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本文基于OH自由基所固有的分子结构特征,通过分子光谱理论系统地分析和计算了OH自由基A2∑+→X2∏r电子带系发射光谱的谱线跃迁频率、能级分布以及爱因斯坦自发发射跃迁概率等重要参数.同时结合实际的光谱实验,分析了谱线的自然展宽、碰撞展宽、多普勒展宽以及仪器展宽等各种展宽因索对谱线线型的影响,从理论上计算了任意转动温度、振动温度以及谱线展宽条件下OH自由基A2∑+→X2∏r电子带系发射光谱的强度分布,并分析了光谱强度分布与转动温度、振动温度以及谱线展宽的关系,为OH自由基A2∑+→X2∏r电子带系发射光谱测温技术提供理论依据.在实验过程中通过理论计算光谱与实验光谱进行拟合,对氢气燃烧火焰的转动温度和振动温度进行了初步的实验研究. 相似文献
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基于NO分子的双重态能级结构特性,利用分子光谱理论分析和计算了NO分子γ带系(A2Σ+→X2Πr)的发射光谱,并通过电晕放电实验光谱进行验证。理论上计算了NO高低能级的双重电子态的能级分布,同时利用r质心近似法求取了能级间跃迁的电偶极矩函数,并得到了不同振动、转动能级间的爱因斯坦跃迁概率,然后计算出不同振动温度和转动温度条件下谱线的强度分布。最后进行NO和N2混合气体的电晕放电实验,通过将实验发射光谱同理论计算结果进行对比分析,确定了NO分子的振动温度和转动温度。 相似文献
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本文基于OH自由基所固有的分子结构特征,通过分子光谱理论系统地分析和计算了OH自由基A2Σ + →X2Πr 电子带系发射光谱的谱线跃迁频率、能级分布以及爱因斯坦自发发射跃迁概率等重要参数.同时结合实际的光谱实验,分析了谱线的自然展宽、碰撞展宽、多普勒展宽以及仪器展宽等各种展宽因素对谱线线型的影响,从理论上计算了任意转动温度、振动温度以及谱线展宽条件下OH自由基A2Σ 关键词:
发射光谱
转动温度
振动温度
自发发射爱因斯坦跃迁概率 相似文献
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MgXI等离子体软X射线自发辐射放大增益的数值模拟 总被引:2,自引:2,他引:0
本文采用碰撞辐射模型,考虑MgX,MgXII,MgXIII的基态及MgXI主量子数n≤6到光谱项层次的21个能级,假定等离子体电子温度按高斯函数随时间下降,用初始温度下定态能级占据数速率方程的解作初值,求解瞬态能级占据数速率方程,根据各能级粒子数的时间分布分析了MgXI1s3p—1s4d,1s3d—1s4f跃迁的自发辐射放大增益系数的时间特性。 相似文献
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毛细管放电条件下类氖序列原子参量计算与分析 总被引:2,自引:0,他引:2
利用多组态求解相对论性的Hartree-Fock-Roothan方程(HFR)方法计算了类氖离子(Z=13~27)2s^22p^5—2s^22p^53s能级之间跃迁的原子参量,包括类氖氩激光系统的能级,振子强度,自发辐射衰变速率,能级寿命,电子碰撞激发截面及电子碰撞激发速率系数等。以类氖氩离子为例,分析了等离子体内46.9nm激光跃迁的粒子数反转的形成及谱线放大过程,讨论了其它几条谱线产生增益的可能性,分析了激光线振子强度随核电荷数的变化规律。根据获得的原子参量,计算了利用毛细管放电产生类氖氩和类氖氪x射线激光的放电参量,其中类氖氩毛细管放电的初始压强的范围为30~90Pa,放电电流峰值为10~50kA。理论计算结果为类氖氩x光激光实验分析,深入研究等离子体反转动力学,激光增益的估算及理论方案设计等提供了基本数据。 相似文献
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用二维光学多道分析仪考察了He-Ne激光器在632.8nm激光振动和不振荡时氖能级3s_2和2p_k(k=1,2,……8,10)的侧光辐射,进行了Abel反演后,得到了3s_2和2p_k各能级粒子数和3s_2和2p_k间粒子数反转的径向分布,研究了此分布勺放电电流、632.8nm激光辐射强度间的关系,推算了在放电管中心3s_2和2p_k能级间受激辐射的激光增益。 相似文献
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NO2分子519~524 nm区的激光诱导荧光激发谱 总被引:1,自引:1,他引:0
实验测定了室温下NO2分子在519~524nm区域的高分辨激光诱导荧光激发谱,标识了25个振动带,并作了转动分析,确定了这些带的带源、转动常数以及旋-转偶合常数等分子常数,其中有8个振动带是新发现的,对振动带的转动结构分析表明,所有得到转动标识的谱线均属于平行跃迁2B2-2A1,其中上振动能级具有B2对称类是由于电子激发态2B2与电子基态的振动能级之间的强烈相互作用所致。 相似文献
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Yudin VI Taichenachev AV Okhapkin MV Bagayev SN Tamm C Peik E Huntemann N Mehlstäubler TE Riehle F 《Physical review letters》2011,107(3):030801
We develop a concept of atomic clocks where the blackbody radiation shift and its fluctuations can be suppressed by 1-3 orders of magnitude independent of the environmental temperature. The suppression is based on the fact that in a system with two accessible clock transitions (with frequencies ν1 and ν2) which are exposed to the same thermal environment, there exists a "synthetic" frequency ν(syn) ∝ (ν1 - ε12ν2) largely immune to the blackbody radiation shift. For example, in the case of 171Yb+ it is possible to create a synthetic-frequency-based clock in which the fractional blackbody radiation shift can be suppressed to the level of 10(-18) in a broad interval near room temperature (300±15 K). We also propose a realization of our method with the use of an optical frequency comb generator stabilized to both frequencies ν1 and ν2, where the frequency ν(syn) is generated as one of the components of the comb spectrum. 相似文献
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通过分析非稳腔DF化学激光器光腔内激光路径特性,指出非稳腔DF化学激光器输出光斑上下游光谱振荡路径不同导致输出光谱存在一定差异。试验测量了一台连续波DF化学激光器光斑上下游光谱,结果表明:非稳腔DF化学激光器光斑上下游光谱主要谱线成分未见显著差异;光斑上下游谱线相对强度存在一定差异;光斑上游各谱带相对强度最大值谱线转动量子数趋向于各谱带低转动量子数方向。根据实测光谱,对光斑上下游光谱所表征光腔温度和相对粒子数范围进行了估算,得到光腔上游平均温度要低于光腔下游平均温度。 相似文献
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J.-M. Flaud F. Kwabia Tchana W. J. Lafferty A. Perrin L. Manceron M. Ndao 《Molecular physics》2018,116(23-24):3463-3467
ABSTRACTA Fourier transform spectrum of phosgene (Cl2CO) has been recorded in the 17.3-μm spectral region at a temperature of 180 K and at a resolution of 0.00102 cm?1 using a Bruker IFS125HR spectrometer coupled to synchrotron radiation, leading to the observation of the ν2 and ν4 vibrational bands of the two isotopologues 35Cl2CO and 35Cl37ClCO. The corresponding upper-state ro-vibrational levels were fit using a Hamiltonian model accounting for the A-type Coriolis interaction linking the rotational levels of the 21 and 41 vibrational states. In this way, it was possible to reproduce the upper-state ro-vibrational levels to within the experimental uncertainty, i.e. ~0.30 × 10?3 cm?1. Very accurate rotational and centrifugal distortion and interaction constants were derived from the fit, together with the following band centres: ν0(ν2, 35Cl2CO) = 572.526299(30) cm?1, ν0(ν4, 35Cl2CO) = 582.089026(30) cm?1, ν0(ν2, 35Cl37ClCO) = 568.951791(35) cm?1 and ν0(ν4, 35Cl37ClCO) = 581.758279(35) cm?1. 相似文献
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《Molecular physics》2012,110(17):2103-2109
We present a narrow-linewidth, singly-resonant cw optical parametric oscillator, emitting more than 1 W in the 2.7–4.2?µm range. The OPO is pumped by a narrow linewidth (40?kHz) fibre-laser system and the signal frequency is locked to a high-finesse Fabry–Pérot cavity in order to increase the spectral resolution, thus obtaining a residual linewidth of 70?kHz for the signal. We tested the spectral performance of our OPO on several transitions in the ν1 rovibrational band of CH3I, measuring line intensities and showing sub-Doppler dip detection. 相似文献
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报道了高压下非线性光学晶体KNbO3(KN),KIO3(KI)和KTiOAsO4(KTA)的Raman散射研究结果,压力引起的Raman光谱非常丰富,在所有的样品中都观察到了压致相变。另外,在KN晶体中发现了非常强的压致振动耦合现象及高压非晶相。对于KTA,建立了Raman光谱变化与其倍频效率随压力提高之间的可能联系。在22 GPa以上,KI晶体的基本组成集团可能由IO3变为IO6。 相似文献
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Dolev M Gross Y Sabo R Gurman I Heiblum M Umansky V Mahalu D 《Physical review letters》2011,107(3):036805
Fractionally charged quasiparticles, which obey non-abelian statistics, were predicted to exist in the ν=8/3, ν=5/2, and ν=7/3 fractional quantum Hall states (in the second Landau level). Here we present measurements of charge and neutral modes in these states. For both ν=7/3 and ν=8/3 states, we found a quasiparticle charge e=1/3 and an upstream neutral mode only in ν=8/3-excluding the possibility of non-abelian Read-Rezayi states and supporting Laughlin-like states. The absence of an upstream neutral mode in the ν=7/3 state also proves that edge reconstruction was not present in the ν=7/3 state, suggesting its absence also in ν=5/2 state, and thus may provide further support for the non-abelian anti-pfaffian nature of the ν=5/2 state. 相似文献
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在二硫化碳(CS2)和苯(C6H6)的二元溶液中,随着相对体积浓度而变化,C6H6的基频ν1(992 cm-1) 的拉曼散射系数随浓度减小而增加,而CS2的基频ν1(656 cm-1)的拉曼散射系数则随浓度增加而增加。文章测量了这二元溶液相对不同体积浓度的拉曼光谱。结果表明,尽管CS2和C6H6的基频ν1的强度都随着浓度变化而发生较大变化,但C6H6的基频ν1对其参与的ν1+ν6~ν8费米共振几乎没有影响,而CS2的基频ν1强度的变化不仅对ν1~2ν2费米共振产生较大影响,还使基频ν2发生变化。文章给出了实验结果,并用Bertran费米共振理论和群论给予了解释。 相似文献
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大口径红外辐射计的光谱定标 总被引:1,自引:0,他引:1
介绍了大口径红外辐射计的光谱定标方法。研制了大口径红外辐射计。该辐射计主要由前置光学系统, 红外探测器(热释电探测器和碲镉汞探测器2~14 μm), 机械斩波器,锁相放大器,信号采集器等组成。首先对大口径红外辐射计的光谱定标方法进行了分析,然后建立红外辐射计光谱定标的测量装置,并分别测试腔体热释电探测器和HgCdTe探测器的响应非线性,最后用腔体热释电探测器在该测量装置上对HgCdTe探测器进行红外光谱响应度校准实验。通过两种相对光谱响应度测量方法的对比,给出多次测量结果的平均值及两种方法的对比分析。分析结果表明,测量系统的不确定度优于3.4%。 相似文献
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In contrast to earlier reports, where the spectrum of the energy density of photonic black‐body radiation modified by SU(2) effects was discussed, we discuss the low‐frequency spectrum of the radiance at temperatures ranging between 5 and 20 Kelvin. We conclude that compared to the conventional theory the only observable effect is associated with the spectral gap (total screening) which for T≥ 4.3 K scales with temperature T as ν*(T)}/GHz = 42.70 (T/K)‐0.53 + 0.21. We also discuss how a low‐temperature black body cavity under the influence of a sufficiently strong static electric field is forced to emit according to Planck's radiation law (pure U(1) theory) even at low frequencies and how this effect can be utilized to measure SU(2) induced deviations. 相似文献