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Er3+单掺及Er3+/Yb3+共掺SiO2-Al2O3-La2O3玻璃光谱性质研究 总被引:10,自引:4,他引:6
研究了单掺Er3+及Er3+/Yb3+共掺SiO2-Al2O3-La2O3玻璃的光谱性质随稀土离子浓度变化规律,应用McCumber理论计算了玻璃在1.53 μm的发射截面及积分吸收截面.结果表明:在Er3+离子掺杂浓度相同时,玻璃在980 nm吸收截面与Yb3+掺杂浓度成反比;当样品中Yb3+离子掺杂浓度为3.94×1020 cm-3时,玻璃在1.53 μm的吸收截面和发射截面最大,在1.40~1.60 μm积分吸收截面也最大;Er3+/Yb3+共掺SiO2-Al2O3-La2O3玻璃在1.53 μm的荧光半高宽随Er3+掺杂浓度升高而增加,当Er3+离子掺杂浓度为2.41×1020 cm-3时,玻璃的荧光半高宽(FWHM)达到52.5 nm. 相似文献
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采用共沉淀法制备了纳米晶ZrO2-Al2O3∶Er3+发光粉体.所制备的粉体室温下具有Er3+离子特征荧光发射,主发射在绿光,其中位于547 nm、560 nm的绿光最强,并得出稀土离子与基质之间有能量传递.对不同煅烧温度下的样品研究表明:因不同温度下所制得的样品晶相不同.研究了纳米晶ZrO2-Al2O3∶Er3+及ZrO2-Al2O3∶Er3+/Yb3+的上转换发光,并分析了上转换的跃迁机制.发现ZrO2-Al2O3∶Er3+的绿光为双光子过程,而ZrO2-Al2O3∶Er3+、Yb3+的上转换光谱中,红光和绿光也为双光子过程,而极弱的蓝光为三光子过程.讨论了Er3+的浓度猝灭现象.最适宜掺杂浓度的原子分数为2%(Er3+/Zr4+). 相似文献
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Er3+/Ce3+共掺TeO2-Bi2O3-TiO2玻璃的热稳定性和光谱特性研究 总被引:1,自引:1,他引:0
用高温熔融法制备了Er3+/Ce3+共掺新型碲酸盐玻璃(TeO2-Bi2O3-TiO2).采用差热分析方法研究了玻璃的热稳定性,测试并分析了不同Ce3+离子掺杂浓度下Er3+离子的吸收光谱、上转换光谱和荧光光谱特性.研究结果表明,制备的碲酸盐玻璃具有很好的热稳定性,玻璃析晶温度Tx与玻璃转变温度Tg之差(ΔT=Tx-Tg)达到了185 ℃,高于其它文献的报道|同时,Ce3+离子共掺引入的能量转移(Ce3+∶2F5/2+Er3+∶4I11/2→Ce3+∶2F7/2+Er3+∶4I13/2)有效地抑制了Er3+离子上转换发光并显著增强了1.53 μm波段荧光强度,而发射截面随着Ce3+离子掺杂浓度相应增大.优异的热稳定性以及光谱性能揭示Er3+/Ce3+共掺碲酸盐玻璃是一种潜在的制备宽带掺铒光纤放大器的理想增益介质. 相似文献
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本文引入与浓度和厚度有关的kNL待定参数, 在J-O理论基础上, 对Er3+/Yb3+掺杂的LiNbO3和LiTaO3单晶衬底上 的多晶水热外延样品进行了基于吸收光谱的拟合计算. LiNbO3:Ω2=2.34× 10-20 cm2, Ω4=0.77× 10-20 cm2, Ω6=0.31×10-20 cm2, kNL=4.32× 10-2 mol·m-2. LiTaO3:Ω2=1.68×10-20 cm2, Ω4=0.84×10-20 cm2, Ω6=0.45×10-20 cm2, kNL=9.17×10-3 mol· m-2. 该方法可尝试推广到粉体或胶体等难以直接获得浓度和厚度数据的体系. 经上转换发光测试及光谱参数计分析认为Er3+/Yb3+离子的掺杂浓度比为1:1的情况下, 样品呈现绿色上转换发光光谱; 可尝试以降低基质声子能量的方法提高4I13/2能级 对2H11/2和4S3/2能级的量子剪裁效率. 相似文献
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采用高温熔融退火法制备了系列 80TeO2-10Bi2O3-10TiO2-0.5Er2O3-xCe2O3 (x=0,0.25, 0.5,0.75,1.0 mol%)和(80-y) TeO2-10Bi2O3-10TiO2-yWO3-0.5Er2O3-0.75Ce2O3 (y=3,6,9,12 mol%)的碲铋酸盐玻璃.测试了玻璃样品400-1700 nm范围内的吸收光谱, 975 nm抽运下的上转换发光谱和1.53 μm波段荧光谱, 以及808 nm激励下的Er3+离子荧光寿命和无掺杂玻璃样品的Raman光谱, 并结合Judd-Ofelt理论和McCumber理论计算了Er3+离子光谱参数.结果表明, 在掺Er3+碲铋酸盐玻璃中引入Ce3+离子进行Er3+/Ce3+共掺, 通过Er3+离子4I11/2能级与Ce3+离子2F5/2 能级间基于声子辅助的能量传递过程,可以有效抑制Er3+离子上转换发光并明显增强其 1.53 μm波段荧光;同时,在现有Er3+/Ce3+共掺玻璃组分基础上引入WO3, 可进一步提高1.53 μm波段荧光并展宽其荧光发射谱. 研究结果对于获取优异光谱特性的宽带掺Er3+光纤放大器玻璃基质具有实际意义. 相似文献
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在Fe:LiNbO3中掺进3mol%和6mol%MgO,生长了Mg:Fe:LiNbO3晶体.测试了Mg:Fe:LiNbO3晶体抗光致散射能力、衍射效率、响应时间和光电导.推导响应时间与光电导之间的关系.在Fe:LiNbO3晶体中掺进6mol%的Mg2+,它的抗光致散射能力比Fe:LiNbO3晶体提高一个数量级,响应速度比Fe:LiNbO3晶体提高四倍. 相似文献
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研究了以Co2+:MgAl2O4晶体为饱和吸收体的LD抽运Er3+,Yb3+共掺磷酸盐玻璃激光器.针对双掺离子之间的能量传递和Er3+的多种跃迁过程,结合Co2+:MgAl2O4晶体中Co2+离子的饱和吸收特性,给出了详尽的速率方程,在其基础上进行了数值分析,分析了输出镜透过率、激光介质长度、谐振腔长度、腔内往返损耗、饱和吸收体长度对激光阈值、峰值功率、单脉冲能量以及脉冲宽度的影响. 相似文献
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V. G. Babajanyan R. B. Kostanyan P. H. Muzhikyan 《Journal of Contemporary Physics (Armenian Academy of Sciences)》2012,47(1):17-22
The results of investigations of luminescent radiations’ kinetic characteristics for LiNbO3:Yb3+-Er3+, LiNbO3:Er3+, and LiNbO3:Yb3+ crystals under optical excitations at 532 nm and 1064 nm wavelengths are presented. The shapes and times of rise and damping
of luminescent signals at 550 nm, 980 nm and 1555 nm wavelengths under selective excitations in the impurity subsystem of
the investigated materials are determined. Comparison of the temporal characteristics of luminescent responses of LiNbO3 crystals doped separately with Yb3+ and Er3+ ions with those of the LiNbO3:Yb3+-Er3+ crystal allows identifying the contributions from different energy transfer processes of optical excitation taking place
in the impurity subsystem of the material. 相似文献
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The optical amplification of LiNbO3:Er3+/Yb3+ channel waveguides has been modelled in the small signal regime using the overlapping integrals method and the rate-equation formalism. It has been found that Yb3+ -sensitisation improves the pump efficiency at 980 nm and a higher gain is achievable in the high power-limit compared to singly-doped LiNbO3:Er3+ amplifiers. 相似文献
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Yannan Qian Rui Wang Lili Xing Yanling Xu Chunhui Yang 《Optics Communications》2012,285(13-14):2986-2989
The effect of Zn2+ ion on the dopant occupancy and optical characteristic of Er3+ ion in Er/Zn-codoped LiNbO3 crystal is reported. The intense 1.54 μm and relatively weak green upconversion emissions are observed for Er (1 mol%)/Zn (6 mol%):LiNbO3 crystal. The OH? absorption and the time-resolved spectra show that the Zn2+ codoping decreases the threshold concentration of Er3+ ion in Er/Zn-codoped LiNbO3 crystal. The experimental results here imply that the potential application of Er3+-doped LiNbO3 crystal can be designed and optimized on the basis of the theoretical investigations. 相似文献
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M. Villegas A. C. Caballero M. Quintanilla J. A. Sanz-García E. Cantelar F. Cussó 《Applied physics. B, Lasers and optics》2011,102(3):651-658
The preparation of LiNbO3:Er3+/Yb3+ nanocrystals and their up-conversion properties have been studied. It is demonstrated that polyethyleneimine- (PEI) assisted dispersion procedures allow obtaining stable aqueous LiNbO3:Er3+/Yb3+ powder suspensions, with average size particles well below the micron range (100–200 nm) and the isoelectric point of the suspension reaching values well above pH 7. After excitation of Yb3+ ions at a wavelength of 980 nm, the suspensions exhibit efficient, and stable, IR-to-visible (green and red) up-conversion properties, easily observed by the naked eye, very similar to those of the starting crystalline bulk material. 相似文献
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V.A. Fedorov Yu.N. Korkishko J.A. Sanz-García E. Cantelar R. Nevado G. Lifante F. Cussó 《Applied physics. B, Lasers and optics》2001,73(5-6):449-451
We report the dependence of the unit-cell parameters and the extraordinary and ordinary refractive indices of Er3+/Yb3+-codoped LiNbO3 crystals. Both properties depend in a non-monotonic manner on the Er3+/Yb3+ content. A singularity was observed at concentrations of 1.1-1.2 mol. % in the crystal (0.6-0.7 mol. % in the melt). In the
same way the Er and Yb concentration influences the periodically poled lithium niobate formation. The observed behavior of
refractive indices and unit-cell parameters of Er3+/Yb3+-codoped LiNbO3 crystals could be explained in terms of the RE3+-ion concentration affecting the Li-vacancy concentration and the RE3+-ion positions in the crystal.
Received: 21 May 2001 / Revised version: 22 August 2001 / Published online: 23 October 2001 相似文献
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V. Dierolf A.B. Kutsenko A. Ostendorf W. von der Osten W. Sohler H. Suche 《Applied physics. B, Lasers and optics》2001,72(7):803-810
Starting from previous investigations in LiNbO3 bulk crystals, we studied the optical properties of Er3+ ions in Ti:LiNbO3 channel waveguides and investigated the waveguide-specific lattice environment of the Er3+ ions (“sites”) caused by the doping method used and the presence of a large number of Ti4+ ions. For that purpose the method of combined excitation–emission spectroscopy was applied for the first time to waveguides
at low temperatures. Comparing the spectroscopic results obtained for the green, red, and near-IR luminescence (λ≈550, ≈650
and ≈980 nm) under direct (450 nm), 2-step (980 nm), and 3-step (1.5 μm) laser excitation, we found several distinguishable
Er3+ sites which in terms of energy levels and relative numbers are similar to those in bulk material, but exhibit significantly
different up-conversion efficiencies and strongly inhomogeneously broadened transitions. Moreover, we were able to distinguish
isolated and cluster Er3+ sites by their characteristic excitation and emission transition energies and studied the respective excitation/relaxation
channels. The cluster sites are most efficient in the up-conversion process, especially under 3-step excitation. Using accepted
microscopic models for Er3+ and Ti4+ incorporation into the LiNbO3 crystal lattice, the site distribution and up-conversion mechanisms are elucidated and their consequences for laser applications
in different spectral regions are discussed.
Received: 16 November 2000 / Published online: 21 March 2001 相似文献
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S. H. Choh J. H. Kim I. -W. Park H. J. Kim D. Choi S. S. Kim 《Applied magnetic resonance》2003,24(3-4):313-319
Rare-earth ions of Nd3+ and Er3+ in nearly stoichiometric and MgO-doped LiNbO3 crystals, respectively, have been investigated by employing an X-band electron spin resonance (ESR) spectrometer. The grown crystal was heated in Li-rich powder at 1100°C in order to make it nearly stoichiometric by the vapor transport equilibrium technique. Due to the fact that the ESR linewidth is much narrower in the stoichiometric crystal than in the congruent LiNbO3, we were able to determine the hyperfine constants of143Nd and145Nd at 4 K. By codoping MgO into LiNbO3, a new Er3+ center has been observed with a differentg-tensor. We propose that the new Er3+ center in Mg-doped LiNbO3 occupies the niobium site due to the local excessive Mg2+ ion at the lithium site, whereas Nd3+ and Er3+ in congruent crystals reside at the lithium site. The proposal is consistent with theg-value anisotropy. 相似文献
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Results of cooperative phenomena investigations in the impurity subsystem of lithium niobate crystals doped with Er3+ and co-doped with Yb3+ impurity ions under continuous wave and pulsed excitation at 975 nm and 1064 nm wavelengths are presented. Dependences of some spectroscopic characteristics on the intensity of laser pumping are studied. Based on the pair centers model the analysis of the cooperative luminescence behavior in LiNbO3:Yb3++Er3+ crystals is performed. 相似文献
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Dynamics of the Yb3+ to Er3+ energy transfer in LiNbO3 总被引:1,自引:0,他引:1
The energy transfer dynamics between Yb3+ and Er3+ ions in lithium niobate is investigated after ytterbium-pulsed excitation at 920 nm. The sensitisation of the LiNbO3:Er3+ system with Yb3+ ions does not modify the lifetime of the 4I13/2 erbium level (1.5-μm emission), whereas it induces a marked, concentration-dependent change in the lifetime of the 2F5/2 (Yb3+) and 4S3/2 (Er3+) multiplets (1060-nm and 550-nm emissions, respectively). The results are analysed by using the rate-equation formalism and
cross-relaxation model for the energy transfer.
Received: 15 October 1998 / Revised version: 24 November 1998 / Published online: 24 February 1999 相似文献
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The polarized optical absorption of Er3+-doped LiNbO3 has been obtained and analyzed within the framework of the Judd-Ofelt theory including polarization dependences. These results are compared with those obtained under unpolarized conditions. Fluorescence lifetimes for different Er3+ concentrations have also been measured in the temperature range 10–300 K. 相似文献