SrMn0.5Fe0.5O3的自旋玻璃态和过渡金属离子价态的研究

采用固相反应法制备了SrMn_0.5Fe_0.5O₃陶瓷样品,并对样品的晶体结构,磁性和离子价态进行了系统的表征与分析. X射线衍射谱的Rietveld拟合表明样品属于理想的立方钙钛矿型结构,Mn离子和Fe离子随机占据B位的O八面体中心. X射线光电子能谱表明Mn离子为+3和+4的混合原子价态,Fe离子为+3价. 样品在大于230K的高温区域呈现Curie顺磁特性,在小于230 K的低温区域样品表现出自旋玻璃态行为,这种特性源于Mn离子和Fe离子之间的交换作用及自身价态和分布的不均匀性. 由于Fe³⁺离子占据O八面体的中心,对顺磁区的Mssbauer谱测量表现为四级分裂. 关键词： 晶体结构 价态 顺磁 自旋玻璃态     

SrMn0.5Fe0.5O3的自旋玻璃态和过渡金属离子价态的研究

采用固相反应法制备了SrMn_0.5Fe_0.5O₃陶瓷样品,并对样品的晶体结构,磁性和离子价态进行了系统的表征与分析. X射线衍射谱的Rietveld拟合表明样品属于理想的立方钙钛矿型结构,Mn离子和Fe离子随机占据B位的O八面体中心. X射线光电子能谱表明Mn离子为+3和+4的混合原子价态,Fe离子为+3价. 样品在大于230K的高温区域呈现Curie顺磁特性,在小于230 K的低温区域样品表现出自旋玻璃态行为,这种特性源于Mn离子和Fe离子之间的交换作用及自身价态和分布的不均匀性. 由于Fe³⁺离子占据O八面体的中心,对顺磁区的Mssbauer谱测量表现为四级分裂.     

Nd0.5Pb0.5-xSrx (Mn, Fe)O3的局域结构畸变和磁输运性质的研究

通过X光衍射，穆斯堡尔谱和输运性质的测量研究了掺杂Fe的Nd0.5Pb0.5-xSrxMnO3样品的结构和磁输运性质。x光衍射和穆斯堡尔谱都表明了样品随Sr的增多结构畸变减小。Sr的掺杂同时也降低了室温时的电阻率并使磁电阻增大。由于在样品中Mn3+ 与 Mn4+的比率是一样的，也就意味着具有相同的双交换作用。所以Sr对样品性质的改变可以认为是由于晶格畸变所产生的。由于Jahn-Teller 效应而产生的Mn(Fe)O6八面体的局域结构畸变可以局域电子。由我们的实验可以看到在居里温度Tc以上，除了双交换作用之外，Jahn-Teller 效应对于输运性质也起了重要作用。     

单相Na0.5Bi0.5Ti1-xMnxO3陶瓷中的多铁性

溶胶凝胶法制备了Na0.5Bi0.5Ti1-xMnxO3(x=0,0.02,0.04)陶瓷样品,X射线衍射(XRD)分析表明陶瓷样品均形成了单一的钙钛矿(ABO3)型结构且没有杂质相的形成.随着Mn含量的增加,XRD峰向高角度方向移动,表明Mn离子进入Na0.5Bi0.5TiO3晶格.掺杂样品均表现出室温铁磁性和铁电性.磁测量表明样品中存在复杂的磁相互作用,包括铁磁,反铁磁和顺磁相互作用.以上结果表明,通过Mn的掺杂可以使铁电材料Na0.5Bi0.5TiO3转变为多铁材料.     

La0.5Ca0.5-xBaxMnO3体系中的异常磁电阻行为

实验研究了La0.5Ca0.5MnO3系统Ca位上Ba掺杂对其磁电阻效应的影响.结果表明,掺杂量低于0.2的样品,磁电阻效应随温度降低而增大,在转变温度附近达到最大值,然后随温度降低而变小,随着温度进一步降低磁电阻效应再次增大.而对于掺杂量高于0.2的样品,磁电阻效应在整个温区随温度降低而单调增加.文中通过考虑铁磁性和反铁磁性两种效应的竞争而对实验观察给出解释.     

Nd0.5Ca0.5Mn1-xAlxO3 (x=0,0.03)体系中电荷有序态的超声研究

系统研究了Nd0．5Ca0．5Mn1-xAlxO3(x=0,0．03)单相多晶样品在低温下的电磁性质和超声特性．电阻和磁化率测量表明,Nd0．5Ca0.5O3体系在TCO-257 K处发生了电荷有序相变．超声声速从室温开始随着温度的降低逐渐减小,并在TCO附近达到最小,之后,随着温度的进一步降低,声速急刷增加,同时伴随着一个尖锐的超声衰减峰出现.TCO附近的超声异常表明体系中存在着强烈的电-声子相互作用,该电-声子耦合来源于Mn3 的Jahn-Teller效应．在低温下,出现了另一个超声衰减峰,它的出现归结为反铁磁相与顺磁相之间的相分离现象.随着Al在Mn位的掺入,超声声速的最低点和衰减峰向低温移动,表明体系中的电荷有序态和反铁磁相均被部分抑制,     

Mo低掺杂La_(0.67)Sr_(0.33)MnO_3的磁电特性及室温磁电阻增强(英文)

采用固相反应法成功制备了Mo低掺杂La0.67Sr0.33Mn1-xMoxOc(x=0,0.02)单相多晶样品,系统研究了样品的磁性、电输运特性和磁电阻效应.发现Mo低掺杂对La0.67Sr0.33MnO3 的居里温度影响很小,但在La0.67Sr0.33MnO3铁磁基态背景下诱导出团簇自旋玻璃态行为.在低温区(0.1相似文献   

LiNi_(0.5)Mn_(0.5)O_2制备及表征

采用共沉淀法制备了LiNi0.5Mn0.5O2.XRD,Raman测试都表明材料是六方结构.XPS检测得出镍主要以正二价存在,锰元素主要以正四价存在.合成的LiNi0.5Mn0.5O2得到了50次的循环,但比容量较低.充放电循环性能比较研究表明,经过40次循环后,0.3,0.6,1.5 C的放电比容量分别是65.88,61.56,52.23 mA.h.g-1.     

Cr掺杂对Bi0.5Ca0.5MnO3磁性和电输运性质的影响

通过对M～T曲线、M～H曲线和P～T曲线的测量,研究了Bi0.5Ca0.5Mn1-xCrxO3(O≤x≤0.12)系列样品的磁性和电输运特性.结果表明,随Cr掺杂量的增加,反铁磁转变和电荷有序转变分别在x～0.03和x～0.12相继消失.低温下始终出现自旋玻璃或团簇玻璃行为,说明存在反铁磁与铁磁的相互竞争.对电阻率数据的拟合表明,所有组分载流子的电输运可用可变程跃迁描述.我们用相分离的图象解释了相关现象.     

Co掺杂对La5/8Ca3/8MnO3体系铁磁有序的影响与电子的局域化效应

系统研究了强关联锰氧化物La5/8Ca3/8Mn1-xCoxO3(x=0,0.05)体系的结构和输运特性.结果表明,样品均为很好的正交O′单相结构,Mn位5%Co掺杂明显影响了样品铁磁-顺磁(FM-PM)转变和金属-绝缘体(M-I)转变,M-I转变温度TM-I从未掺杂时的271K降至227K,对应的峰值电阻率ρp增大;随着TM-I的降低,Tc同时降低,磁电阻MR%亦相应增加;La5/8Ca3/8MnO3样品在Tc以下表现出长程铁磁有序态,Mn位5%Co掺杂样品则表现为团簇玻璃型短程铁磁有序行为.证明Co掺杂引起电子的局域化效应乃是导致体系输运行为发生变化的主要原因.同时,从Mn3 -O2--Mn4 双交换(DE)作用和超交换(SE)相互作用机制等出发,对样品的输运行为、CMR效应以及与Co掺杂之间的关联进行了讨论.     

A comparative study of magnetic and dielectric behaviors for La(1-x)Bi(x)Mn(1-y)Fe(y)O3 series (with x = 0.5, 0.7 and y = 0.3, 0.7)

We have carried out an extensive investigation into the effect of doping on both the A- and B-sites for the multiferroic La(0.5)Bi(0.5)Mn(0.5)Fe(0.5)O(3) in relation to its physical properties. The temperature dependent magnetization and dielectric response are determined for different percentages of Bi- and Fe-substitutions. For La(0.5)Bi(0.5)Mn(0.7)Fe(0.3)O(3), there is a prominent ferromagnetic transition T(C) around 110 K, whereas the other La(0.5)Bi(0.5)Mn(0.3)Fe(0.7)O(3) and La(0.3)Bi(0.7)Mn(0.3)Fe(0.7)O(3) phases fail to exhibit any clear transition. On the other hand, for the Fe-rich phases, the coercive field increases to 2450 Oe compared to 1720 Oe (for the Mn-rich phase). All the compositions exhibit coexistence of ferromagnetic and antiferromagnetic phases at low temperatures. The temperature dependent dielectric constant of the investigated samples varies from 32,000 to 500 at room temperature and the data has been analyzed using the universal dielectric response model.     

57Fe Mössbauer Spectroscopy Study of LaFe1−x Co x O3 (x=0 and 0.5) Formed by Mechanical Milling

Hyperfine Interactions - Perovskite-related phases of the type LaFe1?x Co x O3 (x=0 and 0.5) have been synthesised by milling techniques. The materials are of smaller particle size and more...     

Temperature-dependent magnetization in (Mn, N)-codoped ZnO-based diluted magnetic semiconductors

The influences of Mn doping on the structural quality of the Zn_xMn_1−xO:N alloy films have been investigated by XRD. Chemical compositions of the samples (Zn and Mn content) and their valence states were determined by X-ray photoelectron spectrometry (XPS). Hall effect measurements versus temperature for Zn_xMn_1−xO:N samples have been designed and studied in detail. The ferromagnetic transitions happened at different T_C should explain that the magnetic transition in field-cooled magnetization of Zn_1−xMn_xO:N films at low temperature is caused by the strong p-d exchange interactions besides magnetic transition at 46 K resulting from Mn oxide, and that the room temperature ferromagnetic signatures are attributed to the uncompensated spins at the surface of anti-ferromagnetic nano-crystal of Mn-related Zn(Mn)O.     

Nanostructured multiferroic PbFe<Subscript>0.5</Subscript>Nb<Subscript>0.5</Subscript>O<Subscript>3</Subscript> and its physical properties

Polycrystalline multiferroic PbFe_0.5Nb_0.5O3 (PFN) fabricated by a solid-phase method is studied. Before sintering, a synthesized PFN powder is processed in Bridgman anvils via a force action in combination with shear deformation (FASD) at room temperature. The electrophysical properties and structural parameters of processed samples and a reference sample are compared. Point defects are shown to play a key role in the formation of the physical properties beginning from an FASD of 200 MPa.     

Structural properties of Pb2MnW(1-x)Re(x)O6 double perovskites

Pb2MnW(1-x)Re(x)O6 samples have been synthesized and their structure determined by powder x-ray diffraction. These samples undergo a first order structural phase transition between 413 and 445 K depending on the composition. Above this temperature, the samples are cubic. Below the transition temperature, solid solutions are found for x ≤ 0.2 and x ≥ 0.5. The W-rich samples adopt an orthorhombic cell whereas the Re-rich compounds are monoclinic. In the intermediate region, 0.2 < x < 0.5, both phases coexist. X-ray absorption spectra did not reveal significant changes in the local structure for Pb, Mn or Re atoms across the structural phase transition. All the atoms exhibit distorted environments in the whole series. In the case of Pb and W(Re) atoms, the local distortion remains in the high temperature phase. Samples with x ≤ 0.2 also show a sharp discontinuity in the dielectric permittivity at the phase transition temperature indicating the presence of a concomitant electrical ordering in the bulk grains. Such an anomaly in the dielectric constant is not observed for the x ≥ 0.5 samples, compatible with the lack of dipole ordering for this composition range. The different electrical behaviours also explain the differences in the entropy content for the two types of transition.     

基于La_(1.4)Ca_(1.6)Mn_2O_7结构、电输运及磁性研究(英文)

我们制备了名义成分是La1.4 Ca1.6 Mn2 O7的多晶样品,并且研究了它的结构、磁性和电性.利用Rietveld方法对X射线衍射数据进行精修的结果表明,该La1.4 Ca1.6 Mn2 O7是由钙钛矿锰氧化物La0.66 Ca0.34 MnO3和氧化钙CaO组成的复相混合物.其中,La0.66 Ca0.34 MnO3占相成分的大部分,而CaO占小部分.我们对比了该名义组分样品La1.4 Ca1.6 Mn2 O7和La0.7 Ca0.3 MnO3的铁磁居里转变温度和绝缘体-金属转变温度,结果表明该La1.4 Ca1.6 Mn2 O7的磁输运性质是由其中的钙钛矿相成分决定的.所有的这些结果表明,名义组分样品La1.4 Ca1.6 Mn2 O7实际上并没有形成所谓的Sr3Ti2O7型的双层结构,而实际形成的是以钙钛矿结构作为主相的复相混合物.