基于牛顿迭代法高温光谱温度和发射率的反演研究

针对基于光谱数据进行温度与发射率分离过程中存在的n个方程包含n+1个未知数这一欠定问题,提出利用牛顿迭代法来实现材料表面真温及发射率的反演计算,通过给定温度和发射率初值,利用泰勒级数的线性项建立迭代公式,通过迭代得到温度和发射率的近似解。分别利用理论热辐射谱和腔黑体的实验数据进行验证,结果表明,任意给定温度和发射率初值均可获得与真实温度接近的计算温度值,相对误差小于0.09。发射率反演结果与真实发射率线形一致,当温度和发射率初值越接近真实温度和发射率时,发射率反演结果越精确。该方法消除了发射率假定模型限制,有望应用于高温及超高温下各种材料真实温度和光谱发射率研究。     

自然状态下水泥路面温度与其发射率耦合关系研究

地表发射率是地表温度遥感反演中不可缺少的参数之一。常规获取地表发射率的遥感方法中,存在温度和发射率病态反演的问题;而实验室实测方法在恒定的自然条件下测定,对于遥感实用有一定的局限性。为解决上述问题,本研究利用温度和发射率相互耦合的关系,剔除温度效应的影响,提高发射率的精度,进而提高遥感反演地表温度的精度。对于不同地表物质而言,发射率和温度耦合关系又不同,本研究针对典型的城市人造地表类型之一——水泥路面,基于合理的自然状态下水泥路面发射率和温度观测实验,筛选理想大气环境下实测数据;利用最优发射率与温度分离算法取代光谱仪自带算法,提取精度较高发射率数据;分析时序水泥路面温度和发射率数据的耦合关系,建立耦合模型,并进行验证。研究结果表明：水泥路面的发射率二阶导数与温度相关性最高,相关系数为-0.925 1。以发射率二阶导数为自变量的逐步回归模型为最佳关系模型,判定系数R2达到0.886,验证结果的均方根误差RMSE为0.292 1。水泥路面温度与其发射率耦合关系模型的建立为提高遥感反演地表温度的精度提供了一种途径。     

低温装置材料表面辐射系数实验研究

材料表面辐射系数与材料的种类、壁面的温度以及材料的表面状况有关。文中对不同材料的不同表面和不同温度情况下的辐射系数进行了实验研究 ,为低温装置系统表面处理工艺方法提供了依据。     

超光谱红外卫星资料同步反演不同地表类型的大气廓线、地表温度和地表发射率

大气温度、水汽、地表温度和地表发射率是大气和地表的本征信息量。利用卫星红外资料精确反演大气温湿廓线有利于准确预报天气和研究气候变化,同时地表温度和地表发射率光谱的反演为研究植物生长与作物产量、地表水分蒸发与循环、能量平衡、地表成分及物理性质、气候变迁与全球环境提供重要参数指标。把大气和地面作为一个整体系统来考虑,建立一种能同步反演大气温度廓线、大气水汽廓线、地表温度和地表发射率的反演方法,利用超光谱红外卫星资料(atmospheric infrared sounder, AIRS),针对我国新疆地区沙漠和雪地两种典型发射率地表同步反演大气温度廓线、水汽廓线、地表温度和地表发射率。反演方法首先线性化地球-大气系统红外辐射传输方程, 提出通过经验正交函数构建大气廓线和地表发射率光谱,有效减少反演变量数,建立同步物理反演模式,然后以美国国家环境预报中心(National Centers for Environmental Prediction,NCEP)的预报结果(初始大气温度、水汽廓线以及地表参数)作为初始值,最后通过牛顿迭代得到最优化解。反演观测区域覆盖我国新疆塔克拉玛干沙漠和准噶尔盆地,分别选择位于塔克拉玛干沙漠腹地的塔中探测站(纬度38.98°, 经度83.64°)和准噶尔盆地的阜康荒漠生态系统国家野外科学观测研究站(纬度44.2°, 经度87.9° )为反演地面验证点。反演结果表明,塔克拉玛干沙漠地表温度明显高于准噶尔盆地地表温度,与实际情况相一致;根据反演的8.6和13.4 μm处的地表发射率分布情况,可以看出在8.6 μm处沙漠地表发射率明显低于雪地发射率,在6～15 μm范围内,反演的沙漠地区(塔中站)地表发射率和雪地地区(阜康站)地表发射率与美国喷气推进实验室测量的沙漠发射率光谱和雪地发射率光谱相一致。研究表明,把大气和地面作为一个整体系统来考虑,把地表发射率加入到反演中,通过比较和分析沙漠地区(塔中)和雪地地区(阜康)的大气廓线反演结果与当地气象探空值和传统反演方法反演值,改进了大气温度廓线和水汽廓线反演精度,特别是边界层温度和水汽改进尤为明显;同时分析表明在发射率光谱变化较大的沙漠地区, 大气廓线反演精度的改进比雪地要高,这是由于地表发射率光谱在沙漠、戈壁地区变化较大,而雪地的发射率光谱变化不大。用该方法针对地表发射率光谱变化较大的地区(沙漠)同步反演大气廓线、地表温度和地表发射率,可以更有效的提高大气温度廓线、水汽廓线的反演精度。该研究结果可以为数值天气预报和我国未来超光谱红外卫星应用提供服务和有力支持, 具有十分重要的意义。     

热辐射体真实温度的测试研究

在辐射测温中，普遍存在一个问题，被测温度物体表面发射率影响很大，而物体的发射率很难确测量，这是因为发射率不仅与材料有关，而且还与波长，温度，表面状态（表面粗糙度，氧化程度等）有关，本文叙述一种利用多波长辐射法测量实际物体真实温度的方法，该方法利用最小二乘法原理拟合出实际热辐射体的光谱发射率曲线，从而使测量目标的真实温度成为可能。     

发射率限定辐射测温原理

辐射测温技术随着辐射测量传感器技术的进步而不断进步,已经由单波长测温发展到多波长和多波段测温,由点温测量发展到二维甚至三维温度场测量。但是在辐射测温更精确反演方面,却很难克服因发射率未知性而引起的模型构建误差。发射率行为难以确定并极大地影响了测温精度,急需发展一种具有通用性,不受发射率具体行为限制,具有较高稳定性的辐射测温方法。双波长测温适用于发射率具有灰体行为的物体温度测量,一系列的发射率补偿算法和波长选择方法均未能很好地实现通用性测量,往往直接单色测量可能误差比比色法更小。多波长测温得到广泛应用,但并不是波长越多越好,发射率模型仍然具有较大局限性。提出了发射率直接限定算法和发射率松驰限定算法来反演温度。在发射率限定条件相同时,这两种方法是等价的。发射率松驰限定算法基于最小二乘算法和松驰因子进行真温求解。推导了松驰限定法的误差传递公式,发现在保证测量信号强度的前提下,λT越小温度误差越小;发射率行为对温度相对误差具有重要影响,在相同的λT条件下,发射率随波长变化越大,在限定区间上覆盖越均匀,测量误差越小。但从直接限定算法可以看出所测波长数越多,测量误差越小。两种方法均可以看出,减少限定区间长度也可以显著地提高测量精度。     

Spectral emissivity modeling of steel 201 during the growth of oxidation film over the temperature range from 800 to 1100 K in air

This study explores the spectral emissivity modeling of steel 201 during the growth of oxidation film over the temperature range from 800 to 1100 K at 1.5 μm. The radiance coming from the specimen is received by an InGaAs photodiode detector. The specimen temperature is obtained by averaging the two platinum–rhodium thermocouples, which are tightly welded in the front surface of specimen near the measuring area viewed by the detector. The variation of spectral emissivity with the temperature is studied at a given heating time. The variation of spectral emissivity with the heating time is evaluated at a definite temperature. The strong oscillations of spectral emissivity are observed and discussed in detail, which originate from the interference effect between the radiation stemming from the oxidization film on the specimen surface and the radiation coming from the specimen surface. The measurement uncertainties of spectral emissivity contributed only by the surface oxidization are about 3.2–14.1%. At a given heating time, the variation of spectral emissivity with the temperature abides well by a simple analytic functional form. And at a definite temperature, the variation of spectral emissivity with the heating time can also be well reproduced by fitting except for the periodical oscillations.     

The influence of furnace wall emissivity on steel charge heating

Radiation heat transfer is one of the most important heat transfer modes in high-temperature applications. It is a strongly non-linear process, which depends on the temperature and emissivity of heat exchange surfaces, their geometrical configuration and properties of the surrounding atmosphere. Heat exchange intensity between the surfaces depends mainly on their temperature differences. However, their emissivities influence significantly the radiation heat transfer process as well. Emissivity is a function of surface state or atmospheric chemical reactions, temperature and wavelengths. Because of these non-linearities, it is very complicated to evaluate such a real problem by numerical simulation, and experimental work seems to be the most reliable evaluation procedure. We applied special high-temperature coatings of different emissivities on furnace walls to evaluate the dependence between the furnace wall emissivity and steel charge heating. The emissivity analyses of the coatings used and emissivity measurement results in dependence on wavelength are presented in this paper. The dependence of the charge heating on the furnace wall emissivity, the importance of emissivity wavelength dependence and significant differences of the emissivity effect in electrical and gas heated furnaces are shown. The possible consequences and practical benefits are also discussed in this paper.     

Non-contact charge temperature measurement on industrial continuous furnaces and steel charge emissivity analysis

Continuous furnaces are commonly used for steel billet reheating before a rolling operation. It is necessary to perform a number of measurements to set-up and operate the optimization system of the furnaces correctly. A charge temperature measurement using infrared detectors can be one of the usable measurement techniques. This non-contact measurement method is based on the detection of infrared radiation emitted from a measured surface. The radiation intensity depends on the surface temperature and emissivity, which is one of the most important parameters for infrared measurements. Advantages of the non-contact temperature measurement, as well as some problems regarding the surface emissivity, are presented. The direct steel billet temperature measurement procedure using infra-red detectors, emissivity determination procedures, and example results are introduced. It is shown that steel emissivity can vary from approx. 0.17 to 0.8, depending on the surface state, scale formation, and wavelength interval. These problems are critical for the charge temperature measurement using the infra-red detectors, and are discussed in this paper.     

Study on infrared emissivity of biomimetic motheye sapphire single crystal

As a focus of research on materials science, bionic structure has drawn a great deal of attention from researchers. In this paper, patterned antireflection microstructure used for space optical window was fabricated on the surface of sapphire single crystal based on “Biomimetic Motheye Structure”. Meanwhile, emissivity of patterned sapphire at high temperature was investigated. The results indicated that transmittance of sapphire increased with spectrum red shift effect because of surface microstructures; the emissivity of patterned sapphire increased with rising of temperature in 6∼11 μm band; microstructures on surface led the scattering and attenuation coefficient of light to increase, thus, the emissivity of patterned sapphire was greater than that of contrast specimen which was not patterned. At the end of the paper, an audacious conclusion was made that the effect of microstructure on emissivity would decrease or even disappear with the increase of temperature.     

Experimental study of the relationships between the spectral emissivity of brass and the temperature in the oxidizing environment

Effect of surface oxidization on the spectral emissivity of brass is studied over the temperature range from 800 to 1070 K at the wavelength of 1.5 μm. The temperature of brass surface is measured by averaging the two R-type platinum–rhodium thermocouples. The radiant energy emitted by the brass surface is received by an InGaAs photodiode detector. Two kinds of relationships between the spectral emissivity and the temperature are investigated in the oxidizing environment at the elevated temperature. One is the variation of spectral emissivity with the heating-duration time at the given temperature. The other is the variation of spectral emissivity with the temperature at the given heating-duration time. The interference effect of radiation coming from the brass surface and coming from the oxidization film is discussed when the oxidation film on the surface is grown. The resonant structures of spectral emissivity are observed during the whole heating period, in particular at the early stage of heating duration. The analytic formula of spectral emissivity versus the temperature is derived at the heating-duration time of 30, 60, 90, 120, 150, 180, 210, 240, 270 and 300 min, respectively. The conclusion is obtained that coefficients of analytic expressions between the spectral emissivity and the temperature are different from each other for the experimental results obtained at the different heating-duration time, though the polynomial functional form is suitable to fit all the measurements obtained in the present work.     

白铜热氧化过程中光谱发射率特性研究

随着科技的发展,工业领域对白铜产品质量的要求日益提升;利用辐射测温技术对白铜在冶炼和加工时的温度进行精确测量,是决定产品质量的重要手段,因此研究白铜的光谱发射率特性就显得尤为重要。基于傅里叶红外光谱仪搭建的光谱发射率测量装置,测量了白铜在四个温度点（673,773,873和973 K）,波长范围2～22 μm内的光谱发射率,分别研究了波长、温度、加热时间和氧化对白铜光谱发射率的影响。研究发现,在氮气环境下白铜的光谱发射率随温度的升高而增加,随波长的增加而减少。当白铜暴露在空气环境中,随着温度的升高,其光谱发射率迅速增加。673 K时,白铜表面生成一层细微的氧化物颗粒,阻止白铜进一步氧化,这些氧化物颗粒的光谱发射率大于白铜基底,所以此温度下短波处的光谱发射率略微增加。773 K时,白铜表面氧化物的主要成分是Cu₂O,在实验过程中也观察到白铜表面逐渐变红的现象,这也是白铜在773 K温度下其光谱发射率迅速增加的原因。873 K时,白铜表面氧化物的种类和含量明显增多,氧化膜的厚度满足干涉效应条件,在白铜的光谱发射率曲线中可以明显地观察到干涉极值的演变,随着加热时间的增加,干涉极值逐渐向长波移动。随着温度的升高,白铜的抗氧化能力下降。973 K时,白铜表面的氧化程度最深,在XRD图中氧化物的峰值也最大,因此氧化1 h后由于干涉效应产生的干涉极值数最多。综上所述,波长、温度和氧化对白铜的光谱发射率有重要的影响,在运用辐射测温技术测量白铜温度时应充分考虑上述因素的影响。该研究丰富了白铜的光谱发射率数据,为辐射测温提供了真实可靠的数据支撑。     

Detection of Sea Surface Temperature (SST) Using Infrared Band Data of Advanced Very High Resolution Radiometer (AVHRR) in the Gulf of Finland

This paper presents the detection of sea surface temperature (SST) in the Gulf of Finland using infrared band data of Advanced Very High Resolution Radiometer (AVHRR). AVHRR imagery is evaluated as a main data source for monitoring SST as a measure of upwelling's dynamic. Sea surface effects (SSE), however, cause a temperature difference between the sea surface skin and water below the surface. Therefore, SSE is taken into account as one of the major error factors in the SST esimation. Further studies will be investigated using both AVHRR and MODIS in the future.     

Infrared technique for simultaneous determination of temperature and emissivity

This paper presents, in the context of materials dynamic behaviour study, a method for simultaneous measurement of the temperature and emissivity of a solid’s surface, by the use of infrared radiation. In contrast to existing methods, this method has no need for a pre-measurement of the surface emissivity. The emissivity and the temperature are measured simultaneously, by detecting the variations of emitted radiation and infrared radiation reflecting on the surface, at two different spectral zones. In this way, the accuracy of the measured temperature is greatly improved in cases were the surface optical properties vary during the measurement. Several experiments were carried out in order to complete the theoretical foundation of the method and to outline its accuracy and some of its limitations. There are various industrial applications of this method, for example the control of the temperature of the mechanical parts during work machining. One of them may be the measurement of the temperature of a sample during mechanical testing. An application of the method is proposed, that is easy to employ with non-sophisticated infrared and optical components. The results confirm the accuracy of the proposed method with an order of 3% of precision for temperature determination.     

目标表面发射率对红外热像仪测温精度的影响

介绍了红外热像仪测温原理,分析了影响红外热像仪测温精度的因素,计算了不同表面发射率下红外热像仪的测温误差曲线。理论分析表明,目标表面发射率越高,红外热像仪测温精度越高。实验改变表面发射率的设置,计算了不同表面发射率对应的总辐射亮度,得到TP8型长波红外热像仪能够精确测温时,目标表面发射率必须大于0.5的结果。最后,对表面发射率分别为0.96、0.93和0.3的3种材料进行实际测温,结果表明,材料表面发射率较高时,红外热像仪具有较好的测温精度。     

一种红外光谱发射率测量装置的研制

研制了一种利用对称双光路比对法测量材料表面光谱发射率的装置,该装置采用多光谱辐射测温技术测量材料表面温度,解决了不规则材料表面温度难以精确测定的问题,实现了材料表面半球发射率和表面温度的同时测定。     

中红外波段地表发射率特性分析

陆表温度(LST)在地-气相互作用过程中扮演着重要的角色,是全球变化研究的关键参数。陆表发射率是陆表温度反演的关键输入参数之一。中红外谱区(3~5 μm)介于可见光-近红外谱区(0.38~2.5 μm)与热红外谱区(8~14 μm)之间,地物的发射率在该谱区表现出独特的光谱特性,可用于霜冻监测、矿物成分分析等研究。由于传感器在中红外谱区探测到的能量既有来自于地物自身发射的热辐射能量,又有反射的太阳辐射能量,这两部分的能量分离机理比较复杂,因此中红外谱区发射率特性分析的相关文献较少。本文针对单一均匀地表和具有混合像元的复杂地表计算了MODIS红外通道的有效发射率,发现通道有效发射率在单一均匀地表下与温度的耦合效应不强烈;但在复杂地表下,通道有效发射率与混合像元内的成分比例以及成分的地表温度具有耦合效应。在误差允许的范围内,混合像元的有效发射率可以忽略成分地表温度的影响。发射率误差对陆表温度反演精度的敏感性随着波长的变化而变化。在热红外波段,敏感性是其在中红外波段的2倍左右,说明利用中红外波段进行陆表温度反演具有一定的优势。     

基于相关性的中红外温度与发射率分离算法

温度和发射率是耦合在一起的.在精确获得大气参数的情况下,由传感器的辐射测量反演地表的温度与发射率,仍然是一个病态问题,必须采取一定的策略进行温度与发射率的分离.因此,温度与发射率的分离是红外遥感的核心问题.文章在分析无太阳直射光影响时大气下行辐射和含有大气残留的地表发射率之间关系的基础上,提出了一个针对野外测量中红外高光谱数据的温度与发射率分离算法.该算法利用大气下行辐射和含有大气残留的地表发射率之间的相关性作为判据来优化地表温度,进而获得地表发射率.基于模拟的中红外高光谱数据,对算法的精度进行评价.结果表明,该算法能够获得较高的地表温度和发射率反演精度;具有较广的适用范围,对测量过程中大气下行辐射变化不敏感;同时算法具有一定的抗噪性.     

目标表面发射率对红外热像仪测温精度的影响

介绍了红外热像仪测温原理,分析了影响红外热像仪测温精度的因素,计算了不同表面发射率下红外热像仪的测温误差曲线。理论分析表明,目标表面发射率越高,红外热像仪测温精度越高。实验改变表面发射率的设置,计算了不同表面发射率对应的总辐射亮度,得到TP8型长波红外热像仪能够精确测温时,目标表面发射率必须大于0.5的结果。最后,对表面发射率分别为0.96、0.93和0.3的3种材料进行实际测温,结果表明,材料表面发射率较高时,红外热像仪具有较好的测温精度。     

Total emissivity measurements without use of an absolute reference

Total emissivity measurement by ordinary steady state radiometric methods are difficult at low temperature; besides, those methods require an emissivity reference. In this paper, several new periodic methods suitable for total emissivity measurements are presented. First it is shown that the thermal modulation of a sample allows direct emissivity measurements, even at low temperature, with an ordinary equipment involving no cooled vessel. Very accurate measurements have been performed within a few minutes at room temperature, on reflective materials. Second, it is shown that indirect total emissivity measurements are also feasible, provided source and sample temperatures are equal. This condition can be fulfilled with a modulated temperature hemispherical gray surface as IR source, or in a simpler way, with a mobile part of a hemisphere. Third, it is shown that if both sample and source temperatures are modulated, simultaneous direct and indirect measurements can be carried out. This results in an absolute emissivity measurement without reference. As an experimental validation, simultaneous direct and indirect measurements of the total directional emissivity are carried out on three samples at room temperature. Periodic radiometry methods are found to be reliable and accurate, emission and reflection measurements giving the same result.