共查询到18条相似文献,搜索用时 250 毫秒
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X射线衍射实验表明YBa2(Cu0.95M0.05)3O7-δ(M=Ti,V,Cr,Mn,Fe,Co,Ni,Cu和Zn)均为单相结构。Fe,Co,Ni和Zn对Cu的替代使超导临界温度Tc显著下降,而同样含量的Ti,V,Cr,Mn对Cu的替代并未对超导性能产生显著影响。并利用中子衍射分析了Ti,Mn,Fe和Co对Cu原子的取代,发现代换原子对Cu的两个晶位各自存在不同的择优占据
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通过X射线衍射分析和磁测量研究了Gd-Fe-Co-Cr四元系中对应于化学式Gd3(Fe,Co,Cr)29且Gd含量为一定值的截面内富Fe,Co区的相关系,重点探索了高Co含量3∶29型化合物合成的可能性,研究了3∶29型Gd3(Fe1-xCox)29-yCry化合物的结构与磁性.研究结果表明,获得3∶29型单相Gd3(Fe1-xCox)29-yCry化合物的范围为:y=5,0≤x≤0.7;y=5.5,0.7≤x≤0.8和y=6,0.8≤x≤0.9.基于对Gd3(Fe1-xCox)29-yCry化合物成相条件的研究,成功地合成了纯Co基Gd3Co29-yCry化合物,其固溶范围为6.5≤y≤7.3.3∶29型单相Gd3(Fe1-xCox)29-yCry化合物的晶体结构都属于单斜晶系,Nd3(Fe,Ti)29型结构,空间群为A2m.得到3∶29型单相Gd3(Fe1-xCox)29-yCry化合物的固溶极限即Co含量的极大值与稳定元素Cr含量有关.Co原子的含量越高,所需稳定元素Cr的含量越大.值得注意的是,用Co原子替代Fe原子会导致Gd3(Fe1-xCox)29-yCry化合物磁晶各向异性的显著改变.当x≥0.4时,化合物的磁晶各向异性从易面型转变为易轴型
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3(Fe1-xCox)29-yCry化合物')" href="#">Gd3(Fe1-xCox)29-yCry化合物
相关系和相结构
X射线衍射
磁晶各向异性 相似文献
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本文研究了Bi-Sr-Ca-Cu-O体系中理想成份为Bi2Sr2CaCu2O8化合物的超导性能和晶体结构。名义成份为BiSrCaCu2O5.5零电阻超导转变温度Tc(0)=81.5K。用X射线粉末衍射方法测定了Bi2Sr2CaCu2O8的晶体结构,其基本结构属体心四方晶系,空间群为D4h17-l4/mmm,点阵常数a=3.825?,c=30.82?。每单胞化合式单位为2.2Ca占据2(a)等效点系,4Sr,4Bi和4Cu占据三组4(e)位置,其原子参数z分别为0.110,0.302和0.445,16O分别占据8(g),z=0.445和二组4(e),z=0.210和0.380。Bi2Sr2CaCu2O8晶体结构可认为是阳离子沿z轴的(00z)和((1/2)(1/2)z)交错排列,由Aurivillius相导生出来的。讨论了在Bi-Sr-Ca-Cu-O体系中可能存在的其它沿z轴不同堆垛层数的超导相。
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通过测量YBa2Cu3-xMxO7-y(M=Zn,Ni,x=0,0.025,0.05,0.075,0.1,0.15,0.2,0.3)系列样品的晶体结构、正常态电子输运性质、超导电性以及O含量,给出了Zn择优取代Cu(2)的更直接证据;同时,观察到掺Zn系统中的由正交相Ⅰ到正交相Ⅱ的结构相变以及Ni取代Cu带来的电子局域化效应。研究结果表明,具有正二价态的Zn对Cu(2)具有择优取代性,而具有正二价和正三价的Ni并不具有明显的择优取代。对Cu(2)的取代引起超导临界温度的显著变化,但对正常态电子输运性质的影响不明显;对Cu(1)的取代更显著地影响了晶体结构和正常态电子输运性质,同时对Tc产生抑制,我们认为,YBa2Cu307中的高温超导电性以及正常态输运性质是由CU-O平面和Cu-0链共同承担,而Cu-O平面和Cu-0链之间的耦合强度决定着该系统的超导电性的强弱。
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本文研究Co对Cu(I)和Ca对Y作取代时,YBa2Cu3Oy系统中的空穴浓度、晶体结构和超导临界温度随掺杂量的变化关系及其起源。结果表明,上述取代对体系中的Cu-O平面上的空穴浓度Psh都有重要影响,但其作用和方式是不同的。前一种取代主要是通过对空穴的复合和增强对空穴的局域化而使Psh下降:后者则具有明显的退局域化作用,从而使得Psh上升。当两种取代同时进行时,局域化作用不
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研究了掺Ba对Bi2Sr2-xBaxCaCu2Oy(0≤x≤0.15,0.3)单晶和多晶样品超导电性的影响,结果表明,有少量Ba2+离子进入了超导相,且有固溶度极限.对于2212相单晶,c轴参数和Tc均随Ba含量增加而增加;对于慢冷多晶样品,掺Ba可明显提高Tc;然而对于淬大多晶样品,Tc没有明显变化,用掺Ba
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The effect of Co, Ni and Zn substitutions for Cu on the phase stability and superconducting properties of (Hg0.7Cr0.3)Sr2CuO4+δ was investigated. X-ray diffraction (XRD) revealed that both Co and Zn are soluble in the (Hg0.7Cr0.3)Sr2CuO4+δ material up to about 5% of the Cu content, whereas the solubility of Ni is extended up to 10%. Electrical resistivity and magnetic susceptibility measurements show that the value of the superconducting critical temperature Tc decreases linearly with the impurity content. The depression of Tc indicates that the suppression of the superconductivity in Co- and Ni-substituted samples is much stronger than that in Zn-substituted ones. The residual resistivity scales linearly with the doping level as expected from the impurity scattering due to disorder. Some possible explanations for the stronger suppression of Tc by the Co and Ni substitution than by Zn substitution are provided. 相似文献
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Bond covalency and valence of elements in HgBa2Can−1CunO2n+2+δ (n=1, 2, 3, 4) were calculated and their relationship with Tc was discussed. For both oxygen and argon annealed samples, the results indicated that with the increase of n, the trend of bond covalency of Hg-O and Cu-O was the same or opposite compared with that of superconducting temperature. This may suggest that the magnitudes of Cu-O and Hg-O bond covalency are important in governing the superconducting temperature. For the highest Tc sample, Hg had the lowest valence, implying that lower valence of Hg was preferred in order to produce higher Tc. For fixed n, the valence of Cu in oxygen annealed samples was larger than that in argon annealed samples, indicating that oxygen annealed samples produced more carriers than argon annealed samples. 相似文献
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(Tl0.5Pb0.5)Sr2Ca(Cu2−xMx)O7 (M=Co, Ni and Zn) have been synthesized and investigated by means of X-ray diffraction, scanning electron microscope, electrical resistivity and magnetic susceptibility measurements. X-ray diffraction patterns show that all studied samples contain the nearly single ‘1212’ phase. They crystallize in a tetragonal unit cell with a=3.8028-3.8040 Å and c=12.0748-12.1558 Å. In (Tl0.5Pb0.5)Sr2Ca(Cu2−xMx)O7 system (M=Co or Ni), the superconducting critical temperature Tc decreases linearly with both Co and Ni concentrations and the rate of Tc decrease is around −6.5 and −7.0 K/at%, respectively. For (Tl0.5Pb0.5)Sr2Ca (Cu2−xZnx)O7 system, the dependence of Tc on the Zn dopant concentration deviates from a linear behavior and the Zn substitution suppresses Tc much less (−2.5 K/at%) than the Co and Ni substitutions. The suppression in Tc in Co and Ni doped samples are attributed to the magnetic pair-breaking mechanism and the reduction in the carrier concentration. The suppression of Tc in Zn doped samples is not caused by the reduction in carrier concentration which should remain constant, but rather due to nonmagnetic pair-breaking mechanism induced by disorder as well as the filling of the local Cu dx2−y2 state due to the full d band of Zn ions. 相似文献