAD occurs on a sub-picosecond timescale. Second-order recombination is the dominant decay pathway at higher photo-excitation fluences as observed in neat CH_3NH_3PbI_3 films. In contrast, under similar experimental conditions, second-order recombination weakly contributes the relatively slow recombination between the electrons in the perovskite and the injected holes in HTM, as a loss mechanism at the CH_3NH_3PbI_3/Spiro-OMe TAD interface. Our results offer insights into the intrinsic photophysics of CH_3NH_3PbI_3-based perovskites with direct implications for photovoltaic devices and optoelectronic applications.     

In-plane oriented CH_3NH_3PbI_3 nanowire suppression of the interface electron transfer to PCBM

One-dimensional nanowire is an important candidate for lead-halide perovskite-based photonic detectors and solar cells. Its surface population, diameter, and growth direction, etc., are critical for device performance. In this research,we carried out a detailed study on electron transfer process at the interface of nanowire CH_3 NH_3 PbI_3(N-MAPbI_3)/Phenyl C61 butyric acid methyl-ester synonym(PCBM), as well as the interface of compact CH_3 NH_3 PbI_3(C-MAPbI_3)/PCBM by transient absorption spectroscopy. By comparing the carrier recombination dynamics of N-MAPbI_3, N-MAPbI_3/PCBM,C-MAPbI_3, and C-MAPbI_3/PCBM from picosecond(ps) to hundred nanosecond(ns) time scale, it is demonstrated that electron transfer at N-MAPbI_3/PCBM interface is less efficient than that at C-MAPbI_3/PCBM interface. In addition, electron transfer efficiency at C-MAPbI_3/PCBM interface was found to be excitation density-dependent, and it reduces with photo-generation carrier concentration increasing in a range from 1.0 × 1018 cm~(-3)–4.0 × 1018 cm~(-3). Hot electron transfer,which leads to acceleration of electron transfer between the interfaces, was also visualized as carrier concentration increases from 1.0 × 10~(18) cm~(-3)–2.2 × 10~(18) cm~(-3).     

KZnF3:Ce3+,Tb3+纳米粒子合成与发光

采用微乳液法合成了Ce3 ,Tb3 单掺和双掺KZnF3纳米晶。分析了样品的结构与形态,结果表明,所合成的样品均为单相,颗粒粒度分布均匀。讨论了光谱特性,并与高温固相法合成的产物作了对比。研究发现,KZnF3:Ce3 纳米晶的发射光谱与体相多晶相比,最强峰位置红移约35nm;在KZnF3纳米晶双掺体系中存在Ce3 →Tb3 能量传递,尤其是Tb3 的5D4→7F5跃迁发射显著增强,有望成为一种有发展前途的绿色荧光材料。     

Gd3+,Yb3+和Tm3+共掺杂氟化物纳米晶中Yb3+-Tm3+-Gd3+间的能量传递

用水热法合成了Y_0.8-x-yF₃∶Gd_x³⁺,Yb_0.2³⁺,Tm_y³⁺纳米晶的上转换发光材料。在典型的Y_0.595F₃∶Gd_0.200³⁺,Yb_0.200³⁺, Tm_0.005³⁺纳米微晶中,在980 nm激光激发下,观察到了Tm³⁺的紫外、紫色上转换发射明显增强和来自于Gd³⁺的⁶D_9/2、⁶I_J、⁶P_5/2及⁶P_7/2能级到基态⁸S_7/2能级的紫外发射。通过比较Y_0.8-x-yF₃∶Gd_x³⁺ ,Yb_0.2³⁺,Tm_y³⁺纳米晶样品的上转换发光性质以及Tm³⁺和Gd³⁺中一些激发态的能级寿命,借助于能级图描述了Yb³⁺-Tm³⁺-Ga³⁺之间的有效的能量传递过程。     

Absorption and photoluminescence of YAG:Er3+, YAG:Ce3+, and YAG:Er3++Ce3+ crystals

We have studied absorption and luminescence spectra of yttrium-aluminum garnets doped with Er³⁺ and Ce³⁺ ions, as well as co-doped with Er³⁺+Ce³⁺ impurity ions. Luminescence of studied crystals was excited by cw laser radiation at the wavelengths 457 and 980 nm. We revealed obvious display of the energy transfer processes occurring in the impurity subsystem of a YAG: Er³⁺+Ce³⁺ crystal.     

Nanoscale multiphase separation at La(2/3)Ca(1/3)MnO3/SrTiO3 interfaces

55Mn nuclear magnetic resonance experiments are reported on a series of fully strained epitaxial La(2/3)Ca(1/3)MnO3 thin films on SrTiO3. We have found evidence of multiple phase segregation into ferromagnetic metallic and nonmetallic regions as well as regions that are nonferromagnetic and insulating. These insulating regions are mainly located close to interfaces and may have a significant impact on the performance of spin-tunnel devices. As a result of phase segregation, the ferromagnetic coupling within the metallic regions is depressed. This accounts for the reduction of the Curie temperature and conductivity in nanometric thin films.     

Epitaxial growth of Nb3Ge on Nb3Ir and Nb3Rh

This is a report on a cooperative research carried out in Stanford University to investigate the possibility of using epitaxy to prepare the high T_c superconductor Nb₃Ge in an A15 crystalline structure at the 3:1 stoichiometry.Nb₃Ir polycrystalline films with the A15 structure deposited on sapphire were used as substrates for the epitaxial growth of Nb₃Ge because of the favorable lattice parameter match. The experimental results clearly show that epitaxial growth indeed occurs and helps to extend the range of homogeneity of the A15 phase up to 26.3 at.% Ge as compared with the thermodynamic equilibrium boundary at 19 at.% Ge. We also used Nb₃Rh films as substrates and found them inferior to Nb₃Ir because of the multiphase nature of the films.In addition to extending the A15 phase boundary epitaxy results in a considerable rise in the superconducting transition temperature for Ge-rich samples together with a reduction in the transition width. The work suggests that polycrystalline epitaxy can be an important tool in the synthesis of thin-film intermetallic compounds.     

3He spin diffusion measurements in 3He- 4He mixture films

3He spin diffusion measurements for 3He-4He mixture films on Nuclepore are reported as a function of 3He coverage for 0. 030相似文献   

Absorptionsspektren von Er3+ in InCl3 und in ScCl3

The optical absorption spectra of Er³⁺ in single crystals of InCl₃ and ScCl₃ have been obtained between 14,000 and 29,000 cm^?1. The observed crystal field splittings are interpreted in terms of crystal potential of symmetry 3m for ScCl₃ and of symmetry 2m for InCl₃. There is however found, that for both cases the splittings will be approximately explained by a crystal potential of cubic symmetry. The employed hostlattices are of special interest, because the ions of the iron series can occupy the same sites as the rare earth ions.     

Regge-pole description of γN→πN backward-scattering data

Baryon Regge-pole contributions to u-channel helicity amplitudes for the γN→πN processes are derived, with attention to kinematic singularities and threshold conditions. An N, Nγ and Δδ Regge-exchange model is proposed that describes the backward scattering data on γp→π^op and γp→π⁺n at high energy. The N and Nγ trajectories are found to be nearly degenerate, with residues in the ratio β(Nγ)/β(N)≈0.6. Structure in the differential cross sections is explained as dominance at small u giving way to dominance at large u. An isoscaar-isovector admixture for the γ-coupling to is required by the fits. The solution extrapolates through the mean γp→π^op 180^o differential cross section at intermediate energies, as required by duality.     

一种新型稀土有机电致发光材料：Eu(NO3)3phen

稀土离子的窄谱带发射能够很好地满足彩色显示的要求,寻找新的具有更高荧光量子效率的稀土有机材料作为发光层,以做出更高发光亮度的有机电致发光器件是非常有意义的。     

水杨酸-Tb3+(Gd3+)络合物的高效发光

合成了水杨酸-Tb3+和水杨酸-Tb3+(Gd3+)高效发光材料.通过发射光谱、激发光谱和荧光衰减时间的测定,观察到了水杨酸根与Tb3+之间的能量传递,并获得了高效发光.以Gd3+代替4/5摩尔的Tb3+也得到较好的结果.