聚合物慢极化的唯象理论

将晶态相变中的唯象理论方法推广用于聚合物，说明了聚合物结构转变过程中的介电行为和空间电荷驻极体效应．晶态相变是一级结构的转变，联系着快极化介电常数ε_h的异常．聚合物的各种转变是二级和三级结构的转变，ε_h并无异常而出现慢极化介电常数倒数ε_l^-1的抛物型软化．理论与聚丙烯的实验结果很好地符合 关键词：     

梳型聚合物液晶的介电反应

计算了梳型聚合物双轴丝状相液晶侧链的扭曲缺陷能,对处于外电场的侧链,将其哈密顿量与一维Ising模型相比较,得到侧链在外电场中的极化率.结果表明,聚合物的电极化率远大于普通液晶.在低温下,两者之间的比值趋于聚合度N.对弛豫时间的计算表明,聚合物液晶的极化达到饱和的时间很长,在低温下是普通液晶的N倍,而介电损耗出现的频率则为普通液晶的1/N倍. 关键词：     

偶氮苯聚合物的光致异构与分子链段的取向效应

本文通过实验和计算机模拟对偶氮苯聚合物光致双折射的写入、弛豫、擦写特性进行研究并对光致双折射的产生机制提出了一个新模型.指出对光致双折射有贡献的不仅是光致异构,分子链段的取向也有贡献,因而导致光致双折射有快和慢两个过程。     

用介电时域方法分析聚合物的慢响应

在－３０℃至１４０℃温度范围内用时域方法研究聚合物ＰＥＴ、ＰＳ材料的慢极化响应，获得了一些关于聚合物的有用信息，实验表明，微分时域谱方法简单明了，意义清晰，是很有前途的介电时域研究手段。     

极性相变的介电谱研究

用时域和频域方法研究了(Ba_1-xSr_x)TiO₃陶瓷的极性相变.类似于单晶的铁电相变所观察到的晶格软化,屏蔽电荷激发和畴运动讯号外,在陶瓷中还出现空间电荷运动的强讯号.空间电荷和电畴属于凝聚态物质的高级结构,它提供慢极化效应.慢效应使频域测量结果不能得到确定值.从统计观点给出高级结构的历史记忆效应对频域测量结果的影响;解释了频域介电常量的倒数在一级结构的转变中发生线性软化,而在高级结构的转变中发生抛物型软化. 关键词：     

摩擦导致的聚合物表层微观结构改变

应用大规模分子动力学方法, 模拟了锥形探头在非晶态聚合物薄膜表面的滑动摩擦过程, 研究了摩擦导致的聚合物薄膜表层微观结构改变, 以及探头与基体间黏着作用、滑动速度和分子链长度对基体表层微观结构改变的影响. 当探头与基体之间为黏着作用时, 摩擦导致基体表面滑痕区域的键取向沿滑动方向重新取向, 导致表层分子链回转半径沿滑动方向伸长, 并且这些表层微观结构的改变程度随滑动速度的减小而增大. 在摩擦导致结构改变的过程中, 链端单体和链中单体的贡献作用不同, 形成了不同的分子链拉伸变形机制. 当样本缠结度较大或探头滑动速度较小时, 相比于链中单体, 探头对链端单体的拖曳作用使更多分子链发生拉伸变形. 研究还发现, 在探头与聚合物薄膜系统中, 使薄膜表层微观结构发生改变是摩擦能量耗散的重要途径.     

绝缘液体中空间电荷的扩散和介电谱

用微分时域谱方法，研究了苯和正烷烃中空间电荷的存在和运动规律．理论分析表明，高绝缘体中空间电荷位移的等效扩散运动导致慢极化效应；其响应时间与电极距离的平方成比例，实验证实了理论结果．在苯和正烷烃中都观察到一个快极化和两个慢极化分量．其强度和响应时间随温度的变化给出分子运动与链长关系的信息．微分时域介电谱方法对高绝缘液体中的极微量杂质十分灵敏 关键词：     

纤维悬浮聚合物熔体描述的均一结构多尺度模型

通过对纤维悬浮聚合物熔体的可逆和不可逆热力学过程的耦合,建立了分子链弹性哑铃模型与悬浮纤维取向描述相耦合的、具有均一 (GENERIC) 结构形式的熔体多尺度模型. 由该均一结构的多尺度模型不仅可以得出熔体不同尺度上的应力贡献,还可为一般多尺度模型方程组的建立提供其结构形式均一化的方法. 关键词： GENERIC结构 纤维取向 黏弹性 聚合物     

基于电荷转移过程的PAN-C60共聚物薄膜的时间分辨荧光研究

利用吸收光谱和皮秒时间分辨荧光研究PAN－C60星状共聚物的电荷转移过程。PAN－C60共聚物的吸收和荧光光谱结果显示共聚物中存在着电荷转移过程。时间分辨荧光结果表明PAN的荧光衰减遵循双指数衰减规律（一快过程160ps和一慢过程1500ps)，快衰减过程主要来源于聚合物中主链间相互作用产生的空间间接极化子对的影响，慢变过程主要来源于单重态激子的辐射跃迁弛豫。在共聚物中，C60分子的存在除导致PAN激发态寿命缩短外，还影响聚合物链间的相互作用，C60分子对PAN荧光猝 灭作用主要通过慢变过程影响的，而对PAN的空间极化子对的影响主要与其快衰减过程有关。     

模耦合理论计算纳米粒子在聚合物熔体中的含时扩散系数与常规扩散常数 (cited: 2)

分析和计算了纳米粒子在聚合物熔体中的含时扩散系数与常规扩散常数. 采用广义朗之万方程描述扩散动力学,并通过模耦合理论计算摩擦记忆内核.为简单起见,只考虑了来自两体碰撞和溶剂密度涨落耦合作用两类微观因素对摩擦记忆内核的贡献. 采用聚合物参考作用点模型以及Percus-Yevick闭合条件计算了聚合物-纳米粒子复合溶液的平衡态结构信息函数;详尽分析了纳米粒子的尺寸与聚合物链的尺寸对扩散动力学的影响. 揭示了结构函数、摩擦记忆内核以及扩散系数等随着纳米粒子半径和聚合物链长的变化关系. 结果表明,对于小尺寸的纳米粒子或者短链的聚合物,短时间的非马尔可夫扩散 动力学特征比较显著,含时扩散系数需要更长的时间弛豫到常规扩散常数. 微观因素对扩散常数的贡献随着纳米粒子尺寸的增加而减小,却随着聚合物链长的增加而增大. 此外,模耦合理论得到的扩散常数与Stokes-Einstein关系的预测值进行比较,发现对于小尺寸的纳米粒子或者长链的聚合物,微观因素对扩散常数的的贡献占主导地位. 相反,当纳米粒子较大或者聚合物链长较短时,流体力学的贡献会发挥重要作用.     

快速可调谐电光聚合物波导光栅

提出并设计了快速可调谐电光聚合物波导光栅.该波导光栅通过极化聚合物的线性电光效应 可实现谐振波长的纳秒级快速调谐，调谐灵敏度为61pm/V.研究了该波导光栅的反射谱和透 射谱特性与光栅周期,周期数,折射率调制函数及其调制大小的关系.讨论了波导光栅的材料 选择,制备工艺,快速可调谐性和偏振相关性.该波导光栅不仅克服了光纤光栅调谐速度慢和不利于大规模集成的不足，而且具有调谐灵敏度高,制备工艺与半导体工艺兼容和偏振无关 等优点. 关键词： 光通信器件 光波导 电光效应 聚合物 波导光栅 光纤光栅     

Enhanced pulse compression induced by the interaction between the third—order dispersion and the cross—phase modulation in birefringent fibres

In this paper,we report on the enhanced pulse compression due to the interaction between the positive third-order dispersion (TOD) and the nonlinear effect (cross-phase modulation effect) in birefringent fibres.Polarization soliton compression along the slow axis can be enhanced in a birefringent fibre with positive third-order dispersion,while the polarization soliton compression along the fast axis can be enhanced in the fibre with negative third-order dispersion.Moreover,there is an optimal third-order dispersion parameter for obtaining the optimal pulse compression.Redshifted initial chirp is helpful to the pulse compression,while blueshifted chirp is detrimental to the pulse compression.There is also an optimal chirp parameter to reach maximum pulse compression.The optimal pulse compression for TOD parameters under different N-order solitons is also found.     

Ultra-fast all-optical switching in MEH-PPV photonic crystals with resonantly enhanced nonlinearity

Photonic crystal all-optical switching is realized in two-dimensional nonlinear photonic crystals made of poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene]. Organic polymer films are fabricated by a slow evaporation method. Under resonant excitation, the organic matrix provides very large third-order nonlinear optical susceptibility. An operating pump energy as low as 514 pJ/cm² and a high switching efficiency of 70% are achieved for the photonic crystal optical switching. A switching time of 45.6 ps is maintained due to fast Forster transfer of excitons.     

Microrheology and dynamics of an associative polymer

We study the microscopic viscoelastic properties and relaxation dynamics of solutions of a side-chain associative polymer, hydrophobically modified hydroxyethyl cellulose (hmHEC). Dynamic light scattering from small tracer particles suspended in the polymer solutions is used to determine their viscous and elastic moduli on the scale of the particles. Bulk-scale viscoelastic properties are measured by shear rheometry. The motion of the tracer particles in hmHEC is diffusive at short times and subdiffusive at intermediate and long times. The long-time subdiffusive motion was not observed in parallel experiments on unmodified HEC solutions, and is explained in terms of hindered reptation of the hydrophobically modified polymer chains in the associative network. Dynamic light scattering from the polymer molecules themselves shows that chain relaxation in hmHEC is dominated by slow concentration-dependent processes due to the large-scale associative network structure, while that in HEC is dominated by fast concentration-independent Rouse-like dynamics.     

On Yaglom’s Law for the Interplanetary Proton Density and Temperature Fluctuations in Solar Wind Turbulence

In the past decades, there has been an increasing literature on the presence of an inertial energy cascade in interplanetary space plasma, being interpreted as the signature of Magnetohydrodynamic turbulence (MHD) for both fields and passive scalars. Here, we investigate the passive scalar nature of the solar wind proton density and temperature by looking for scaling features in the mixed-scalar third-order structure functions using measurements on-board the Ulysses spacecraft during two different periods, i.e., an equatorial slow solar wind and a high-latitude fast solar wind, respectively. We find a linear scaling of the mixed third-order structure function as predicted by Yaglom’s law for passive scalars in the case of slow solar wind, while the results for fast solar wind suggest that the mixed fourth-order structure function displays a linear scaling. A simple empirical explanation of the observed difference is proposed and discussed.     

Arrested swelling of highly entangled polymer globules

Upon aging, a collapsed long chain evolves from a crumpled state to a self-entangled globule which can be thought of as a large knot. Swelling of an equilibrium globule in good solvent is a two-step process: (i) fast swelling into an arrested stretched structure with conserved entanglement topology followed by (ii) slow disentanglement. Using computer simulation, we found both mass-mass (m-m) and entanglement-entanglement (e-e) power law correlations inside the swollen globule. The m-m correlations are characterized by a set of two exponents in agreement with a Flory-type argument. The e-e correlations are also characterized by two exponents, both of them larger (by approximately 0.3) than the related m-m exponents. We interpret this difference as evidence of distance-dependent repulsion E=-0.3ln((rho)k(B)T between entanglements sliding along the polymer chain.     

Carrier-envelope phase measurement by all-optical poling with a polar side-chain polymer

Dependence of all-optical poling efficiency on carrier-envelope phase (CEP) could be measured using photoisomerization of dye molecules which are covalently bound to a polymer main chain and have large difference in static dipole moment between the ground state and excited state. Increased chromophore density leads to an order of magnitude reduction in signal-detection time from a dye doped polymer. Analysis of all-optical poling experiments with CEP changes clearly showed the presence of polarization restoring force to zero polarization. This enables resetting of SH activity in the all-optical poling process to be used for fast response loop of CEP stabilization. Phenomenological model could explain well the difference in the growth-and-decay dynamics of poling between sample of dye doped in polymer studied previously and that grafted to a polymer main chain used in the present paper.     

Exciton emissions of CdS nanowire array fabricated on Cd foil by the solvothermal method

Nanowires have recently attracted more attention because of their low-dimensional structure, tunable optical and electrical properties for next-generation nanoscale optoelectronic devices. Cd S nanowire array, which is(002)-orientation growth and approximately perpendicular to Cd foil substrate, has been fabricated by the solvothermal method. In the temperature-dependent photoluminescence, from short wavelength to long wavelength, four peaks can be ascribed to the emissions from the bandgap, the transition from the holes being bound to the donors or the electrons being bound to the acceptors, the transition from Cd interstitials to Cd vacancies, and the transition from S vacancies to the valence band,respectively. In the photoluminescence of 10 K, the emission originated from the bandgap appears in the form of multiple peaks. Two stronger peaks and five weaker peaks can be observed. The energy differences of the adjacent peaks are close to 38 me V, which is ascribed to the LO phonon energy of Cd S. For the multiple peaks of bandgap emission, from low energy to high energy, the first, second, and third peaks are contributed to the third-order, second-order, and first-order phonon replica of the free exciton A, respectively;the fourth peak is originated from the free exciton A;the fifth peak is contributed to the first-order phonon replica of the excitons bound to neutral donors;the sixth and seventh peaks are originated from the excitons bound to neutral donors and the light polarization parallel to the c axis of hexagonal Cd S, respectively.     

半刚性高分子链螺旋结构诱导纳米棒的有序结构

在自然界中, 螺旋结构广泛存在. 在熵的驱动下, 高分子链能在某些特殊情形下形成螺旋结构. 采用分子动力学方法研究了高分子链诱导纳米棒的自组装行为, 发现纳米棒/高分子链体系的构象与纳米棒的数量、高分子链的刚性等密切相关. 当纳米棒与高分子链之间存在适度吸附能时, 纳米棒能够形成三种完全不同的构象, 特别是在半刚性高分子链诱导下纳米棒能够形成线型排列. 研究结果对新型材料制备具有一定指导意义.